Citation: JIN Tao, XU Di, DIAO Peng, XIANG Min. Preparation and Photoelectrocatalytic Water Oxidation Properties of FeO(OH)-TiO₂/CoPi Composite Photoanodes[J]. Acta Physico-Chimica Sinica, ;2012, 28(10): 2276-2284. doi: 10.3866/PKU.WHXB201209101 shu

Preparation and Photoelectrocatalytic Water Oxidation Properties of FeO(OH)-TiO₂/CoPi Composite Photoanodes

1.
Key Laboratory of Aerospace Science and Engineering, Department of Materials Science and Engineering School, Beihang University, Beijing 100191, P. R. China

Received Date: 4 July 2012
Available Online: 10 September 2012
Fund Project: 国家自然科学基金(20973020, 21173016) (20973020, 21173016) 高等学校博士学科点基金(20101102110002) (20101102110002) 新世纪人才支持计划(NCET-08-0034)资助项目 (NCET-08-0034)

TiO₂ nanocrystals were synthesized using a sol-gel method, and then the impregnation technique was used to modify the surface of the TiO₂ nanocrystals with FeO(OH). The optimal concentration of Fe³⁺ for the modification of the TiO₂ nanocrystals was determined by UV-Vis spectroscopy. A cobalt-phosphate (CoPi) water oxidation catalyst was electrochemically deposited onto the FeO(OH)- TiO₂ photoanodes. The resulting FeO(OH)-TiO₂/CoPi composite photoanodes were systematically characterized by transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HRTEM), X-ray diffraction (XRD), and scanning electron microscopy (SEM), and the photoelectrochemical water oxidation properties of the FeO(OH)-TiO₂/CoPi composite photoanodes were investigated in neutral conditions by electrochemical and photoelectrochemical methods. The results indicated that the TiO₂ particles were pure anatase nanocrystals, and the FeO(OH) phase on the TiO₂ surfaces was ethite. The optimal light absorption properties of the FeO(OH)-TiO₂ photoanodes were achieved when the photoanodes were prepared in the precursor solution with a Fe³⁺:TiO₂ mass ratio of 0.05%. The overpotential for oxygen evolution on the FeO(OH)-TiO₂/CoPi composite photoanodes under illumination decreased significantly compared with that obtained on the CoPi catalyst. The high oxygen evolution activity of the composite photoanodes can be attributed to modification of FeO(OH) on TiO₂ nanocrystal surfaces changing the light absorption band from the ultraviolet to the visible region and CoPi inhibited hole-electron recombination through facilitating the photon-induced hole transfer for water oxidation.
- Hydrogen ferric oxide,
- TiO₂ nanocrystal,
- Cobalt-phosphate catalyst,
- Photoelectrochemical oxygen evolution,
- Photon-induced holes
1. [1]
  
