Citation: WANG Hong-Tao, SUN Lin, CHEN Ji-Tang, LUO Chun-Hua. Ionic Conduction in Sn_0.9Mg_0.1P₂O₇ at Intermediate Temperatures[J]. Acta Physico-Chimica Sinica doi: 10.3866/PKU.WHXB201210101 shu

Ionic Conduction in Sn_0.9Mg_0.1P₂O₇ at Intermediate Temperatures

1.
College of Chemistry and Chemical Engineering, Fuyang Teachers College, Fuyang 236041, Anhui Province, P. R. China

Received Date: 16 July 2012
Available Online: 10 October 2012
Fund Project: 国家自然科学基金(50903018)资助项目 (50903018)

Sn_0.9Mg_0.1P₂O₇ was synthesized in a solid state reaction and characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The XRD pattern indicated that the sample exhibited a single cubic phase. The protonic and oxide-ionic conduction were investigated using various electrochemical methods including AC impedance spectroscopy and gas concentration cells at intermediate temperatures (323-523 K). The highest conductivity observed was 5.04×10^-2 S·cm^-1 in a wet H₂ atmosphere at 423 K. The ionic, protonic, oxide-ionic, and electronic transport numbers (N_t) were 0.95-1.00, 0.84-0.96, 0.04-0.10, 0.00-0.05, respectively, in a wet hydrogen atmosphere. The results indicate that Sn_0.9Mg_0.1P₂O₇ is an almost pure ionic conductor, has dominant protonic conduction, some limited oxide-ionic conduction, but little electronic conduction. A H₂/air fuel cell using Sn_0.9Mg_0.1P₂O₇ as the electrolyte (thickness: 1.5 mm) generated maximum power densities of 18.7 mW·cm^-2 at 398 K, 27.7 mW·cm^-2 at 423 K, and 33.9 mW·cm^-2 at 448 K.
- Sn_0.9Mg_0.1P₂O₇,
- Ionic conduction,
- Electrolyte,
- Conductivity,
- Concentration cell,
- Fuel cell
1. [1]
  
