Citation: YANG Yi, YE Wei, CHEN Xiao. Preparation and Controlled Assembly of Asymmetric Janus Particles[J]. Acta Physico-Chimica Sinica doi: 10.3866/PKU.WHXB201208222 shu

Preparation and Controlled Assembly of Asymmetric Janus Particles

1.
Key Laboratory for Colloid and Interface Chemistry, Ministry of Education, Shandong University, Jinan 250100, P. R. China

Received Date: 18 July 2012
Available Online: 22 August 2012
Fund Project: 国家自然科学基金(20973104, 21033005) (20973104, 21033005)山东省自然科学基金(2009ZRB01147)资助项目 (2009ZRB01147)

Janus particles have different or asymmetric hemispheres both in structure and chemical properties. These particles have attracted increasing attention because of their unique characteristics and potential in applications as drug carriers, electronic components, and stabilizers for emulsions. Controlled fabrication of organized aggregates using these Janus particles as novel building blocks is becoming well concerned. Several assembly strategies, including bulk, interfacial and environmental modulated organization, have been developed based on the amphiphilic modification and functionality of Janus particles. This review summarizes recent progress on the preparation, modification, and assembly techniques for Janus particles. Some novel methods, including one-step synthesis, self-assembly of polymers, and seed directed growth, are discussed in detail and compared. Trends for designing new functional Janus particles and their potential applications are identified.
- Janus particle,
- Surface modification,
- Asymmetry,
- Amphiphilicity,
- Assembly
1. [1]
  
  (1) De Gennes, P. G. Angew. Chem. Int. Edit. 1992, 31, 842.doi: 10.1002/(ISSN)1521-3773
2. [2]
  (2) Binks, B. P. Curr. Opinion Colloid Interface Sci. 2002, 7, 21.doi: 10.1016/S1359-0294(02)00008-0
3. [3]
  (3) Takei, H.; Shimizu, N. Langmuir 1997, 13, 1865.
4. [4]
  (4) Liang, F. X.; Liu, J. G.; Zhang, C. G.; Qu, X. Z.; Li, J. L.; Yang,Z. Z. Chem. Commun. 2011, 47, 1231. doi: 10.1039/c0cc03599h
5. [5]
  (5) Tanaka, T.; Okayama, M.; Minami, H.; Okubo, M. Langmuir2010, 26, 11732. doi: 10.1021/la101237c
6. [6]
  (6) Liu, Y.; Li,W.; Perez, T.; Gunton, J. D.; Brett, G. Langmuir2012, 28, 3. doi: 10.1021/la2032303
7. [7]
  (7) Choi, J. S. ; Jun, Y.W.; Yeon, S. I.; Kim, H. C.; Shin, J. S.;Cheon, J.W. J. Am. Chem. Soc. 2006, 128, 15982. doi: 10.1021/ja066547g
8. [8]
  (8) Jiang, S.; Chen, Q.; Tripathy, M.; Luijten, E.; Schweizer, K. S.;Granick, S. Adv. Mater. 2010, 22, 1060. doi: 10.1002/adma.200904094
9. [9]
  (9) Howse, J. R.; Jones, R. A.; Ryan, A. J.; ugh, T.; Vafabakhsh,R.; lestanian, R. Phys. Rev. Lett. 2007, 99, 048102. doi: 10.1103/PhysRevLett.99.048102
10. [10]
  (10) Dupont, J.; Liu, G. J. Soft Matter 2010, 6, 3654. doi: 10.1039/c0sm00044b
11. [11]
  (11) Tanaka, T.; Okayama, M.; Kitayama, Y.; Kagawa, Y.; Okubo, M.Langmuir 2010, 26, 7843. doi: 10.1021/la904701r
12. [12]
  (12) Wang, Q.; Yang, X. L.; Yang, Y. J.; Xu, H. B. Chin. J. Appl. Chem. 2010, 27, 745. [王芹, 杨祥良, 杨亚江, 徐辉碧. 应用化学, 2010, 27, 745.]
13. [13]
  (13) Chen, Y. H.;Wang, C. Y.; Li, Y.; Tong, Z. Prog. Chem. 2009, 21,615. [陈云华, 王朝阳, 李煜, 童真. 化学进展, 2009, 21,615.]
14. [14]
  (14) Lattuada, M.; Hatton, T. A. Nano Today 2011, 6, 286. doi: 10.1016/j.nantod.2011.04.008
15. [15]
  (15) Kim, S. H.; Lim, J. M.; Lee, S. K.; Heo, C. J.; Yang, S. M. Soft Matter 2010, 6, 1092. doi: 10.1039/b920611f
16. [16]
  (16) Yuan, Y.; Zhang, M. Z.; Zhang, H.; Ni, P. H. Acta Chim. Sin.2010, 68, 1537. [袁媛, 张明祖, 张虎, 倪沛红. 化学学报, 2010, 68, 1537.]
