Citation: ZHU Fu-Liang, ZHAO Jing-Xin, CHENG Yong-Liang, LI Hai-Bao, YAN Xing-Bin. Magnetic and Electrochemical Properties of NiCo₂O₄ Microbelts Fabricated by Electrospinning[J]. Acta Physico-Chimica Sinica doi: 10.3866/PKU.WHXB201209063 shu

Magnetic and Electrochemical Properties of NiCo₂O₄ Microbelts Fabricated by Electrospinning

1.
1 School of Material Science and Engineering, Lanzhou University of Technology, Lanzhou 730050, P. R. China;
2 Laboratory of Clean Energy Chemistry and Materials, Lanzhou Institute of Chemical Physics, Chinese Academy of Science, Lanzhou 730000,P. R. China

Received Date: 2 July 2012
Available Online: 6 September 2012
Fund Project: 甘肃省自然科学基金(3ZS042-B25-029) (3ZS042-B25-029)国家自然科学基金(51005225)资助项目 (51005225)

Cobaltate nickel (NiCo₂O₄) microbelts were fabricated by direct calcination of electrospun precursor samples with an appropriate heating rate. The crystal structure, morphology, magnetic properties, and electrochemical properties of the NiCo₂O₄ microbelts were investigated by X-ray diffraction, scanning electron microscopy, vibrating sample magnetometry, and electrochemical analysis. The results showed that a heating rate of 1℃·min^-1 resulted in the formation of cubic spinel NiCo₂O₄ microbelts. After calcination at high temperatures, the microbelts retained their one-dimensional structure. Magnetization results indicated that the NiCo₂O₄ microbelts were superparamagnetic and their magnetization value at 10 kOe was 6.35 emu·g^-1. Moreover, the electrochemical results suggest that the capacitance of the NiCo₂O₄ microbelts is typical pseudocapacitive capacitance, and the value of the specific capacitance gradually decreases with increasing discharge current density.
- NiCo₂O₄,
- Microbelt,
- Magnetic property,
- Electrochemical property,
- Rate capability
1. [1]
  