  (1) Fu, X. Z.; Luo, J. L.; Sanger, A. R.; Luo, N.; Chuang, K. T.J. Power Sources 2010, 195, 2659. doi: 10.1016/j.jpowsour.2009.10.069
2. [2]
  (2) Weber, A.; Tiffee, E. I. J. Power Sources 2004, 127, 273. doi: 10.1016/j.jpowsour.2003.09.024
3. [3]
  (3) Kim, Y. M.; Lohsoontorn, P.; Bae, J. J. Power Sources 2010,195, 6420. doi: 10.1016/j.jpowsour.2010.03.095
4. [4]
  (4) Wang, X.W.; Yin, J. L.; Xu, J. H.;Wang, H. T.; Ma, G. L. Chin. J. Chem. 2011, 29, 2421. doi: 10.1002/cjoc.v29.11
5. [5]
  (5) Haile, S. M.; Boysen, D. A.; Chisholm, C. R. I.; Merle, R. B.Nature 2001, 410, 910. doi: 10.1038/35073536
6. [6]
  (6) Baker, R. T.; Salar, R.; Potter, A. R.; Metcalfe, I. S.; Sahibzada,M. J. Power Sources 2009, 191, 448. doi: 10.1016/j.jpowsour.2009.02.039
7. [7]
  (7) Xie, K.; Yan, R. Q.; Xu, X. X.; Liu, X. Q.; Meng, G. Y. J. Power Sources 2009, 187, 403. doi: 10.1016/j.jpowsour.2008.11.007
8. [8]
  (8) Liu, J.W.; Zhou, D. F.; Yang, M.; Luo, F.; Meng, J. Acta Phys. -Chim. Sin. 2012, 28, 1380. [刘建伟, 周德凤, 杨梅,罗飞, 孟健. 物理化学学报, 2012, 28, 1380.] doi: 10.3866/PKU.WHXB201203304
9. [9]
  (9) Martínez-Amesti, A.; Larrañaga, A.; Rodríguez-Martínez, L.M.; Nó, M. L.; Pizarro, J. L.; Lares iti, A.; Arriortua, M. I.J. Power Sources 2009, 192, 151. doi: 10.1016/j.jpowsour.2009.02.011
10. [10]
  (10) Zhu, B. Solid State Ionics 1999, 125, 397. doi: 10.1016/S0167-2738(99)00201-5
11. [11]
  (11) Zhang, S.; Bi, L.; Zhang, L.; Tao, Z.; Sun,W.;Wang, H.; Liu,W. J. Power Sources 2009, 188, 343. doi: 10.1016/j.jpowsour.2008.12.056
12. [12]
  (12) Yang, J. F.; Cheng, J. G.; Fan, Y. M.;Wang, R.; Gao, J. F. Acta Phys. -Chim. Sin. 2012, 28, 95. [杨俊芳, 程继贵, 樊玉萌,王睿, 高建峰. 物理化学学报, 2012, 28, 95.] doi: 10.3866/PKU.WHXB201111161
13. [13]
  (13) Boysen, D. A.; Uda, T.; Chisholm, C. R. I.; Haile, S. M. Science2004, 303, 68. doi: 10.1126/science.1090920
14. [14]
  (14) Nagao, M.; Kamiya, T.; Heo, P.; Tomita, A.; Hibino, T.; Sano,M. J. Electrochem. Soc. 2006, 153, A1604.
15. [15]
  (15) Tomita, A.; Kajiyama, N.; Kamiya, T.; Nagao, M.; Hibino, T.J. Electrochem. Soc. 2007, 154, B1265.
16. [16]
  (16) Tao, S.W. Solid State Ionics 2009, 180, 148. doi: 10.1016/j.ssi.2008.11.006
17. [17]
  (17) Chen, X.;Wang, C. S.; Payzant, E. A.; Xia, C. R.; Chu, D.J. Electrochem. Soc. 2008, 155, B1264.
18. [18]
  (18) Wu, X.; Verma, A.; Scott, K. Fuel Cells 2008, 8, 453. doi: 10.1002/fuce.v8:6
19. [19]
  (19) Genzaki, K.; Heo, P.; Sano, M.; Hibino, T. J. Electrochem. Soc.2009, 156, B806.
20. [20]
  (20) Tomita, A.; Yoshii, T.; Teranishi, S.; Nagao, M.; Hibino, T.J. Catal. 2007, 247, 137. doi: 10.1016/j.jcat.2007.02.001
21. [21]
  (21) Tomita, A.; Nakajima, J.; Hibino, T. Angew. Chem. Int. Edit.2008, 47, 1462.
22. [22]
  (22) Teranishi, S.; Kondo, K.; Tsuge, A.; Hibino, T. Sens. Actuators B 2009, 140, 170. doi: 10.1016/j.snb.2009.04.044
23. [23]
  (23) Nagao, M.; Takeuchi, A.; Heo, P.; Hibino, T.; Sano, M.; Tomita,A. Electrochem. Solid-State Lett. 2006, 9, A105.
24. [24]
  (24) Shen, Y. B.; Nishida, M.; Kanematsu,W.; Hibino, T. J. Mater. Chem. 2011, 21, 663. doi: 10.1039/c0jm02596h
25. [25]
  (25) Sato, Y.; Shen, Y. B.; Nishida, M.; Kanematsu,W.; Hibino, T.J. Meter. Chem. 2012, 22, 3973. doi: 10.1039/c2jm15335a
26. [26]
  (26) Jin, Y. C.; Okada, M.; Hibino, T. J. Power Sources 2011, 196,4905. doi: 10.1016/j.jpowsour.2011.02.028
27. [27]
  (27) Wang, H.; Liu, J.;Wang,W.; Ma, G. J. Power Sources 2010,195, 5596. doi: 10.1016/j.jpowsour.2010.03.087
28. [28]
  (28) Wang, H.; Zhang, H.; Xiao, G.; Zhang, F.; Yu, T.; Xiao, J.; Ma,G. J. Power Sources 2011, 196, 683. doi: 10.1016/j.jpowsour.2010.07.067
29. [29]
  (29) Shannon, R. D. Acta Cryst. A 1976, 32, 751. doi: 10.1107/S0567739476001551
30. [30]
  (30) Guan, J.; Dorris, S. E.; Balachardran, U.; Liu, M. Solid State Ionics 1997, 100, 45. doi: 10.1016/S0167-2738(97)00320-2
31. [31]
  (31) Shimura, T.; Esaka, K.; Matsumoto, H.; Iwahara, H. Solid State Ionics 2002, 149, 237. doi: 10.1016/S0167-2738(02)00400-9
32. [32]
  (32) Shimada, T.;Wen, C.; Taniguchi, N.; Otomo, J.; Takahashi, H.J. Power Sources 2004, 131, 289. doi: 10.1016/j.jpowsour.2003.11.087
33. [33]
  (33) Guo, Y.; Liu, B.; Chen, C.;Wang,W.; Ma, G. Electrochem. Commun. 2009, 11, 153. doi: 10.1016/j.elecom.2008.10.038
1. [1]
  Jiayu Tang , Jichuan Pang , Shaohua Xiao , Xinhua Xu , Meifen Wu . Improvement for Measuring Transference Numbers of Ions by Moving-Boundary Method. University Chemistry, doi: 10.3866/PKU.DXHX202311021