17. [17]
  (17) Lee, R. S.;Wu, K. P. J. Polymer Sci. Part A 2011, 49, 3163.doi: 10.1002/pola.24753
18. [18]
  (18) Perro, A.; Reculusa, S.; Ravaine, S.; Lami, E. B.; Duguet, E.J. Mater. Chem. 2005, 15, 3745. doi: 10.1039/b505099e
19. [19]
  (19) Erhardt, R.; Böker, A.; Zettl, H.; Kaya, H.; Hintzen,W. P.;Krausch, G.; Abetz, V.; Müller, A. Macromolecules 2001, 34,1069. doi: 10.1021/ma000670p
20. [20]
  (20) Liu, Y. F.; Abetz, V.; Müller, A. Macromolecules 2003, 36, 7894.doi: 10.1021/ma0345551
21. [21]
  (21) Walther, A.; André, X.; Drechsler, M.; Abetz, V.; Müller, A. H.E. J. Am. Chem. Soc. 2007, 129, 6187. doi: 10.1021/ja068153v
22. [22]
  (22) Walther, A.; Drechsler, M.; Müller, A. H. E. Soft Matter 2009, 5,385. doi: 10.1039/b812321g
23. [23]
  (23) Yu, H.; Chen, M.; Rice, P. M.;Wang, S. X.; White, R. L.; Sun,S. H. Nano Lett. 2005, 5, 378.
24. [24]
  (24) Wang, C.;Wei, Y. J.; Jiang, H. Y.; Sun, S. H. Nano Lett. 2009, 9,4544. doi: 10.1021/nl903077t
25. [25]
  (25) Huang, J. M.; Sun, Y. H.; Huang, S. H.; Yu, K.; Zhao, Q.; Peng,F.; Yu, H.;Wang, H. J.; Yang, J. J. Mater. Chem. 2011, 21,17930. doi: 10.1039/c1jm13045e
26. [26]
  (26) Kuang, H, M.; Deng, Z. X.; Li, C. H.; Sun, X. M.; Zhuang, J.;Li, Y. D. Acta Phys. -Chim. Sin. 2002, 18, 477. [匡汉茂, 邓兆祥, 李春辉, 孙晓明, 庄京, 李亚栋. 物理化学学报, 2002, 18,477.] doi: 10.3866/PKU.WHXB20020520
27. [27]
  (27) Mokari, T.; Sztrum, C. G.; Salant, A.; Rabani, E.; Banin, U. Nat. Mater. 2005, 4, 855. doi: 10.1038/nmat1505
28. [28]
  (28) Maynadié, J.; Salant, A.; Falqui, A.; Respaud, M.; Shaviv, E.;Banin, U.; Soulantica, K.; Chaudret, B. Angew. Chem . Int. Edit.2009, 48, 1814. doi: 10.1002/anie.v48:10
29. [29]
  (29) Wang, C.; Daimon, H.; Sun, S. H. Nano Lett. 2009, 9, 1493. doi: 10.1021/nl8034724
30. [30]
  (30) Habas, S. E.; Lee, H.; Yang, P. Nat. Mater. 2007, 6, 692. doi: 10.1038/nmat1957
31. [31]
  (31) Shi,W. L.; Zeng, H.; Sahoo, Y.; Ohulchanskyy, T. Y.; Ding, Y.;Wang, Z. L.; Swihart, M.; Prasad, P. N. Nano Lett. 2006, 6, 875.doi: 10.1021/nl0600833
32. [32]
  (32) Gu, H.W.; Zheng, R. K.; Zhang, X. X.; Xu, B. J. Am. Chem. Soc. 2004, 126, 5664. doi: 10.1021/ja0496423
33. [33]
  (33) Gu, H.W.; Yang, Z. M.; Gao, J. H.; Chang, C. K.; Xu, B. J. Am. Chem. Soc. 2005, 127, 34. doi: 10.1021/ja045220h
34. [34]
  (34) Hong, L.; Jiang, S.; Granick, S. Langmuir 2006, 22, 9495.doi: 10.1021/la062716z
35. [35]
  (35) Jiang, S.; Granick, S. Langmuir 2008, 24, 2438. doi: 10.1021/la703274a
36. [36]
  (36) Liu, B.; Zhang, C. L.; Liu, J. G.;Qu, X. Z.; Yang, Z. Z. Chem. Commun. 2009, 3871.
37. [37]
  (37) Liu, B.;Wei,W.; Qu, X. Z.; Yang, Z. Z. Angew. Chem. Int. Edit.2008, 47, 3973.
