Citation: ZHU Fu-Liang, ZHAO Jing-Xin, CHENG Yong-Liang, LI Hai-Bao, YAN Xing-Bin. Magnetic and Electrochemical Properties of NiCo₂O₄ Microbelts Fabricated by Electrospinning[J]. Acta Physico-Chimica Sinica doi: 10.3866/PKU.WHXB201209063 shu

Magnetic and Electrochemical Properties of NiCo₂O₄ Microbelts Fabricated by Electrospinning

1.
1 School of Material Science and Engineering, Lanzhou University of Technology, Lanzhou 730050, P. R. China;
2 Laboratory of Clean Energy Chemistry and Materials, Lanzhou Institute of Chemical Physics, Chinese Academy of Science, Lanzhou 730000,P. R. China

Received Date: 2 July 2012
Available Online: 6 September 2012
Fund Project: 甘肃省自然科学基金(3ZS042-B25-029) (3ZS042-B25-029)国家自然科学基金(51005225)资助项目 (51005225)

Cobaltate nickel (NiCo₂O₄) microbelts were fabricated by direct calcination of electrospun precursor samples with an appropriate heating rate. The crystal structure, morphology, magnetic properties, and electrochemical properties of the NiCo₂O₄ microbelts were investigated by X-ray diffraction, scanning electron microscopy, vibrating sample magnetometry, and electrochemical analysis. The results showed that a heating rate of 1℃·min^-1 resulted in the formation of cubic spinel NiCo₂O₄ microbelts. After calcination at high temperatures, the microbelts retained their one-dimensional structure. Magnetization results indicated that the NiCo₂O₄ microbelts were superparamagnetic and their magnetization value at 10 kOe was 6.35 emu·g^-1. Moreover, the electrochemical results suggest that the capacitance of the NiCo₂O₄ microbelts is typical pseudocapacitive capacitance, and the value of the specific capacitance gradually decreases with increasing discharge current density.
- NiCo₂O₄,
- Microbelt,
- Magnetic property,
- Electrochemical property,
- Rate capability
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通讯作者: 陈斌, bchen63@163.com

Magnetic and Electrochemical Properties of NiCo₂O₄ Microbelts Fabricated by Electrospinning