  (1) Zhou, X.W.; Chen, Q. S.; Zhou, Z. Y.; Sun, S. G. J. Nanosci. Nanotechnol. 2009, 9, 2392. doi: 10.1166/jnn.2009.SE34
2. [2]
  (2) Gao,Y.Y.; Cao, D. X.;Wang, G. L.;Yin, C. L. Acta Phys. -Chim. Sin. 2010, 26, 29. [高胤义, 曹殿学, 王贵领, 尹翠蕾. 物理化学学报, 2010, 26, 29.] doi: 10.3866/PKU.WHXB20100102
3. [3]
  (3) Fried, T.; Shemer, G.; Markovich, G. Adv. Mater. 2001, 13,1158.
4. [4]
  (4) Jolley, C.; Pool, V.; Idzerda, Y.; Douglas, T. Chem. Mater. 2011,23, 2392.
5. [5]
  (5) Xu, Z. C.; Hou, Y. L.; Sun, S. H. J. Am. Chem. Soc. 2007, 129,8698.
6. [6]
  (6) Zhong, J. Y.; Cao, C. B. Sens. Actuators B 2010, 145, 651. doi: 10.1016/j.snb.2010.01.016
7. [7]
  (7) Chaubal, N. S.; Joshi, V. Y. J. Porous. Mater. 2011, 18, 177. doi: 10.1007/s10934-010-9368-2
8. [8]
  (8) Liu, X. H.;Wang, J. Q.; Zhang, J. Y.; Yang, S. G. Mater. Sci. Eng. A 2006, 430, 248. doi: 10.1016/j.msea.2006.05.059
9. [9]
  (9) Lina, G.; Meng, G. Y. Mater. Res. Bull. 2008, 43, 1555. doi: 10.1016/j.materresbull.2007.06.027
10. [10]
  (10) Mandzhukova, T.; Khrussanova, M.; Gri rova, E.; Stefanov, P.;Khristov, M.; Peshev, P. J. Alloy. Compd. 2008, 457, 472. doi: 10.1016/j.jallcom.2007.03.006
11. [11]
  (11) Keng, C. S.; Tsin, L. K.; Zulkarnain, Z. Electrochim. Acta 2012,67, 67. doi: 10.1016/j.electacta.2012.02.014
12. [12]
  (12) Verma, S.; Joshi, H. M.; Jagadale, T.; Chawla, A.; Chandra, R.;Ogale, S. J. Phys. Chem. C 2008, 112, 15106. doi: 10.1021/jp804923t
13. [13]
  (13) Li, Q. F.; Zeng, L. X.;Wang, J. C.; Tang, D. P.; Liu, B. Q.;Chen, G. N.;Wei, M. D. ACS Appl. Mater. Interfaces 2011, 3,1366. doi: 10.1021/am200228k
14. [14]
  (14) Tavares, A. C.; Cartaxo, M. A. M.; Pereira, M. I. D. S.; Costa, F.M. J. Electroanal. Chem. 1999, 464, 187. doi: 10.1016/S0022-0728(99)00018-2
15. [15]
  (15) Sangeeta, N. K.; Anil, D. J.; Seema, V. Nanomed-Nanotechnol.2012, 8, 452. doi: 10.1016/j.nano.2011.07.010
16. [16]
  (16) Cabo, M.; Pellicer, E.; Rossinyol, E.; Estrader, M.; Ortega, A.L.; Nogues, J.; Castell, O.; Surinach, S.; Baro, M. D. J. Mater. Chem. 2010, 20, 7021. doi: 10.1039/c0jm00406e
17. [17]
  (17) Bao, J. Z.;Wang, S. L. Acta Phys. -Chim. Sin. 2011, 27, 2849.[鲍晋珍, 王森林. 物理化学学报, 2011, 27, 2849.] doi: 10.3866/PKU.WHXB20112849
18. [18]
  (18) Guan, H. Y.; Shao, C.; Liu, Y. C.; Yu, N.; Yang, X. H. Solid State Electrochem. 2004, 131, 107.
19. [19]
  (19) Salunkhe, R. R.; Jang, K. H.; Yu, H.; Yu, S.; Ganesh, T.; Han, S.H.; Ahn, H. J. Alloy. Compd. 2011, 509, 6677. doi: 10.1016/j.jallcom.2011.03.136
20. [20]
  (20) Hu, L. F.;Wu, L. M.; Liao, M. Y.; Hu, X. H.; Fang, X. S. Adv. Funct. Mater. 2012, 22, 998. doi: 10.1002/adfm.v22.5
21. [21]
  (21) Yu, L. Q.; Chen, S. L.; Chang, S.; Li, Y. H.; Gao, Y. Y.;Wang,G. L.; Cao, D. X. Acta Phys. -Chim. Sin. 2011, 27, 615. [于丽秋, 陈书礼, 常莎, 李云虎, 高胤义, 王贵领, 曹殿学. 物理化学学报, 2011, 27, 615.] doi: 10.3866/PKU.WHXB20110317
22. [22]
  (22) Caruso, R. A.; Schauka, J. H.; Greiner, A. Adv. Mater. 2001, 13,1577. doi: 10.1002/1521-4095(200110)13:20<1577::AIDADMA1577>3.0.CO;2-S
23. [23]
  (23) Ochanda, F.; Jones,W. E. Langmuir 2005, 21, 10791. doi: 10.1021/la050911s
24. [24]
  (24) Kim, G. M.; Lee, S. M.; Michjler, G. H.; Roggendorf, H.;Güsele, U.; Knez, M. Chem. Mater. 2008, 20, 3085. doi: 10.1021/cm703398b
25. [25]
  (25) Loscertales, I. G.; Banero, A.; Márquez, M.; Spretz, R.;Velardeortiz, R.; Larsen, G. J. Am. Chem. Soc. 2004, 126, 5376.doi: 10.1021/ja049443j
26. [26]
  (26) Zhan, S. H.; Chen, D. R.; Jiao, X. L.; Tao, C. H. J. Phys. Chem. B 2006, 110, 11199. doi: 10.1021/jp057372k
27. [27]
  (27) Li, D.; Xia, Y. N. Nano Lett. 2004, 4, 933. doi: 10.1021/nl049590f
28. [28]
  (28) Bazilevsky, A. V.; Yarm, A. L.; Meganridis, C. M. Langmuir2007, 23, 2311. doi: 10.1021/la063194q
29. [29]
  (29) Sanders, E. H.; Kloefkorn, R.; Bowlin, G. L.; Simpson, D. G.;Wnek, G. F. Macromolecules 2003, 36, 3803. doi: 10.1021/ma021771l
30. [30]
  (30) Lang, J.W.; Kong, L. B.; Liu, M.; Luo, Y. C.; Kang, L.J. Electrochem. Soc. 2010, 157, 1341. doi: 10.1149/1.3497298
31. [31]
  (31) Cheng, Y. L.; Zou, B. L.; Yang, J. L.;Wang, C. J.; Liu, Y. J.;Fan, X. Z.; Zhu, L.;Wang, Y.; Ma, H. M.; Cao, X. Q.CrystEngComm 2011, 13, 2268. doi: 10.1039/c0ce00802h
32. [32]
  (32) Zhang, Z. Y.; Li, X. H.;Wang, C. H.;Wei, L. M.; Liu, Y. C.;Shao, C. L. J. Phys. Chem. C 2009, 113, 1939. doi: 10.1021/jp806088m
33. [33]
  (33) Pankhurst, O. A.; Polllard, R. J. Phys. Rev. Lett. 1991, 67, 248.doi: 10.1103/PhysRevLett.67.248
34. [34]
  (34) Sun, G. H.; Li, K. X.; Sun, C. G. Microporous Mesoporous Mat. 2010, 128, 56. doi: 10.1016/j.micromeso.2009.07.027
35. [35]
  (35) Xu, M.W.; Zhao, D. D.; Bao, S. J.; Li, H. L. J. Solid State Electrochem. 2007, 11, 1101. doi: 10.1007/s10008-006-0246-4
36. [36]
  (36) Zhang, S. S.; Xu, K.; Jow, T. R. Electrochim. Acta 2004, 49,1057. doi: 10.1016/j.electacta.2003.10.016
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通讯作者: 陈斌, bchen63@163.com

Magnetic and Electrochemical Properties of NiCo₂O₄ Microbelts Fabricated by Electrospinning