Citation:
FAN Cheng-Wei, ZHANG Xin, CHEN Sheng, WANG Hai-Fang, CAO Ao-Neng. Solution-Processable, Highly Conductive, Permanently Rippled Graphene Sheets[J]. Acta Physico-Chimica Sinica,
;2012, 28(10): 2465-2470.
doi:
10.3866/PKU.WHXB201209103
-
The single atom thick sp2 carbon structure of graphene gives rise to its unique properties and potential applications. However, one serious obstacle for its application is that graphene is prone to aggregate in suspension and gradually stack into graphite. Here, we report a novel approach to solve this problem. The basic idea is to introduce sp2 carbon nano-islands on the graphene sheets that act as permanent ripples to prevent the stacking and graphitization of graphene and make it easy to re-suspend. Unlike most functionalization methods, this approach avoids the introduction of heteroatoms. Thus, it does not deteriorate the structure and change the properties of graphene. The carbon-rippled graphene has a remarkable electronic conductivity of ~65000 S·m-1, and can be readily suspended in solvent.
-
Keywords:
-
Graphene
, - Ripple,
- Carbon nanocage,
- Expandable graphite,
- Conductivity,
- Solution stability
-
-
-
-
[1]
(1) Mermin, N. D. Phys. Rev. 1968, 176, 250. doi: 10.1103/PhysRev.176.250
-
[2]
(2) Meyer, J. C.; Geim, A. K.; Katsnelson, M. I.; Novoselov, K. S.;Booth, T. J.; Roth, S. Nature 2007, 446, 60. doi: 10.1038/nature05545
-
[3]
(3) Novoselov, K. S.; Jiang, D.; Schedin, F.; Booth, T. J.;Khotkevich, V. V.; Morozov, S. V.; Geim, A. K. Proc. Natl. Acad. Sci. U. S. A. 2005, 102, 10451. doi: 10.1073/pnas.0502848102
-
[4]
(4) Fasolino, A.; Los, J. H.; Katsnelson, M. I. Nat. Mater. 2007, 6,858. doi: 10.1038/nmat2011
-
[5]
(5) Geim, A. K.; Novoselov, K. S. Nat. Mater. 2007, 6, 183. doi: 10.1038/nmat1849
-
[6]
(6) Huang, X.; Yin, Z. Y.;Wu, S. X.; Qi, X. Y.; He, Q. Y.; Zhang, Q.C.; Yan, Q. Y.; Boey, F.; Zhang, H. Small 2011, 7, 1876. doi: 10.1002/smll.201002009
-
[7]
(7) Geim, A. K. Science 2009, 324, 1530. doi: 10.1126/science.1158877
-
[8]
(8) Jiang, H. J. Small 2011, 7, 2413.
-
[9]
(9) Huang, X.; Qi, X. Y.; Boey, F.; Zhang, H. Chem. Soc. Rev. 2012,41, 666. doi: 10.1039/c1cs15078b
-
[10]
(10) Li, X. L.; Zhang, G. Y.; Bai, X. D.; Sun, X. M.;Wang, X. R.;Wang, E. G.; Dai, H. J. Nat. Nanotechnol. 2008, 3, 538. doi: 10.1038/nnano.2008.210
-
[11]
(11) Liu, Z.; Fan, C.W.; Chen, L.; Cao, A. N. J. Nanosci. Nanotech.2010, 10, 7382. doi: 10.1166/jnn.2010.2780
-
[12]
(12) Hernandez, Y.; Nicolosi, V.; Lotya, M.; Blighe, F.; Sun, Z.; De,S.; Mc vern, I. T.; Holland, B.; Byrne, M.; Gunko, Y.; Boland,J.; Niraj, P.; Duesberg, G.; Krishnamurti, S.; odhue, R.;Hutchison, J.; Scardaci, V.; Ferrari, A. C.; Coleman, J. N. Nat. Nanotechnol. 2008, 3, 563.
