Citation: WANG Wan-Li, MA Zi-Feng. Synthesis and Characteristics of Pt/graphene by Co-Reduction Method for Oxygen Reduction Reactions[J]. Acta Physico-Chimica Sinica doi: 10.3866/PKU.WHXB201209252 shu

Synthesis and Characteristics of Pt/graphene by Co-Reduction Method for Oxygen Reduction Reactions

WANG Wan-Li ,
MA Zi-Feng

1.
Department of Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, P.R. China

Received Date: 5 July 2012
Available Online: 25 September 2012
Fund Project: 国家自然科学基金(21073120, 21176155) (21073120, 21176155)上海市自然科学基金(10JC1406900)资助项目 (10JC1406900)

40% (w) Pt/graphene composites were prepared by sodium borohydride chemical coreduction, and were subsequently used as an electrocatalyst for oxygen reduction reactions. The electrocatalytic activity and stability was evaluated by cyclic voltammetry. The results indicated that the initial activity of Pt/graphene was lower than that of Pt/C due to the oxygen diffusion inhibition; however, the Pt/graphene showed superior durability characteristics. Degradation tests showed a 50% degradation of Pt/ graphene, which was substantially less than that of Pt/C (79%). X-ray diffraction and transmission electron microscope results showed that the composite formed strong interactions between the platinum nanoparticles and the graphene supports. The graphene supports may also prevent the graphene sheets from folding or re-stacking, which would hinder platinum nanoparticles' aggregation. The performance of a single cell was also tested, confirming an improvement in durability.
- Graphene,
- Co-reduction method,
- Electrocatalyst,
- Oxygen reduction reaction,
- Proton exchange membrane fuel cell
1. [1]
  
