Citation: CAO Chun-Hui, LIN Rui, ZHAO Tian-Tian, HUANG Zhen, MA Jian-Xin. Preparation and Characterization of Core-Shell Co@Pt/C Catalysts for Fuel Cell[J]. Acta Physico-Chimica Sinica, ;2013, 29(01): 95-101. doi: 10.3866/PKU.WHXB201209272 shu

Preparation and Characterization of Core-Shell Co@Pt/C Catalysts for Fuel Cell

CAO Chun-Hui ^1,2 ,
LIN Rui ^1,2, ,
ZHAO Tian-Tian ^1,2 ,
HUANG Zhen ^1,2 ,
MA Jian-Xin ^1,2,

1.
1 Clean Energy Automotive Engineering Center, Tongji University, Shanghai 201804, P. R. China;
2 School of Automotive Studies, Tongji University, Shanghai 201804, P. R. China

Received Date: 11 July 2012
Available Online: 27 September 2012
Fund Project: 国家自然科学基金(21276199) (21276199)同济大学青年优秀人才基金(2006KJ022) (2006KJ022)上海市重点学科建设项目(B303) (B303)(B08019)资助 (B08019)

Co@Pt/C core-shell catalysts have been synthesized by a two-step chemical reduction method, followed by heat treatment in a H₂ and N₂ mixture. High resolution transmission electron microscopy (HR-TEM) and X-ray photoelectron spectroscopy (XPS) techniques were used to characterize the catalyst microstructure and morphology. The results indicate that the core-shell structure of Co rich in core and Pt rich in shell is formed and the nano-particles are highly dispersed on the surface of the carbon support. Heat treatment affects the structure and morphology of the catalysts. The electrocatalytic performance, kinetic characteristics of O₂ reduction reaction (ORR), and durability of the catalysts were measured by cyclic voltammetry (CV) and linear sweep voltammetry (LSV) techniques. It was found that the formation of the core-shell structure is favorable for improving the performance and utilization of Pt. The Co@Pt/C catalyst mechanism proceeds by an approximately four-electron pathway in acid solution, through which molecular oxygen is directly reduced to water. Compared with alloy catalysts, the formation of the core-shell structure obviously improves the catalyst durability.
- Fuel cell,
- Core-shell structure Co@Pt/C catalyst,
- Electrochemical performance,
- Reaction kinetic,
- Durability
1. [1]
  
