Citation: DUAN Lin-Qiang, QIAO Cheng-Fang, WEI Qing, XIA Zheng-Qiang, CHEN San-Ping, ZHANG Guo-Chun, ZHOU Chun-Sheng, GAO Sheng-Li. Structures, Thermodecomposition Kinetics and Luminescence Properties of Three Lanthanide-Based Supramolecular Compounds with 1H-Benzimidazole-2-carboxylic Acid[J]. Acta Physico-Chimica Sinica doi: 10.3866/PKU.WHXB201210122 shu

Structures, Thermodecomposition Kinetics and Luminescence Properties of Three Lanthanide-Based Supramolecular Compounds with 1H-Benzimidazole-2-carboxylic Acid

1.
1 Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi'an 710069, P. R. China;
2 Department of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Comprehensive Utilization of Tailing Resources, Shangluo University, Shangluo 726000, Shaanxi Province, P. R. China

Received Date: 25 July 2012
Available Online: 12 October 2012
Fund Project: 国家自然科学基金(21173168, 21073142, 21127004) (21173168, 21073142, 21127004)陕西省教育厅科研基金(2010JK882, 2010JQ2007, 11JS110, 11JK0578)资助项目 (2010JK882, 2010JQ2007, 11JS110, 11JK0578)

Three lanthanide-based supramolecular compounds, [Ln(HBIC)₃]_n[Ln=Sm (1), Ho (2), Yb (3); H₂BIC=1H-benzimidazole-2-carboxylic acid], were hydrothermally synthesized and structurally characterized by X-ray single crystal diffraction (compounds 1 and 2), powder X-ray diffraction (XRD) (compound3), elemental analysis, infrared (IR) spectroscopy, and thermal analysis. Structural analyses reveal that compounds 1-3 are isomorphous and display a two-dimensional (2D) plane, in which each lanthanide center is coordinated by three N and five O atoms from five flexible HBIC^- ligands with two kinds of new coordination modes, giving rise to a slightly distorted two-capped triangle prism geometry. The 2D square networks are further assembled into a three-dimensional (3D) supramolecular framework through strong hydrogen-bonding interactions. Thermogravimetry analyses (TG) indicate that compounds 1-3 exhibit od thermostability and could be stable up to 360℃. By means of differential scanning calorimetry (DSC) techniques, the thermoanalysis kinetics parameters of the thermodecomposition of compound 1 were calculated by the Kissinger's and Ozawa-Doyle's methods; the pre-exponential factor A_K was 1.286×108 s^-1 and the apparent activation energy E_K and E_O were determined to be 199.3 and 205.2 kJ·mol^-1, respectively. In addition, the luminescent properties of compounds 1 and 3 were also studied at room temperature in the solid state. The results reveal that compounds 1 and 3 exhibit characteristic emission bands of the corresponding lanthanide ions in the visible and near-infrared regions, respectively.
- Lanthanide coordination compound,
- 1H-Benzimidazole-2-carboxylic acid,
- Structure analysis,
- Luminescence,
- Thermoanalysis kinetics
1. [1]
  