  (1) Fujishima, A.; Honda, K. Nature 1972, 238, 37. doi: 10.1038/238037a0
2. [2]
  (2) Jang, J. S.; Kim, H. G.; Joshi, U. A.; Jang, J.W.; Lee, J. S. Int. J. Hydrog. Energy 2008, 33, 5975. doi: 10.1016/j.ijhydene.2008.07.105
3. [3]
  (3) Dholam, R.; Patel, N.; Adami, M.; Miotello, A. Int. J. Hydrog. Energy 2009, 34, 5337. doi: 10.1016/j.ijhydene.2009.05.011
4. [4]
  (4) Shankar, K.; Basham, J. I.; Allam, N. K.; Varghese, O. K.; Mor,G. K.; Feng, X.; Paulose, M.; Seabold, J. A.; Choi, K. S.;Grimes, C. A. J. Phys. Chem. C 2009, 113, 6327. doi: 10.1021/jp809385x
5. [5]
  (5) Liu, F. S.; Ji, R.;Wu, M.; Sun, Y. M. Acta Phys. -Chim. Sin.2007, 23, 1899. [刘福生, 吉仁, 吴敏, 孙岳明. 物理化学学报, 2007, 23, 1899.] doi: 10.3866/PKU.WHXB20071213
6. [6]
  (6) Li, H. L. Luo,W. L.; Chen, T.; Tian,W. Y.; Sun, M.; Li, C.; Zhu,D.; Liu, R. R.; Zhao, Y. L.; Liu, C. L. Acta Phys. -Chim. Sin.2008, 24, 1383. [李海龙, 罗武林, 陈涛, 田文宇, 孙茂,黎春, 朱地, 刘冉冉, 赵宇亮, 刘春立. 物理化学学报,2008, 24, 1383.] doi: 10.3866/PKU.WHXB20080810
7. [7]
  (7) Asahi, R.; Morikawa, T.; Ohwaki, T.; Aoki, K.; Taga, Y. Science2001, 293, 269. doi: 10.1126/science.1061051
8. [8]
  (8) ng, J.; Lai, Y.; Lin, C. Electrochimica Acta 2010, 55, 4776.doi: 10.1016/j.electacta.2010.03.055
9. [9]
  (9) Fei, H.; Yang, Y.; Ro w, D. L.; Fan, X.; Oliver, S. R. J. ACS Appl. Mater. Interfaces 2010, 2, 974. doi: 10.1021/am100087b
10. [10]
  (10) Zhang, Z.; Hossain, M. F.; Takahashi, T. Int. J. Hydrog. Energy2010, 35, 8528. doi: 10.1016/j.ijhydene.2010.03.032
11. [11]
  (11) Ni, M.; Leung, M. K. H.; Leung, D. Y. C.; Sumathy, K. Renew. Sust. Energ. Rev. 2007, 11, 401. doi: 10.1016/j.rser.2005.01.009
12. [12]
  (12) Liu, M.; Qiu, X.; Miyauchi, M.; Hashimoto, K. Chem. Mater.2011, 23, 5282. doi: 10.1021/cm203025b
13. [13]
  (13) Yu, H.; Irie, H.; Shimodaira, Y.; Hosogi, Y.; Kuroda, Y.;Miyauchi, M.; Hashimoto, K. J. Phys. Chem. C 2010, 114,16481. doi: 10.1021/jp1071956
14. [14]
  (14) Irie, H.; Shibanuma, T.; Kamiya, K.; Miura, S.; Yokoyama, T.;Hashimoto, K. App. Catal. B: Environ. 2010, 96, 142.
15. [15]
  (15) Irie, H.; Kamiya, K.; Shibanuma, T.; Miura, S.; Tryk, D. A.;Yokoyama, T.; Hashimoto, K. J. Phys. Chem. C 2009, 113,10761. doi: 10.1021/jp903063z
16. [16]
  (16) Nakamura, R.; Okamoto, A.; Osawa, H.; Irie, H.; Hashimoto, K.J. Am. Chem. Soc. 2007, 129, 9596. doi: 10.1021/ja073668n
17. [17]
  (17) Luo, D. C;. Zhang, L. L.; Long, H. J.; Chen, Y. M.; Cao, Y. A.Acta Phys. -Chim. Sin. 2008, 24, 1095. [罗大超, 张兰兰, 龙绘锦, 陈咏梅, 曹亚安. 物理化学学报, 2008, 24, 1095.] doi: 10.3866/PKU.WHXB20080632
18. [18]
  (18) Kanan, M.W.; Nocera, D. G. Science 2008, 321, 1072. doi: 10.1126/science.1162018
19. [19]
  (19) Surendranath, Y.; Kanan, M.W.; Nocera, D. G. J. Am. Chem. Soc. 2010, 132, 16501. doi: 10.1021/ja106102b
20. [20]
  (20) Gerken, J. B.; McAlpin, J. G.; Chen, J. Y. C.; Rigsby, M. L.;Casey,W. H.; Britt, R. D.; Stahl, S. S. J. Am. Chem. Soc. 2011,133, 14431. doi: 10.1021/ja205647m
21. [21]
  (21) Steinmiller, E. M. P.; Choi, K. S. Proc. Natl. Acad. Sci. U. S. A.2009, 106, 20633. doi: 10.1073/pnas.0910203106
22. [22]
  (22) Barroso, M.; Cowan, A. J.; Pendlebury, S. R.; Grätzel, M.; Klug,D. R.; Durrant, J. R. J. Am. Chem. Soc. 2011, 133, 14868. doi: 10.1021/ja205325v
23. [23]
  (23) Zhong, D. K.; Gamelin, D. R. J. Am. Chem. Soc. 2010, 132,4202. doi: 10.1021/ja908730h
24. [24]
  (24) Zhong, D. K.; Sun, J.; Inumaru, H.; Gamelin, D. R. J. Am. Chem. Soc. 2009, 131, 6086. doi: 10.1021/ja9016478
25. [25]
  (25) Abdi, F. F.; van de Krol, R. J. Phys. Chem. C 2012, 116, 9398.
26. [26]
  (26) Zhong, D. K.; Choi, S.; Gamelin, D. R. J. Am. Chem. Soc. 2011,133, 18370. doi: 10.1021/ja207348x
27. [27]
  (27) Jeon, T. H.; Choi,W.; Park, H. Phys. Chem. Chem. Phys. 2011,13, 21392.
28. [28]
  (28) Seabold, J. A.; Choi, K. S. Chem. Mater. 2011, 23, 1105. doi: 10.1021/cm1019469
29. [29]
