Citation: LI Song-Mei, WANG Bo, LIU Jian-Hua, YU Mei, AN Jun-Wei. Synthesis and Microwave Absorption Properties of Nickel Nanoparticles-Graphene Composites with Different Morphologies[J]. Acta Physico-Chimica Sinica doi: 10.3866/PKU.WHXB201208292 shu

Synthesis and Microwave Absorption Properties of Nickel Nanoparticles-Graphene Composites with Different Morphologies

1.
Key Laboratory of Aerospace Materials and Performance,Ministry of Education, School of Materials Science and Engineering, Beihang University, Beijing 100191, P. R. China

Received Date: 2 July 2012
Available Online: 29 August 2012
Fund Project: 航空科学基金(20110251003)资助项目 (20110251003)

Nickel nanoparticles-graphene (Ni-GNs) composites with two different morphologies were successfully synthesized by in situ chemical reduction, and the morphology-dependent electromagnetic absorption properties of the composites was investigated. By changing the sequence of the reactants are added during preparation, spherical and spinous spherical nickel nanoparticle-graphene composites were obtained. The structure, morphology, and microwave absorption properties of the composites were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and vector network analysis (VNA). The results indicated that the spinous spherical nickel nanoparticle-graphene composites had better microwave absorption ability than the spherical nickel nanoparticle-graphene composites. This is due to the unique isotropic antenna morphology of the spinous spherical nickel nanoparticles in the composites, arising from the point discharge effect. This facile in situ chemical reduction method for the preparation of nickel nanoparticle-graphene composites to give different morphologies could be used for the preparation of other composites.
- Graphene,
- Nickel,
- Nanocomposite,
- Microwave absorption,
- In-situ chemical reduction method
1. [1]
  