  (1) Lv, Y. K.; Zhan, C. H.; Feng, Y. L. CrystEngComm 2010, 12,3052. doi: 10.1039/b925546j
2. [2]
  (2) Lv, Y. K.; Zhan, C. H.; Jiang, Z. G.; Feng, Y. L. Inorg. Chem. Commun. 2010, 13, 440. doi: 10.1016/j.inoche.2010.01.007
3. [3]
  (3) Halder, G. J.; Kepert, C. J.; Moubaraki, B.; Murray, K. S.;Cashion, J. D. Science 2002, 298, 1762. doi: 10.1126/science.1075948
4. [4]
  (4) Min, K. S.; Suh, M. P. J. Am. Chem. Soc. 2000, 122, 6834. doi: 10.1021/ja000642m
5. [5]
  (5) Dong, Y. B.; Jiang, Y. Y.; Li, J.; Ma, J. P.; Liu, F. L.; Tang, B.;Huang, R. Q.; Batten, S. R. J. Am. Chem. Soc. 2007, 129, 4520.doi: 10.1021/ja0701917
6. [6]
  (6) Sudik, A. C.; Millward, A. R.; Ockwig, N.W.; Côté, A. P.; Kim,J.; Yaghi, O. M. J. Am. Chem. Soc. 2005, 127, 7110. doi: 10.1021/ja042802q
7. [7]
  (7) Bünzli, J. C. G.; Piguet, C. Chem. Rev. 2002, 102, 1897. doi: 10.1021/cr010299j
8. [8]
  (8) Dias, A. D. B.; Viswanathan, S. Chem. Commun. 2004, 1024.
9. [9]
  (9) Ronson, T. K.; Lazarides, T.; Adams, H. Chem. Eur. J. 2006, 12,9299. doi: 10.1002/chem.200600698
10. [10]
  (10) Yu, Y. Y.; Liu, J. F.; Li, H. Q.; Zhao, G. L. Acta Phys. -Chim. Sin. 2010, 26, 1535. [余玉叶, 刘建风, 李花琼, 赵国良. 物理化学学报, 2010, 26, 1535.] doi: 10.3866/PKU.WHXB20100622
11. [11]
  (11) Zhu,W. H.;Wang, Z. M.; Gao, S. Inorg. Chem. 2007, 46, 1337.doi: 10.1021/ic061833e
12. [12]
  (12) Ying, S. M.; Mao, J. G. Cryst. Growth Des. 2006, 6, 964. doi: 10.1021/cg050554j
13. [13]
  (13) Do, K.; Muller, F. C.; Muller, G. J. Phys. Chem. A 2008, 112,6789. doi: 10.1021/jp804463e
14. [14]
  (14) Long, D. L.; Blake, A. J.; Champness, N. R.;Wilson, C.;Schröder, M. Angew. Chem. Int. Edit. 2001, 40, 2443.
15. [15]
  (15) Long, D. L.; Hill, R. J.; Blake, A. J.; Champness, N. R.;Hubberstey, P.; Proserpio, D. M.;Wilson, C.; Schröder, M.Angew. Chem. Int. Edit. 2004, 43, 1851. doi: 10.1002/anie.200352625
16. [16]
  (16) Cui, Y.; N , H. L.; White, P. S.; Lin,W. Chem. Commun. 2002,1666.
17. [17]
  (17) Qin, C.;Wang, X. L.;Wang, E. B.; Su, Z. M. Inorg. Chem.2005, 44, 7122. doi: 10.1021/ic050906b
18. [18]
  (18) Zhang, M. B.; Zhang, J.; Zheng, S. T.; Yang, G. Y. Angew. Chem. Int. Edit. 2005, 44, 1385. doi: 10.1002/anie.200461424
19. [19]
  (19) Wagner, E.;Wittmann, H. J.; Elz, S.; Strasser, A. Bioorg. Med. Chem. Lett. 2011, 21, 6274. doi: 10.1016/j.bmcl.2011.09.001
20. [20]
  (20) Nandhakumar, R.; Soo, A. Y.; Hong, J.; Ham, S.; Kim, K. M.Tetrahedron 2009, 65, 666. doi: 10.1016/j.tet.2008.11.022
21. [21]
  (21) Zheng, S. R.; Cai, S. L.; Fan, J.; Xiao, T. T.; Zhang,W. G. Inorg. Chem. Commun. 2011, 14, 818. doi: 10.1016/j.inoche.2011.02.017
22. [22]
  (22) Fan, J.; Cai, S. L.; Zheng, S. R.; Zhang,W. G. Acta Crystallogr. Sect. C: Cryst. Struct. Commun. 2011, 67, m346.
23. [23]
  (23) Sheldrick, G. M. SHELXS-97, Program for Solution of CrystalStructures; University of ttingen: Germany, 1997.
24. [24]
  (24) Sheldrick, G. M. SHELXL-97, Program for Refinement ofCrystal Structures; University of ttingen, Germany, 1997.
25. [25]
  (25) Nakamoto, K. Infrared Spectra and Raman Spectra of Inorganic and Coordination Compounds;Wiley VCH: New York, 1986.
26. [26]
  (26) Kissinger, H. E. Anal. Chem. 1957, 29, 1702. doi: 10.1021/ac60131a045
27. [27]
  (27) Ozawa, T. Bull. Chem. Soc. Jpn. 1965, 38, 1881. doi: 10.1246/bcsj.38.1881
28. [28]
  (28) Hu, R. Z.; Gao, S. L.; Zhao, F. Q.; Shi, Q. Z.; Zhang, T. L.;Zhang, J. J. Thermal Analysis Kinetics; Science Press: Beijing,2007. [胡荣祖, 高胜利, 赵风起, 史启祯, 张同来, 张建军. 热分析动力学. 北京: 科学出版社, 2007.]
29. [29]
  (29) Su, S. Q.; Chen,W.; Qin, C.; Song, S. Y.; Guo, Z. Y.; Li, G. H.;Song, X. Z.; Zhu, M.;Wang, S.; Hao, Z. M.; Zhang, H. J. Cryst. Growth Des. 2012, 12, 1808. doi: 10.1021/cg201283a
30. [30]
  (30) Liu, M. S.; Yu, Q. Y.; Cai, Y. P.; Su, C. Y.; Lin, X. M.; Zhou, X.X.; Cai, J.W. Cryst. Growth Des. 2008, 8, 4083. doi: 10.1021/cg800526y
31. [31]
  (31) Li, Z. F.; Yu, J. B.; Zhou, L.; Zhang, H. J.; Deng, R. P. Inorg. Chem. Commun. 2008, 11, 1284. doi: 10.1016/j.inoche.2008.08.008