  (1) Wang, Y.; Chen, K. S.; Mishler, J.; Cho, S. C.; Adroher, X. C.Appl. Energy 2011, 88, 981. doi: 10.1016/j.apenergy.2010.09.030
2. [2]
  (2) Wee, J. H.; Lee, K. Y.; Kim, S. H. J. Power Sources 2007, 165,667. doi: 10.1016/j.jpowsour.2006.12.051
3. [3]
  (3) Zhang, H. Y.; Cao, C. H.; Zhao, J.; Lin, R.; Ma, J. X. Chin. J. Catal. 2012, 33, 229. [张海艳, 曹春晖, 赵健, 林瑞, 马建新. 催化学报, 2012, 33, 229.]
4. [4]
  (4) Carrette, L.; Friedrich, K. A.; Stimming, U. Fuel Cells 2001, 1,15.
5. [5]
  (5) Zhang, Z. L.; Yuan, J. N.; Sun, Y. P.; Liu, S. B.; Duan, D. H.;Hao, X. G. Chin. J. Inorg. Chem. 2011, 27, 2413. [张忠林,员娟宁, 孙彦平, 刘世斌, 段东红, 郝晓刚. 无机化学学报,2011, 27, 2413.]
6. [6]
  (6) Gao, H. L.; Liao, S. J.; Zeng, J. H.; Liang, Z. X.; Xie, Y. C. Acta Phys. -Chim. Sin. 2010, 26, 3193. [高海丽, 廖世军, 曾建皇,梁振兴, 谢义淳. 物理化学学报, 2010, 26, 3193.] doi: 10.3866/PKU.WHXB20101214
7. [7]
  (7) Wang, G. X.;Wu, H. M.;Wexler, D.; Liu, H. K.; Savado , O.J. Alloy. Compd. 2010, 503, L1.
8. [8]
  (8) Zhu, H.; Li, X.W.;Wang, F. H. Int. J. Hydrog. Energy 2011, 36,9151. doi: 10.1016/j.ijhydene.2011.04.224
9. [9]
  (9) Kristian, N.; Yu, Y. L.; Lee, J. M.; Liu, X.W.;Wang, X.Electrochim. Acta 2010, 56, 1000. doi: 10.1016/j.electacta.2010.09.073
10. [10]
  (10) Choi, I.; Ahn, S. H.; Kim, J. J.; Kwon, O. J. Appl. Catal. B: Environ. 2011, 102, 608. doi: 10.1016/j.apcatb.2010.12.047
11. [11]
  (11) Dang, D.; Gao, H. L.; Peng, L. J.; Su, Y. L.; Liao, S. J.;Wang, Y.Acta Phys. -Chim. Sin. 2011, 27, 2379. [党岱, 高海丽, 彭良进, 苏允兰, 廖世军, 王晔. 物理化学学报, 2011, 27, 2379.]doi: 10.3866/PKU.WHXB20110922
12. [12]
  (12) Sun, D.; He, J. P.; Zhou, J. H.;Wang, T.; Di, Z. Y.; Ding, X. C.Acta Phys. -Chim. Sin. 2010, 26, 1219. [孙盾, 何建平, 周建华, 王涛, 狄志勇, 丁晓春. 物理化学学报, 2010, 26, 1219.]doi: 10.3866/PKU.WHXB20100507
13. [13]
  (13) Wu, H. M.;Wexler, D.;Wang, G. X.; Liu, H. K. J. Solid State Electrochem. 2012, 16, 1105. doi: 10.1007/s10008-011-1486-5
14. [14]
  (14) Lee, M. H.;Wang, P. S.; Do, J. S. J. Solid State Electrochem.2008, 12, 879. doi: 10.1007/s10008-007-0477-z
15. [15]
  (15) Liu, S. B.; Yuan, J. N.; Zhang, Z. L.; Duan, D. H.; Li, Y. B.;Hao, X. G. Chin. J. Inorg. Chem. 2010, 26, 1171. [刘世斌, 员娟宁, 张忠林, 段东红, 李一兵, 郝晓刚. 无机化学学报, 2010,26, 1171.]
16. [16]
  (16) Ryan, O'H.; Che, S. Y.; Whitney, C.; Fritz, B. P. Fuel Cell Fundamentals; Publishing House of Electronics Industry:Beijing, 2007; p 196; translated byWang, X. H., Huang, H.[Ryan, O'H., 车硕源, Whitney, C., Fritz, B. P. 燃料电池基础.王晓红, 黄宏, 译. 北京: 电子工业出版社, 2007: 196.]
17. [17]
  (17) Moulder, J. F.; Stickle,W. F.; Sobol, P. E.; Bomben, K. D.Handbook of X-ray Photo-electron Spectroscopy; Perkin-ElmerCorporation: Minnesota, 1992; pp 186-187.
18. [18]
  (18) Santia , E. I.; Varanda, L. C.; Villullas, M. J. Phys. Chem. C2007, 111, 3146. doi: 10.1021/jp0670081
19. [19]
  (19) Kiros, Y. J. Electrochem. Soc. 1996, 143, 2152. doi: 10.1149/1.1836974
20. [20]
  (20) Xiong, L.; Manthiram, A. J. Mater. Chem. 2004, 14, 1454. doi: 10.1039/b400968c
21. [21]
  (21) Bard, A. J.; Faulkner, L. R. Electrochemical Methods, 2nd ed.;Wiley & Sons: New York, 2001; pp 331-332.
22. [22]
  (22) Duong, H. T.; Rigsby, M. A.; Zhou,W. P.;Wieckowski, A.J. Phys. Chem. C 2007, 111, 13460. doi: 10.1021/jp072586i
1. [1]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
2. [2]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
3. [3]
  Kun Xu , Xinxin Song , Zhilei Yin , Jian Yang , Qisheng Song . Comprehensive Experimental Design of Preferential Orientation of Zinc Metal by Heat Treatment for Enhanced Electrochemical Performance. University Chemistry, 2024, 39(4): 192-197. doi: 10.3866/PKU.DXHX202309050
4. [4]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
5. [5]