  (1) Novoselov, K. S.; Geim, A. K.; Morozov, S. V.; Jiang, D.;Zhang, Y.; Dubonos, S. V.; Gri rieva, I. V.; Firsov, A. A.Science 2004, 306 (5696), 666. doi: 10.1126/science.1102896
2. [2]
  (2) Chae, H. K.; Siberio-Perez, D. Y.; Kim, J.; , Y.; Eddaoudi,M.; Matzger, A. J.; Okeeffe, M.; Yaghi, O. M. Nature 2004, 427(6974), 523. doi: 10.1038/nature02311
3. [3]
  (3) Sclladler, L. S.; Giammris, S. C.; Ajayan, P. M. Appl. Phys. Lett.1998, 73 (26), 3842.
4. [4]
  (4) Zhang, Y. B.; Tan, J.W.; Stormer, H. L.; Kim, P. Nature 2005,438 (7065), 201. doi: 10.1038/nature04235
5. [5]
  (5) Bolotin, K. I.; Sikes, K. J.; Jiang, Z.; Klima, M.; Fudenberg, G.;Hone, J.; Kim, P.; Stormer, H. L. Solid State Commun. 2008, 146 (9/10), 351.
6. [6]
  (6) Balandin, A. A.; Ghosh, S.; Bao,W. Z.; Calizo, I.;Teweldebrhan, D.; Miao, F.; Lau, C. N. Nano Lett. 2008, 8 (3),902. doi: 10.1021/nl0731872
7. [7]
  (7) Reina, A.; Thiele, S.; Jia, X. T.; Bhaviripudi, S.; Dresselhaus, M.S.; Schaefer, J. A.; Kong, J. Nano Res. 2009, 2 (6), 509. doi: 10.1007/s12274-009-9059-y
8. [8]
  (8) Berger, C.; Song, Z.; Li, X.;Wu, X. S.; Brown, N.; Naud, C.;Mayou, D.; Li, T.; Hass, J.; Marchhenkow, A. N.; Conrad, E. H.;First, P. N.; Heer,W. A. Science 2006, 312 (5777), 1191. doi: 10.1126/science.1125925
9. [9]
  (9) Pei, S. F.; Zhao, J. P.; Du, J. H.; Ren,W.C.; Cheng, H. M.Carbon 2010, 48 (15), 4466. doi: 10.1016/j.carbon.2010.08.006
10. [10]
  (10) Stankovich, S.; Piner, R. D.; Chen, X. Q.;Wu, N. Q.; Nguyen,S. T.; Ruoff, R. S. J. Mater. Chem. 2006, 16 (2), 155. doi: 10.1039/b512799h
11. [11]
  (11) Stankovich, S.; Dikin, D. A.; Dommett, G. H.; Kohlhaas, K. M.;Zimney, E. J.; Stach, E. A.; Piner, R. D.; Nguyen, S. T.; Ruoff,R. S. Nature 2006, 442 (7100), 282. doi: 10.1038/nature04969
12. [12]
  (12) Niu, H. L.; Chen, Q.W.; Ning, M.; Jia, Y. S.;Wang, X, J.J. Phys. Chem. B 2004, 108 (13), 3996. doi: 10.1021/jp0361172
13. [13]
  (13) An, Z. G.; Pan, S. L.; Zhang, J. J. J. Phys. Chem. C 2009, 113 (4), 1346. doi: 10.1021/jp809224j
14. [14]
  (14) Zhao, H. T.; Han, X. J.; Zhang, L. F.;Wang, G. Y.;Wang, C.; Li,X. A.; Xu, P. Radiat. Phys. Chem. 2011, 80 (3), 390. doi: 10.1016/j.radphyschem.2010.11.007
15. [15]
  (15) Ma, F.; Ma, J.; Huang, J. J.; Li, J. G. J. Magn. Magn. Mater.2012, 324 (2), 205. doi: 10.1016/j.jmmm.2011.08.013
16. [16]
  (16) Wang, C.; Han, X. J.; Xu, P.;Wang, J. Y.; Du, Y. C.;Wang, X.H.; Qin,W.; Zhang, T. J. Phys. Chem. C 2010, 114 (7), 3196.doi: 10.1021/jp908839r
17. [17]
  (17) Deng, Y. D.; Zhao, L.; Shen, B.; Liu, L.; Hu,W. B. J. Appl. Phys. 2006, 100 (1), 014304. doi: 10.1063/1.2210187
18. [18]
  (18) Zhao, J. P.; Pei, S. F.; Ren,W. C.; Gao, L. B.; Cheng, H. M. ACS Nano 2010, 4 (9), 5245. doi: 10.1021/nn1015506
19. [19]
  (19) Xu, C.;Wang, X. Small 2009, 5 (19), 2212. doi: 10.1002/smll.v5:19
20. [20]
  (20) Yu, M.; Liu, P. R.; Sun, Y. J.; Liu, J. H.; An, J.W.; Li, S. M.J. Inorg. Mater. 2012, 27 (1), 89. [于美, 刘鹏瑞, 孙玉静, 刘建华, 安军伟, 李松梅. 无机材料学报, 2012, 27 (1), 89.]
21. [21]
  (21) Xu, P.; Han, X. J.;Wang, C.; Zhao, H. T.;Wang, J. Y.;Wang, X.H.; Zhang, B. J. Phys. Chem. B 2008, 112 (10), 2775. doi: 10.1021/jp710259v
22. [22]
  (22) Sue, K.; Suzuki, A.; Suzuki, M.; Arai, K.; Hakuta, Y.; Hayashi,H.; Hiaki, T. Ind. Eng. Chem. Res. 2006, 45 (2), 623. doi: 10.1021/ie0506062
23. [23]
  (23) Sarkar, S.; Sinha, A. K.; Pradhan, M.; Basu, M.; Negish, Y.; Pal,T. J. Phys. Chem. C 2011, 115 (5), 1659. doi: 10.1021/jp109572c
24. [24]
  (24) Li, S. M.; Chen, D. M.; Liu, J. H. Acta Phys. -Chim. Sin. 2004,20 (11), 1389. [李松梅, 陈冬梅, 刘建华. 物理化学学报,2004, 20 (11), 1389. ] doi: 10.3866/PKU.WHXB20041121
25. [25]
  (25) Ferreira, M. G. S.; Duarte, R. G.; Montemor, M. F.; Simoes, A.M. P. Electrochim. Acta 2004, 49 (17-18), 2927. doi: 10.1016/j.electacta.2004.01.051
26. [26]
  (26) Sigh, P.; Babbar, V. K.; Razdan, A.; Puri, R. K.; el, T. C.J. Appl. Phys. 2000, 87 (9), 4362.
27. [27]
  (27) Zhuo, R. F.; Qiao, L.; Feng, H. T.; Chen, J. T.; Yan, D.;Wu, Z.G.; Yan, P. X. J. Appl. Phys. 2008, 104 (9), 094101. doi: 10.1063/1.2973198
28. [28]
