Citation: FAN Cheng-Wei, ZHANG Xin, CHEN Sheng, WANG Hai-Fang, CAO Ao-Neng. Solution-Processable, Highly Conductive, Permanently Rippled Graphene Sheets[J]. Acta Physico-Chimica Sinica, ;2012, 28(10): 2465-2470. doi: 10.3866/PKU.WHXB201209103 shu

Solution-Processable, Highly Conductive, Permanently Rippled Graphene Sheets

1.
Institute of Nanochemistry and Nanobiology, Shanghai University, Shanghai 200444, P. R. China

Received Date: 23 July 2012
Available Online: 10 September 2012
Fund Project: 国家自然科学基金(21073117) (21073117) 国家重点基础研究发展规划项目(973)(2009CB930200, 2011CB933402) (973)(2009CB930200, 2011CB933402)上海市重点学科(S30109)资助 (S30109)

The single atom thick sp² carbon structure of graphene gives rise to its unique properties and potential applications. However, one serious obstacle for its application is that graphene is prone to aggregate in suspension and gradually stack into graphite. Here, we report a novel approach to solve this problem. The basic idea is to introduce sp² carbon nano-islands on the graphene sheets that act as permanent ripples to prevent the stacking and graphitization of graphene and make it easy to re-suspend. Unlike most functionalization methods, this approach avoids the introduction of heteroatoms. Thus, it does not deteriorate the structure and change the properties of graphene. The carbon-rippled graphene has a remarkable electronic conductivity of ~65000 S·m^-1, and can be readily suspended in solvent.
- Graphene,
- Ripple,
- Carbon nanocage,
- Expandable graphite,
- Conductivity,
- Solution stability
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