-
[13]
(13) Eda, G.; Fanchini, G.; Chhowalla, M. Nat. Nanotechnol. 2008,3, 270. doi: 10.1038/nnano.2008.83
-
[14]
(14) Li, D.; Muller, M. B.; Gilje, S.; Kaner, R. B.;Wallace, G. G.Nat. Nanotechnol. 2008, 3, 101. doi: 10.1038/nnano.2007.451
-
[15]
(15) Cao, A. N.; Liu, Z.; Chu, S. S.;Wu, M. H.; Ye, Z. M.; Cai, Z.W.; Chang, Y. L.;Wang, S. F.; ng, Q. H.; Liu, Y. F. Adv. Mater. 2010, 22, 103. doi: 10.1002/adma.v22:1
-
[16]
(16) Qi, X. Y.; Pu, K. Y.; Zhou, X. Z.; Li, H.; Liu, B.; Boey, F.;Huang, W.; Zhang, H. Small 2010, 6, 663. doi: 10.1002/smll.v6:5
-
[17]
(17) Stankovich, S.; Dikin, D. A.; Dommett, G. H. B.; Kohlhaas, K.M.; Zimney, E. J.; Stach, E. A.; Piner, R. D.; Nguyen, S. T.;Ruoff, R. S. Nature 2006, 442, 282. doi: 10.1038/nature04969
-
[18]
(18) Choucair, M.; Thordarson, P.; Stride, J. A. Nat. Nanotechnol.2009, 4, 30. doi: 10.1038/nnano.2008.365
-
[19]
(19) Qi, X. Y.; Pu, K. Y.; Li, H.; Zhou, X. Z.;Wu, S.; Fan, Q. L.; Liu,B.; Boey, F.; Huang,W.; Zhang, H. Angew. Chem. Int. Edit.2010, 49, 9426. doi: 10.1002/anie.201004497
-
[20]
(20) Feng, X.; Hu, G.; Hu, J. Nanoscale 2011, 3, 2099. doi: 10.1039/c1nr00004g
-
[21]
(21) Dreyer, D. R.; Park, S.; Bielawski, C.W.; Ruoff, R. S. Chem. Soc. Rev. 2010, 39, 228. doi: 10.1039/b917103g
-
[22]
(22) Park, S.; An, J.; Jung, I.; Piner, R. D.; An, S. J.; Li, X. S.;Velamakanni, A.; Ruoff, R. S. Nano Lett. 2009, 9, 1593. doi: 10.1021/nl803798y
-
[23]
(23) Dikin, D. A.; Stankovich, S.; Zimney, E. J.; Piner, R. D.;Dommett, G. H. B.; Evmenenko, G.; Nguyen, S. T.; Ruoff, R. S.Nature 2007, 448, 457. doi: 10.1038/nature06016
-
[24]
(24) Zhou, X. Z.; Huang, X.; Qi, X. Y.;Wu, S. X.; Xue, C.; Boey, F.Y. C.; Yan, Q. Y.; Chen, P.; Zhang, H. J. Phys. Chem. C 2009,113, 10842. doi: 10.1021/jp903821n
-
[25]
(25) Chang, Y. L.; Chen, S.; Cao, A. N. J. Shanghai University (Natural Science) 2010, 16 (6), 577. [常艳丽, 陈胜, 曹傲能. 上海大学学报(自然科学版), 2010, 16 (6), 577.]
-
[26]
(26) Yang, S. T.; Chen, S.; Chang, Y.; Cao, A.; Liu, Y.;Wang, H.J. Colloid Interface Sci. 2011, 359, 24. doi: 10.1016/j.jcis.2011.02.064
-
[27]
(27) Yang, S. T.; Chang, Y.;Wang, H.; Liu, G.; Chen, S.;Wang, Y.;Liu, Y.; Cao, A. J. Colloid Interface Sci. 2010, 351, 122. doi: 10.1016/j.jcis.2010.07.042
-
[28]
(28) Chang, Y.; Yang, S. T.; Liu, J. H.; Dong, E.;Wang, Y.; Cao, A.;Liu, Y.;Wang, H. Toxicol Lett. 2011, 200, 201. doi: 10.1016/j.toxlet.2010.11.016
-
[29]
(29) Hao, R.; Qian,W.; Zhang, L.; Hou, Y. Chem. Commun. 2008,6576.
-
[30]
(30) Qian,W.; Cui, X.; Hao, R.; Hou, Y.; Zhang, Z. ACS Appl. Mater. Interfaces 2011, 3 (7), 2259. doi: 10.1021/am200479d
-
[31]
(31) Qian,W.; Hao, R.; Hou, Y.; Tian, Y.; Shen, C.; Gao, H.; Liang,X. Nano Res. 2009, 2, 706. doi: 10.1007/s12274-009-9074-z
-
[32]
(32) Kauzmann,W. Adv. Protein Chem. 1959, 14, 1. doi: 10.1016/S0065-3233(08)60608-7
-
[33]
(33) Dill, K. A. Biochemistry 1990, 29, 7133. doi: 10.1021/bi00483a001
-
[34]
(34) Jung, I.; Dikin, D. A.; Piner, R. D.; Ruoff, R. S. Nano Lett.2008, 8, 4283. doi: 10.1021/nl8019938
-
[35]
(35) mez-Navarro, C.;Weitz, R. T.; Bittner, A. M.; Scolari, M.;Mews, A.; Burghard, M.; Kern, K. Nano Lett. 2007, 7, 3499.doi: 10.1021/nl072090c
-
[36]
(36) Si, Y. C.; Samulski, E. T. Nano Lett. 2008, 8, 1679. doi: 10.1021/nl080604h
-
[1]
-
-
-
[1]
Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
-
[2]
Xiaofang DONG , Yue YANG , Shen WANG , Xiaofang HAO , Yuxia WANG , Peng CHENG . Research progress of conductive metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 14-34. doi: 10.11862/CJIC.20240388
-
[3]
Yunting Shang , Yue Dai , Jianxin Zhang , Nan Zhu , Yan Su . Something about RGO (Reduced Graphene Oxide). University Chemistry, 2024, 39(9): 273-278. doi: 10.3866/PKU.DXHX202306050
-
[4]
Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO2-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
-
[5]
Zhenlin Zhou , Siyuan Chen , Yi Liu , Chengguo Hu , Faqiong Zhao . A New Program of Voltammetry Experiment Teaching Based on Laser-Scribed Graphene Electrode. University Chemistry, 2024, 39(2): 358-370. doi: 10.3866/PKU.DXHX202308049
-
[6]
Tianqi Bai , Kun Huang , Fachen Liu , Ruochen Shi , Wencai Ren , Songfeng Pei , Peng Gao , Zhongfan Liu . 石墨烯厚膜热扩散系数与微观结构的关系. Acta Physico-Chimica Sinica, 2025, 41(3): 2404024-. doi: 10.3866/PKU.WHXB202404024
-
[7]
Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099
-
[8]
Hao BAI , Weizhi JI , Jinyan CHEN , Hongji LI , Mingji LI . Preparation of Cu2O/Cu-vertical graphene microelectrode and detection of uric acid/electroencephalogram. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1309-1319. doi: 10.11862/CJIC.20240001
-
[9]
Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312
-
[10]
Baitong Wei , Jinxin Guo , Xigong Liu , Rongxiu Zhu , Lei Liu . Theoretical Study on the Structure, Stability of Hydrocarbon Free Radicals and Selectivity of Alkane Chlorination Reaction. University Chemistry, 2025, 40(3): 402-407. doi: 10.12461/PKU.DXHX202406003
-
[11]
Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
-
[12]
Shitao Fu , Jianming Zhang , Cancan Cao , Zhihui Wang , Chaoran Qin , Jian Zhang , Hui Xiong . Study on the Stability of Purple Cabbage Pigment. University Chemistry, 2024, 39(4): 367-372. doi: 10.3866/PKU.DXHX202401059
-
[13]
Jie XIE , Hongnan XU , Jianfeng LIAO , Ruoyu CHEN , Lin SUN , Zhong JIN . Nitrogen-doped 3D graphene-carbon nanotube network for efficient lithium storage. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1840-1849. doi: 10.11862/CJIC.20240216
-
[14]
Tian TIAN , Meng ZHOU , Jiale WEI , Yize LIU , Yifan MO , Yuhan YE , Wenzhi JIA , Bin HE . Ru-doped Co3O4/reduced graphene oxide: Preparation and electrocatalytic oxygen evolution property. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 385-394. doi: 10.11862/CJIC.20240298
-
[15]
Xuyang Wang , Jiapei Zhang , Lirui Zhao , Xiaowen Xu , Guizheng Zou , Bin Zhang . Theoretical Study on the Structure and Stability of Copper-Ammonia Coordination Ions. University Chemistry, 2024, 39(3): 384-389. doi: 10.3866/PKU.DXHX202309065
-
[16]
Xiaoning TANG , Junnan LIU , Xingfu YANG , Jie LEI , Qiuyang LUO , Shu XIA , An XUE . Effect of sodium alginate-sodium carboxymethylcellulose gel layer on the stability of Zn anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1452-1460. doi: 10.11862/CJIC.20240191
-
[17]
Jiaxi Xu , Yuan Ma . Influence of Hyperconjugation on the Stability and Stable Conformation of Ethane, Hydrazine, and Hydrogen Peroxide. University Chemistry, 2024, 39(11): 374-377. doi: 10.3866/PKU.DXHX202402049
-
[18]
Jing SU , Bingrong LI , Yiyan BAI , Wenjuan JI , Haiying YANG , Zhefeng Fan . Highly sensitive electrochemical dopamine sensor based on a highly stable In-based metal-organic framework with amino-enriched pores. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1337-1346. doi: 10.11862/CJIC.20230414
-
[19]
Xuewei BA , Cheng CHENG , Huaikang ZHANG , Deqing ZHANG , Shuhua LI . Preparation and luminescent performance of Sr1-xZrSi2O7∶xDy3+ phosphor with high thermal stability. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 357-364. doi: 10.11862/CJIC.20240096
-
[20]
Renqing Lü , Shutao Wang , Fang Wang , Guoping Shen . Computational Chemistry Aided Organic Chemistry Teaching: A Case of Comparison of Basicity and Stability of Diazine Isomers. University Chemistry, 2025, 40(3): 76-82. doi: 10.12461/PKU.DXHX202404119
-
[1]
Metrics
- PDF Downloads(683)
- Abstract views(1776)
- HTML views(15)