32. [32]
  (32) Huang,W.;Wu, D. Y.; Zhou, P.; Yan,W. B.; Guo, D.; Duan, C.Y.; Meng, Q. J. Cryst. Growth Des. 2009, 9, 1361. doi: 10.1021/cg800531y
1. [1]
  Liyang ZHANG , Dongdong YANG , Ning LI , Yuanyu YANG , Qi MA . Crystal structures, luminescent properties and Hirshfeld surface analyses of three cadmium(Ⅱ) complexes based on 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)benzoate. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240079
2. [2]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240114
3. [3]
  Yaling Chen . Basic Theory and Competitive Exam Analysis of Dynamic Isotope Effect. University Chemistry, doi: 10.3866/PKU.DXHX202311093
4. [4]
  Cheng Zheng , Shiying Zheng , Yanping Zhang , Shoutian Zheng , Qiaohua Wei . Synthesis, Copper Content Analysis, and Luminescent Performance Study of Binuclear Copper (I) Complexes with Isomeric Luminescence Shift: A Comprehensive Chemical Experiment Recommendation. University Chemistry, doi: 10.3866/PKU.DXHX202310131
5. [5]
  Tianyun Chen , Ruilin Xiao , Xinsheng Gu , Yunyi Shao , Qiujun Lu . Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes. University Chemistry, doi: 10.3866/PKU.DXHX202312017
6. [6]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20230271
7. [7]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240145
8. [8]
  You Wu , Chang Cheng , Kezhen Qi , Bei Cheng , Jianjun Zhang , Jiaguo Yu , Liuyang Zhang . ZnO/D-A共轭聚合物S型异质结高效光催化产H₂O₂及其电荷转移动力学研究. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202406027
9. [9]
  Ting WANG , Peipei ZHANG , Shuqin LIU , Ruihong WANG , Jianjun ZHANG . A Bi-CP-based solid-state thin-film sensor: Preparation and luminescence sensing for bioamine vapors. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240134
10. [10]
  Wenyan Dan , Weijie Li , Xiaogang Wang . The Technical Analysis of Visual Software ShelXle for Refinement of Small Molecular Crystal Structure. University Chemistry, doi: 10.3866/PKU.DXHX202302060
11. [11]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240078
12. [12]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20230357
13. [13]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240188
14. [14]
  Ji Qi , Jianan Zhu , Yanxu Zhang , Jiahao Yang , Chunting Zhang . Visible Color Change of Copper (II) Complexes in Reversible SCSC Transformation: The Effect of Structure on Color. University Chemistry, doi: 10.3866/PKU.DXHX202307050
15. [15]
  Wanqun Hu , Pingping Zhu , Yuan Zheng , Wanqun Zhang , Wei Shao , Hong Wu , Qiang Zhou , Kaiping Yang , Xiang Sheng . Design and Practice of Ideological and Political Case Study in Instrumental Analysis Experiment Course: the Extraction and Structural Identification of Artemisinin. University Chemistry, doi: 10.3866/PKU.DXHX202310062
16. [16]
  Yaofeng Yuan , Keyin Ye , Chunfa Xu , Hong Yan , Yuanming Li . Fostering an International Perspective in Postgraduate Student Teaching: A Case Study of the Organic Structure Analysis Course. University Chemistry, doi: 10.3866/PKU.DXHX202402024
17. [17]
  Fan JIA , Wenbao XU , Fangbin LIU , Haihua ZHANG , Hongbing FU . Synthesis and electroluminescence properties of Mn²⁺ doped quasi-two-dimensional perovskites (PEA)₂Pb_yMn_1-yBr₄. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20230473
18. [18]
  Shule Liu . Application of SPC/E Water Model in Molecular Dynamics Teaching Experiments. University Chemistry, doi: 10.3866/PKU.DXHX202310029
19. [19]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240003
20. [20]
  Jinfu Ma , Hui Lu , Jiandong Wu , Zhongli Zou . Teaching Design of Electrochemical Principles Course Based on “Cognitive Laws”: Kinetics of Electron Transfer Steps. University Chemistry, doi: 10.3866/PKU.DXHX202309052

Get Citation

PDF

XML

Metrics

PDF Downloads(667)
Abstract views(1948)
HTML views(4)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142