  (28) Zhou, Z.W.; Chu, L. S.; Hu, S. C. Mater. Sci. Eng. B 2006, 126 (1), 93. doi: 10.1016/j.mseb.2005.09.009
1. [1]
  Min LI , Xianfeng MENG . Preparation and microwave absorption properties of ZIF-67 derived Co@C/MoS₂ nanocomposites. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240065
2. [2]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20230447
3. [3]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20230253
4. [4]
  Yunting Shang , Yue Dai , Jianxin Zhang , Nan Zhu , Yan Su . Something about RGO (Reduced Graphene Oxide). University Chemistry, doi: 10.3866/PKU.DXHX202306050
5. [5]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240043
6. [6]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240067
7. [7]
  Guang Huang , Lei Li , Dingyi Zhang , Xingze Wang , Yugai Huang , Wenhui Liang , Zhifen Guo , Wenmei Jiao . Cobalt’s Valor, Nickel’s Foe: A Comprehensive Chemical Experiment Utilizing a Cobalt-based Imidazolate Framework for Nickel Ion Removal. University Chemistry, doi: 10.3866/PKU.DXHX202311051
8. [8]
  Fangfang WANG , Jiaqi CHEN , Weiyin SUN . CuBi@Cu-MOF composite catalysts for electrocatalytic CO₂ reduction to HCOOH. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240350
9. [9]
  Jinyi Sun , Lin Ma , Yanjie Xi , Jing Wang . Preparation and Electrocatalytic Nitrogen Reduction Performance Study of Vanadium Nitride@Nitrogen-Doped Carbon Composite Nanomaterials: A Recommended Comprehensive Chemistry Experiment. University Chemistry, doi: 10.3866/PKU.DXHX202310094
10. [10]
  Jie XIE , Hongnan XU , Jianfeng LIAO , Ruoyu CHEN , Lin SUN , Zhong JIN . Nitrogen-doped 3D graphene-carbon nanotube network for efficient lithium storage. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240216
11. [11]
  Tian TIAN , Meng ZHOU , Jiale WEI , Yize LIU , Yifan MO , Yuhan YE , Wenzhi JIA , Bin HE . Ru-doped Co₃O₄/reduced graphene oxide: Preparation and electrocatalytic oxygen evolution property. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240298
12. [12]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20230252
13. [13]
  Xin Zhou , Zhi Zhang , Yun Yang , Shuijin Yang . A Study on the Enhancement of Photocatalytic Performance in C/Bi/Bi₂MoO₆ Composites by Ferroelectric Polarization: A Recommended Comprehensive Chemical Experiment. University Chemistry, doi: 10.3866/PKU.DXHX202310008
14. [14]
  Yuting ZHANG , Zunyi LIU , Ning LI , Dongqiang ZHANG , Shiling ZHAO , Yu ZHAO . Nickel vanadate anode material with high specific surface area through improved co-precipitation method: Preparation and electrochemical properties. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240204
15. [15]
  Meng Lin , Hanrui Chen , Congcong Xu . Preparation and Study of Photo-Enhanced Electrocatalytic Oxygen Evolution Performance of ZIF-67/Copper(I) Oxide Composite: A Recommended Comprehensive Physical Chemistry Experiment. University Chemistry, doi: 10.3866/PKU.DXHX202308117
16. [16]
  Wen YANG , Didi WANG , Ziyi HUANG , Yaping ZHOU , Yanyan FENG . La promoted hydrotalcite derived Ni-based catalysts: In situ preparation and CO₂ methanation performance. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20230276
17. [17]
  Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20230312
18. [18]
  Zhenlin Zhou , Siyuan Chen , Yi Liu , Chengguo Hu , Faqiong Zhao . A New Program of Voltammetry Experiment Teaching Based on Laser-Scribed Graphene Electrode. University Chemistry, doi: 10.3866/PKU.DXHX202308049
19. [19]
  Tianqi Bai , Kun Huang , Fachen Liu , Ruochen Shi , Wencai Ren , Songfeng Pei , Peng Gao , Zhongfan Liu . 石墨烯厚膜热扩散系数与微观结构的关系. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202404024
20. [20]
  Jiahui CHEN , Tingting ZHENG , Xiuyun ZHANG , Wei LÜ . Research progress of near-infrared absorption inorganic nanomaterials in photothermal and photodynamic therapy of tumors. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240106

Get Citation

PDF

XML

Metrics

PDF Downloads(1405)
Abstract views(3310)
HTML views(110)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142