  (1) Wang, Y.; Shi, Z.; Huang, Y.; Ma, Y.;Wang, C.; Chen, M.;Chen, Y. The Journal of Physical Chemistry C 2009, 113 (30),13103. doi: 10.1021/jp902214f
2. [2]
  (2) Lu, X. J.; Dou, H.; Yang, S. D.; Hao, L.; Zhang, F.; Zhang, X.G. Acta Phys. -Chim. Sin. 2011, 27 (10), 2333. [卢向军,窦辉, 杨苏东, 郝亮, 张方, 张校刚. 物理化学学报,2011, 27 (10), 2333.] doi: 10.3866/PKU.WHXB20111022
3. [3]
  (3) Guo, P.; Song, H.; Chen, X. Electrochem. Commun. 2009, 11 (6), 1320. doi: 10.1016/j.elecom.2009.04.036
4. [4]
  (4) Liang, M.; Zhi, L. J. Mater. Chem. 2009, 19 (33), 5871. doi: 10.1039/b901551e
5. [5]
  (5) Xu, K.; Shen, L. F.; Mi, C. H.; Zhang, X. G. Acta Phys. -Chim. Sin. 2012, 28 (1), 105. [徐科, 申来法, 米常焕, 张校刚.物理化学学报, 2012, 28 (1), 105.] doi: 10.3866/PKU.WHXB201228105
6. [6]
  (6) Yang, X.W.; He, Y. S.; Liao, X. Z.; Ma, Z. F. Acta Phys. -Chim. Sin. 2011, 27 (11), 2583. [杨晓伟, 何雨石, 廖小珍, 马紫峰.物理化学学报, 2011, 27 (11), 2583.] doi: 10.3866/PKU.WHXB20111123
7. [7]
  (7) Li, Y.; Tang, L.; Li, J. Electrochem. Commun. 2009, 11 (4), 846.doi: 10.1016/j.elecom.2009.02.009
8. [8]
  (8) Si, Y.; Samulski, E. T. Chem. Mater. 2008, 20 (21), 6792. doi: 10.1021/cm801356a
9. [9]
  (9) Li, Y. X.;Wei, Z. D.; Zhao, Q. L.; Ding,W.; Zhang, Q.; Chen, S.G. Acta Phys. -Chim. Sin. 2011, 27 (4), 858. [李云霞, 魏子栋,赵巧玲, 丁炜, 张骞, 陈四国. 物理化学学报, 2011, 27 (4),858.] doi: 10.3866/PKU.WHXB20110411
10. [10]
  (10) Castro Neto, A. H.; Kotov, V. N.; Nilsson, J.; Pereira, V. M.;Peres, N. M. R.; Uchoa, B. Solid State Commun. 2009, 149 (27-28), 1094. doi: 10.1016/j.ssc.2009.02.040
11. [11]
  (11) Geim, A. K. Science 2009, 324 (5934), 1530. doi: 10.1126/science.1158877
12. [12]
  (12) Neto, A. H. C.; Guinea, F.; Peres, N. M. R.; Novoselov, K. S.;Geim, A. K. Reviews of Modern Physics 2009, 81 (1), 109. doi: 10.1103/RevModPhys.81.109
13. [13]
  (13) Rao, C. N. R.; Sood, A. K.; Subrahmanyam, K. S.; vindaraj,A. Angewandte Chemie-International Edition 2009, 48 (42),7752. doi: 10.1002/anie.v48:42
14. [14]
  (14) Barbir, F. PEM Fuel Cells —— Theory and Practice; ElsevierAcademic Press: Burlington, 2005.
15. [15]
  (15) Baughman, R. H.; Zakhidov, A. A.; De Heer,W. A. Science2002, 297 (5582), 787. doi: 10.1126/science.1060928
16. [16]
  (16) Chen, H.; Müller, M. B.; Gilmore, K. J.;Wallace, G. G.; Li, D.Adv. Mater. 2008, 20 (18), 3557. doi: 10.1002/adma.200800757
17. [17]
  (17) Kou, R.; Shao, Y.;Wang, D.; Engelhard, M. H.; Kwak, J. H.;Wang, J.; Viswanathan, V. V.;Wang, C.; Lin, Y.;Wang, Y.;Aksay, I. A.; Liu, J. Electrochem. Commun. 2009, 11 (5), 954.doi: 10.1016/j.elecom.2009.02.033
18. [18]
  (18) Huffman, G. P.; Shah, N.;Wang, Y.; Huggins, F. E. Prepr. Pap. -Am. Chem. Soc., Div. Fuel Chem. 2004, 49 (2), 731.
19. [19]
  (19) Kovtyukhova, N. I. Chem. Mater. 1999, 11 (3), 771. doi: 10.1021/cm981085u
20. [20]
  (20) Fournier, J.; Faubert, G.; Tilquin, J. Y.; Cote, R.; Guay, D.;Dodelet, J. P. J. Electrochem. Soc. 1997, 144 (1), 145. doi: 10.1149/1.1837377
21. [21]
  (21) Gasteiger, H. A.; Panels, J. E.; Yan, S. G. J. Power Sources2004, 127 (1-2), 162. doi: 10.1016/j.jpowsour.2003.09.013
22. [22]
  (22) Carmo, M.; Paganin, V. A.; Rosolen, J. M.; nzalez, E. R.J. Power Sources 2005, 142 (1-2), 169. doi: 10.1016/j.jpowsour.2004.10.023
23. [23]
  (23) Schniepp, H. C.; Li, J. L.; McAllister, M. J.; Sai, H.; Herrera-Alonso, M.; Adamson, D. H.; Prud'homme, R. K.; Car, R.;Saville, D. A.; Aksay, I. A. The Journal of Physical Chemistry B2006, 110 (17), 8535. doi: 10.1021/jp060936f
24. [24]
  (24) McAllister, M. J.; Li, J. L.; Adamson, D. H.; Schniepp, H. C.;Abdala, A. A.; Liu, J.; Herrera-Alonso, M.; Milius, D. L.; Car,R.; Prud'homme, R. K.; Aksay, I. A. Chem. Mater. 2007, 19 (18), 4396. doi: 10.1021/cm0630800
25. [25]
  (25) Climent, V.; Markovi?, N. M.; Ross, P. N. The Journal of Physical Chemistry B 2000, 104 (14), 3116.
26. [26]
  (26) Takenaka, S.; Matsumori, H.; Matsune, H.; Tanabe, E.; Kishida,M. J. Electrochem. Soc. 2008, 155 (9), B929.
27. [27]
  (27) Cho, Y. H.; Park, H. S.; Cho, Y. H.; Jung, D. S.; Park, H. Y.;Sung, Y. E. J. Power Sources 2007, 172 (1), 89. doi: 10.1016/j.jpowsour.2007.01.067
28. [28]
  (28) Wang, C.;Waje, M.;Wang, X.; Tang, J. M.; Haddon, R. C.; Yan,Y. Nano Lett. 2003, 4 (2), 345.
29. [29]
  (29) Chen, Z.;Waje, M.; Li,W.; Yan, Y. Angew. Chem. 2007, 119 (22), 4138. doi: 10.1002/ange.200700894
30. [30]
  (30) Rochefort, A.; Yang, D. Q.; Sacher, E. Carbon 2009, 47 (9),2233. doi: 10.1016/j.carbon.2009.04.013
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