  (29) Sugimoto, T.; Zhou, X.; Muramatsu, A. J. Colloid Interface Sci.2003, 259, 43. doi: 10.1016/S0021-9797(03)00036-5
30. [30]
  (30) Sugimoto, T.; Zhou, X.; Muramatsu, A. J. Colloid Interface Sci.2003, 259, 53. doi: 10.1016/S0021-9797(03)00035-3
31. [31]
  (31) Zhong, D. K.; Cornuz, M.; Sivula, K.; Grätzel, M.; Gamelin, D.R. Energy & Environmental Science 2011, 4, 1759. doi: 10.1039/c1ee01034d
32. [32]
  (32) Chen, Y.; He, X.; Zhao, X.; Yuan, Q.; Gu, X. J. Colloid Interface Sci. 2007, 310, 171. doi: 10.1016/j.jcis.2007.01.046
33. [33]
  (33) Klahr, B.; Gimenez, S.; Fabregat-Santia , F.; Hamann, T.;Bisquert, J. J. Am. Chem. Soc. 2012, 134, 4294. doi: 10.1021/ja210755h
1. [1]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
2. [2]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
3. [3]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
4. [4]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
5. [5]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
6. [6]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
7. [7]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
8. [8]
  Jiapei Zou , Junyang Zhang , Xuming Wu , Cong Wei , Simin Fang , Yuxi Wang . A Comprehensive Experiment Based on Electrocatalytic Nitrate Reduction into Ammonia: Synthesis, Characterization, Performance Exploration, and Applicable Design of Copper-based Catalysts. University Chemistry, 2024, 39(6): 373-382. doi: 10.3866/PKU.DXHX202312081
9. [9]
  Caixia Lin , Zhaojiang Shi , Yi Yu , Jianfeng Yan , Keyin Ye , Yaofeng Yuan . Ideological and Political Design for the Electrochemical Synthesis of Benzoxathiazine Dioxide Experiment. University Chemistry, 2024, 39(2): 61-66. doi: 10.3866/PKU.DXHX202309005
10. [10]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
11. [11]
  Meng Lin , Hanrui Chen , Congcong Xu . Preparation and Study of Photo-Enhanced Electrocatalytic Oxygen Evolution Performance of ZIF-67/Copper(I) Oxide Composite: A Recommended Comprehensive Physical Chemistry Experiment. University Chemistry, 2024, 39(4): 163-168. doi: 10.3866/PKU.DXHX202308117
12. [12]
  Yongmei Liu , Lisen Sun , Zhen Huang , Tao Tu . Curriculum-Based Ideological and Political Design for the Experiment of Methanol Oxidation to Formaldehyde Catalyzed by Electrolytic Silver. University Chemistry, 2024, 39(2): 67-71. doi: 10.3866/PKU.DXHX202308020
13. [13]
  Jiaxin Su , Jiaqi Zhang , Shuming Chai , Yankun Wang , Sibo Wang , Yuanxing Fang . Optimizing Poly(heptazine imide) Photoanodes Using Binary Molten Salt Synthesis for Water Oxidation Reaction. Acta Physico-Chimica Sinica, 2024, 40(12): 2408012-. doi: 10.3866/PKU.WHXB202408012
14. [14]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101
15. [15]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 736-750. doi: 10.11862/CJIC.20230346
16. [16]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
17. [17]
  Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H₂ production activity of BaTiO₃ nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
18. [18]
  Minna Ma , Yujin Ouyang , Yuan Wu , Mingwei Yuan , Lijuan Yang . Green Synthesis of Medical Chemiluminescence Reagents by Photocatalytic Oxidation. University Chemistry, 2024, 39(5): 134-143. doi: 10.3866/PKU.DXHX202310093
19. [19]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
20. [20]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . 钛酸铋/氮化碳无机有机复合S型异质结纯水光催化产过氧化氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-. doi: 10.3866/PKU.WHXB202403009

Get Citation

PDF

XML

Metrics

PDF Downloads(1095)
Abstract views(2026)
HTML views(15)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Photoelectrocatalytic Water Oxidation Properties of FeO(OH)-TiO2/CoPi Composite Photoanodes

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation and Photoelectrocatalytic Water Oxidation Properties of FeO(OH)-TiO₂/CoPi Composite Photoanodes