  Fengqiao Bi , Jun Wang , Dongmei Yang . Specialized Experimental Design for Chemistry Majors in the Context of “Dual Carbon”: Taking the Assembly and Performance Evaluation of Zinc-Air Fuel Batteries as an Example. University Chemistry, 2024, 39(4): 198-205. doi: 10.3866/PKU.DXHX202311069
6. [6]
  Yeyun Zhang , Ling Fan , Yanmei Wang , Zhenfeng Shang . Development and Application of Kinetic Reaction Flasks in Physical Chemistry Experimental Teaching. University Chemistry, 2024, 39(4): 100-106. doi: 10.3866/PKU.DXHX202308044
7. [7]
  Yan Li , Xinze Wang , Xue Yao , Shouyun Yu . Kinetic Resolution Enabled by Photoexcited Chiral Copper Complex-Mediated Alkene E→Z Isomerization: A Comprehensive Chemistry Experiment for Undergraduate Students. University Chemistry, 2024, 39(5): 1-10. doi: 10.3866/PKU.DXHX202309053
8. [8]
  Jinfu Ma , Hui Lu , Jiandong Wu , Zhongli Zou . Teaching Design of Electrochemical Principles Course Based on “Cognitive Laws”: Kinetics of Electron Transfer Steps. University Chemistry, 2024, 39(3): 174-177. doi: 10.3866/PKU.DXHX202309052
9. [9]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
10. [10]
  Dexin Tan , Limin Liang , Baoyi Lv , Huiwen Guan , Haicheng Chen , Yanli Wang . Exploring Reverse Teaching Practices in Physical Chemistry Experiment Courses: A Case Study on Chemical Reaction Kinetics. University Chemistry, 2024, 39(11): 79-86. doi: 10.12461/PKU.DXHX202403048
11. [11]
  Xuzhen Wang , Xinkui Wang , Dongxu Tian , Wei Liu . Enhancing the Comprehensive Quality and Innovation Abilities of Graduate Students through a “Student-Centered, Dual Integration and Dual Drive” Teaching Model: A Case Study in the Course of Chemical Reaction Kinetics. University Chemistry, 2024, 39(6): 160-165. doi: 10.3866/PKU.DXHX202401074
12. [12]
  Yiying Yang , Dongju Zhang . Elucidating the Concepts of Thermodynamic Control and Kinetic Control in Chemical Reactions through Theoretical Chemistry Calculations: A Computational Chemistry Experiment on the Diels-Alder Reaction. University Chemistry, 2024, 39(3): 327-335. doi: 10.3866/PKU.DXHX202309074
13. [13]
  Hongyi LI , Aimin WU , Liuyang ZHAO , Xinpeng LIU , Fengqin CHEN , Aikui LI , Hao HUANG . Effect of Y(PO₃)₃ double-coating modification on the electrochemical properties of Li[Ni_0.8Co_0.15Al_0.05]O₂. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1320-1328. doi: 10.11862/CJIC.20230480
14. [14]
  Yue Wu , Jun Li , Bo Zhang , Yan Yang , Haibo Li , Xian-Xi Zhang . Research on Kinetic and Thermodynamic Transformations of Organic-Inorganic Hybrid Materials for Fluorescent Anti-Counterfeiting Application information: Introducing a Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(6): 390-399. doi: 10.3866/PKU.DXHX202403028
15. [15]
  You Wu , Chang Cheng , Kezhen Qi , Bei Cheng , Jianjun Zhang , Jiaguo Yu , Liuyang Zhang . ZnO/D-A共轭聚合物S型异质结高效光催化产H₂O₂及其电荷转移动力学研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406027-. doi: 10.3866/PKU.WHXB202406027
16. [16]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
17. [17]
  Qin ZHU , Jiao MA , Zhihui QIAN , Yuxu LUO , Yujiao GUO , Mingwu XIANG , Xiaofang LIU , Ping NING , Junming GUO . Morphological evolution and electrochemical properties of cathode material LiAl_0.08Mn_1.92O₄ single crystal particles. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1549-1562. doi: 10.11862/CJIC.20240022
18. [18]
  Yong Zhou , Jia Guo , Yun Xiong , Luying He , Hui Li . Comprehensive Teaching Experiment on Electrochemical Corrosion in Galvanic Cell for Chemical Safety and Environmental Protection Course. University Chemistry, 2024, 39(7): 330-336. doi: 10.3866/PKU.DXHX202310109
19. [19]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
20. [20]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252

Get Citation

PDF

XML

Metrics

PDF Downloads(1165)
Abstract views(2115)
HTML views(9)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142