2. [2]
  Ru SONG , Biao WANG , Chunling LU , Bingbing NIU , Dongchao QIU . Electrochemical properties of stable and highly active PrBa_0.5Sr_0.5Fe_1.6Ni_0.4O_5+δ cathode material. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240397
3. [3]
  Jiandong Liu , Zhijia Zhang , Mikhail Kamenskii , Filipp Volkov , Svetlana Eliseeva , Jianmin Ma . Research Progress on Cathode Electrolyte Interphase in High-Voltage Lithium Batteries. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202308048
4. [4]
  Ran HUO , Zhaohui ZHANG , Xi SU , Long CHEN . Research progress on multivariate two dimensional conjugated metal organic frameworks. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240195
5. [5]
  Tao Jiang , Yuting Wang , Lüjin Gao , Yi Zou , Bowen Zhu , Li Chen , Xianzeng Li . Experimental Design for the Preparation of Composite Solid Electrolytes for Application in All-Solid-State Batteries: Exploration of Comprehensive Chemistry Laboratory Teaching. University Chemistry, doi: 10.3866/PKU.DXHX202308057
6. [6]
  Mingyang Men , Jinghua Wu , Gaozhan Liu , Jing Zhang , Nini Zhang , Xiayin Yao . 液相法制备硫化物固体电解质及其在全固态锂电池中的应用. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202309019
7. [7]
  Fengqiao Bi , Jun Wang , Dongmei Yang . Specialized Experimental Design for Chemistry Majors in the Context of “Dual Carbon”: Taking the Assembly and Performance Evaluation of Zinc-Air Fuel Batteries as an Example. University Chemistry, doi: 10.3866/PKU.DXHX202311069
8. [8]
  Bowen Yang , Rui Wang , Benjian Xin , Lili Liu , Zhiqiang Niu . C-SnO₂/MWCNTs Composite with Stable Conductive Network for Lithium-based Semi-Solid Flow Batteries. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202310024
9. [9]
  Aoyu Huang , Jun Xu , Yu Huang , Gui Chu , Mao Wang , Lili Wang , Yongqi Sun , Zhen Jiang , Xiaobo Zhu . Tailoring Electrode-Electrolyte Interfaces via a Simple Slurry Additive for Stable High-Voltage Lithium-Ion Batteries. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202408007
10. [10]
  Qinjin DAI , Shan FAN , Pengyang FAN , Xiaoying ZHENG , Wei DONG , Mengxue WANG , Yong ZHANG . Performance of oxygen vacancy-rich V-doped MnO₂ for high-performance aqueous zinc ion battery. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240326
11. [11]
  Yuyao Wang , Zhitao Cao , Zeyu Du , Xinxin Cao , Shuquan Liang . Research Progress of Iron-based Polyanionic Cathode Materials for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202406014
12. [12]
  Pengyang FAN , Shan FAN , Qinjin DAI , Xiaoying ZHENG , Wei DONG , Mengxue WANG , Xiaoxiao HUANG , Yong ZHANG . Preparation and performance of rich 1T-MoS₂ nanosheets for high-performance aqueous zinc ion battery cathode materials. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240339
13. [13]
  Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202310034
14. [14]
  Yifeng Xu , Jiquan Liu , Bin Cui , Yan Li , Gang Xie , Ying Yang . “Xiao Li’s School Adventures: The Working Principles and Safety Risks of Lithium-ion Batteries”. University Chemistry, doi: 10.12461/PKU.DXHX202404009
15. [15]
  Yu Guo , Zhiwei Huang , Yuqing Hu , Junzhe Li , Jie Xu . 钠离子电池中铁基异质结构负极材料的最新研究进展. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202311015
16. [16]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240149
17. [17]
  Siyu Zhang , Kunhong Gu , Bing'an Lu , Junwei Han , Jiang Zhou . Hydrometallurgical Processes on Recycling of Spent Lithium-lon Battery Cathode: Advances and Applications in Sustainable Technologies. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202309028
18. [18]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202311030
19. [19]
  Jiaxuan Zuo , Kun Zhang , Jing Wang , Xifei Li . 锂离子电池Ni-Co-Mn基正极材料前驱体的形核调控及机制. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202404042
20. [20]
  Xiaotian ZHU , Fangding HUANG , Wenchang ZHU , Jianqing ZHAO . Layered oxide cathode for sodium-ion batteries: Surface and interface modification and suppressed gas generation effect. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240260

Get Citation

PDF

XML

Metrics

PDF Downloads(506)
Abstract views(2042)
HTML views(56)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Ionic Conduction in Sn0.9Mg0.1P2O7 at Intermediate Temperatures

Metrics

通讯作者: 陈斌, bchen63@163.com

Ionic Conduction in Sn_0.9Mg_0.1P₂O₇ at Intermediate Temperatures