38. [38]
  (38) Suzuki, D.; Tsuji, S.; Kawaguchi, H. J. Am. Chem. Soc. 2007,129, 8088. doi: 10.1021/ja072258w
39. [39]
  (39) Duan, C. Y.; Zhou, J. F.;Wu, Z. S.; Dang, H. X. Acta Phys. -Chim. Sin. 2003, 19, 1049. [段春英, 周静芳, 吴志申,党鸿辛. 物理化学学报, 2003, 19, 1049.] doi: 10.3866/PKU.WHXB20031113
40. [40]
  (40) Wang, B. B.; Li, B.; Zhao, B.; Li, C. Y. J. Am. Chem. Soc. 2008,130, 11594. doi: 10.1021/ja804192e
41. [41]
  (41) Zhang, L.; Zhang, F.; Dong,W. F.; Song, J. F.; Huo, Q. S.; Sun,H. B. Chem. Commun. 2011, 47, 1225. doi: 10.1039/c0cc03946b
42. [42]
  (42) Li, Z. T.; Cheng, E. J.; Huang,W. X.; Zhang, T.; Yang, Z. Q.;Liu, D. S.; Tang, Z. Y. J. Am. Chem. Soc. 2011, 133, 15284.doi: 10.1021/ja205712a
43. [43]
  (43) Chen, T.; Yang, M. X.;Wang, X. J.; Tan, L. H.; Chen, H. Y.J. Am. Chem. Soc. 2008, 130, 11858. doi: 10.1021/ja8040288
44. [44]
  (44) Chen, T.; Chen, G.; Xing, S. G.;Wu, T.; Chen, H. Y. Chem. Mater. 2010, 22, 3826. doi: 10.1021/cm101155v
45. [45]
  (45) Jiang, S.; Schultz, M. J.; Chen, Q.; Moore, J. S.; Granick, S.Langmuir 2008, 24, 10073. doi: 10.1021/la800895g
46. [46]
  (46) Perro, A.; Reculusa, S.; Pereira, F.; Delville, M. H.; Min taud,C.; Duguet, E.; Lami, E. B.; Ravaine, S. Chem. Commun. 2005,5542.
47. [47]
  (47) Liu, L. Y.; Ren, M.W.; Yang,W. T. Langmuir 2009, 25, 11048.doi: 10.1021/la901364a
48. [48]
  (48) Teo, B. M.; Suh, S. K.; Hatton, T. A.; Ashokkumar, M.; Grieser,F. Langmuir 2011, 27, 30. doi: 10.1021/la104284v
49. [49]
  (49) Liang, F. X.; Shen, K.; Qu, X. Z.; Zhang, C. L.;Wang, Q.; Li, J.L.; Liu, J. G.; Yang, Z. Z.; Angew. Chem. Int. Edit. 2011, 123,2427.
50. [50]
  (50) Hong, L.; Cacciuto, A.; Luijten, E.; Granick, S. Langmuir 2008,24, 621. doi: 10.1021/la7030818
51. [51]
  (51) Dendukuri, D.; Hatton, T. A.; Doyle, P. S. Langmuir 2007, 23,4669. doi: 10.1021/la062512i
52. [52]
  (52) Biji, P.; Sarangi, N. K.; Patnaik, A. Langmuir 2010, 26, 14047.doi: 10.1021/la102371v
53. [53]
  (53) Chen, Q.; Whitmer, J. K.; Jiang, S.; Bae, S. C.; Luijten, E.;Granick, S. Science 2011, 331, 199. doi: 10.1126/science.1197451
54. [54]
  (54) Rosenthal, G.; Gubbins, K, E.; Klapp, S. H. L. J. Chem. Phys.2012, 136, 174901. doi: 10.1063/1.4707954
55. [55]
  (55) Zhao, N. N.; Liu, K.; Greener, J.; Nie, Z.; Kumacheva, E. Nano Lett. 2009, 9, 3077. doi: 10.1021/nl901567a
56. [56]
  (56) Zhao, N. N.; Vickery, J.; Guerin, G.; Park, J. I.;Winnik, M. A.;Kumacheva, E. Angew. Chem. Int. Edit. 2011, 50, 4606. doi: 10.1002/anie.201004915
57. [57]
  (57) Herrikhuyzen, J. V.; Portale, G.; Gielen, J. C.; Christianen, P. C.M.; Sommerdijk, N. A. J. M.; Meskers, S. C. J.; Schenning, A.P. H. J. Chem. Commun. 2008, 697.
58. [58]
  (58) Nørgaard, K.;Weygand, M.; Kjaer, K.; Brust, M.; Bjørnholm, T.Faraday Discuss. 2004, 125, 221. doi: 10.1039/b303117a
59. [59]
  (59) Xu, Q.; Kang, X.W.; Bo molni, R. A.; Chen, S.W. Langmuir2010, 26, 14923. doi: 10.1021/la102540n
60. [60]
  (60) He, J.; Hourwitz, M. J.; Liu, Y. J.; Perez, M. T.; Nie, Z. H.Chem. Commun. 2011, 47, 12450. doi: 10.1039/c1cc15603a
61. [61]
  (61) Guo, Y. Y.; Saei, S. H.; Izumi, C. M. S.; Moffitt, M. G. ACS Nano 2011, 3309.
