Citation: GUO Wei, WANG Kai, SHEN Yi-Hua, ZHANG He, WENG Tao, MA Ting-Li. A Simple Template Synthesis of Hierarchically Mesoporous TiO₂ Microsphere for Dye-Sensitized Solar Cells[J]. Acta Physico-Chimica Sinica, ;2013, 29(01): 82-88. doi: 10.3866/PKU.WHXB201211071 shu

A Simple Template Synthesis of Hierarchically Mesoporous TiO₂ Microsphere for Dye-Sensitized Solar Cells

GUO Wei ¹ ,
WANG Kai ¹ ,
SHEN Yi-Hua ¹ ,
ZHANG He ² ,
WENG Tao ² ,
MA Ting-Li ^1,2,

1.
1 State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, Liaoning Province, P. R. China;
2 Yingkou Opvtech New Energy Co. Ltd, Yingkou 115003, Liaoning Province, P. R. China

Received Date: 3 September 2012
Available Online: 7 November 2012
Fund Project: 国家自然科学基金(51273032)资助项目 (51273032)

Mesoporous TiO₂ microspheres were synthesized using a simple template method. The effect of the alkyl chain length on the synthesis and properties of the TiO₂ microspheres was studied. A high power conversion efficiency (9.5%-10.1%) was attained by the dye-sensitized solar cells (DSCs) fabricated with the hierarchically mesoporous TiO₂ microsphere films. The physical properties of the TiO₂ microspheres were analyzed by X-ray diffraction (XRD), N₂ physisorption (BET), and scanning electron microscopy (SEM). The results indicated the TiO₂microsphere crystal structure to be in the pure anatase phase; the rough surface microstructure of the TiO₂ microspheres, formed through accumulation of nanocrystalline (14-18 nm diameter) TiO₂ particles, provides a proper large surface area and mesoporous structure. The hierarchically mesoporous TiO₂ microspheres can form od paths for mass transport, and also act as light scattering layers for efficient light harvesting. Meanwhile, the rough TiO₂ microsphere surface ensures a sufficient amount of dye uptake, and consequently improves the photo-generated electron density. Electrochemical impedance analysis demonstrated the advantage of using microspheres for mass transport in electrolytes.
- Dye-sensitized solar cell,
- Photoelectrode,
- TiO₂ sphere,
- Nanostructure,
- Photoelectric conversion
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沈阳化工大学材料科学与工程学院沈阳 110142

A Simple Template Synthesis of Hierarchically Mesoporous TiO2 Microsphere for Dye-Sensitized Solar Cells

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通讯作者: 陈斌, bchen63@163.com

A Simple Template Synthesis of Hierarchically Mesoporous TiO₂ Microsphere for Dye-Sensitized Solar Cells