Citation: LI Song-Mei, WANG Bo, LIU Jian-Hua, YU Mei, AN Jun-Wei. Synthesis and Microwave Absorption Properties of Nickel Nanoparticles-Graphene Composites with Different Morphologies[J]. Acta Physico-Chimica Sinica doi: 10.3866/PKU.WHXB201208292 shu

Synthesis and Microwave Absorption Properties of Nickel Nanoparticles-Graphene Composites with Different Morphologies

1.
Key Laboratory of Aerospace Materials and Performance,Ministry of Education, School of Materials Science and Engineering, Beihang University, Beijing 100191, P. R. China

Received Date: 2 July 2012
Available Online: 29 August 2012
Fund Project: 航空科学基金(20110251003)资助项目 (20110251003)

Nickel nanoparticles-graphene (Ni-GNs) composites with two different morphologies were successfully synthesized by in situ chemical reduction, and the morphology-dependent electromagnetic absorption properties of the composites was investigated. By changing the sequence of the reactants are added during preparation, spherical and spinous spherical nickel nanoparticle-graphene composites were obtained. The structure, morphology, and microwave absorption properties of the composites were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and vector network analysis (VNA). The results indicated that the spinous spherical nickel nanoparticle-graphene composites had better microwave absorption ability than the spherical nickel nanoparticle-graphene composites. This is due to the unique isotropic antenna morphology of the spinous spherical nickel nanoparticles in the composites, arising from the point discharge effect. This facile in situ chemical reduction method for the preparation of nickel nanoparticle-graphene composites to give different morphologies could be used for the preparation of other composites.
- Graphene,
- Nickel,
- Nanocomposite,
- Microwave absorption,
- In-situ chemical reduction method
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沈阳化工大学材料科学与工程学院沈阳 110142