62. [62]
  (62) Cheng, L.; Zhang, G. Z.; Zhu, L.; Dao, Y.; Chen, D. Y.; Jiang,M. Angew. Chem. Int. Edit. 2008, 47, 10171. doi: 10.1002/anie.v47:52
63. [63]
  (63) Walther, A.; Drechsler, M.; Rosenfeldt, S.; Harnau, L.; Ballauff,M.; Abetz, V.; Müller, A. H. E. J. Am. Chem. Soc. 2009, 131,4720. doi: 10.1021/ja808614q
64. [64]
  (64) Isojima, T.; Lattuada, M.; Vander Sande, J. B.; Hatton, T. A.ACS Nano 2008, 9, 1799.
65. [65]
  (65) Binks, B. P.; Lumsdon, S. O. I. Langmuir 2001, 17, 4540. doi: 10.1021/la0103822
66. [66]
  (66) Jiang, S.; Granick, S. J. Chem. Phys. 2007, 127, 161102. doi: 10.1063/1.2803420
67. [67]
  (67) Cheung, D. L.; Bon, S. Soft Matter 2009, 5, 3969. doi: 10.1039/b908462b
68. [68]
  (68) Miller,W. L.; Cacciuto, A. Phys. Rev. E 2009, 80, 1539.
69. [69]
  (69) Yang, M.;Wang,W.; Lieberwirth, I.;Wegner, G. J. Am. Chem. Soc. 2009, 131, 6283. doi: 10.1021/ja900739e
70. [70]
  (70) Brugarolas, T.; Park, B. J.; Lee, M. H.; Lee, D. Adv. Funct. Mater. 2011, 21, 3924. doi: 10.1002/adfm.v21.20
71. [71]
  (71) Sashuk, V.; Holyst, R.;Wojciechowski, T.; Fialkowski, M.J. Colloid Interface Sci. 2012, 375, 180. doi: 10.1016/j.jcis.2012.02.057
72. [72]
  (72) Ruhland, T. M.; Gröschel, A. H.;Walther, A.; Müller, A.Langmuir 2011, 27, 9807. doi: 10.1021/la201863x
73. [73]
  (73) Park, B. J.; Brugarolas, T.; Lee, D. Soft Matter 2011, 7, 6413.doi: 10.1039/c1sm05460k
74. [74]
  (74) Wang, Y. Z.; Fan, D. Q.; He, J. P.; Yang, Y. L. Colloid Polym. Sci. 2011, 289, 1885. doi: 10.1007/s00396-011-2506-9
75. [75]
  (75) Virgilio, N.; Favis, B. D. Macromolecules 2011, 44, 5850. doi: 10.1021/ma200647t
76. [76]
  (76) Yin, Y. Y.; Zhou, S. X.; You, B.;Wu, L. M. J. Polym. Sci. Part A2011, 49, 3272. doi: 10.1002/pola.v49.15
77. [77]
  (77) Gangwal, S.; Cayre, O. J.; Velev, O. D. Langmuir 2008, 24,13312.
78. [78]
  (78) Kretzschmar, I.; Song, J. H. Curr. Opin. Colloid Interface Sci.2011, 16, 84. doi: 10.1016/j.cocis.2011.01.002
79. [79]
  (79) Yuet, K. P.; Hwang, D. K.; Hagh oie, R.; Doyle, P. S.Langmuir 2010, 26, 4281. doi: 10.1021/la903348s
80. [80]
  (80) Smoukov, S. K.; Gangwal, S.; Marquez, M.; Velev, O. D. Soft Matter 2009, 5, 1285. doi: 10.1039/b814304h
81. [81]
  (81) Ren, B.; Ruditskiy, A.; Song, J. H.; Kretzschmar, I. Langmuir2012, 28, 1149. doi: 10.1021/la203969f
1. [1]
  Fengqiao Bi , Jun Wang , Dongmei Yang . Specialized Experimental Design for Chemistry Majors in the Context of “Dual Carbon”: Taking the Assembly and Performance Evaluation of Zinc-Air Fuel Batteries as an Example. University Chemistry, doi: 10.3866/PKU.DXHX202311069
2. [2]
  Ke QIAO , Yanlin LI , Shengli HUANG , Guoyu YANG . Advancements in asymmetric catalysis employing chiral iridium (ruthenium) complexes. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240265
3. [3]
  Qianwen Han , Tenglong Zhu , Qiuqiu Lü , Mahong Yu , Qin Zhong . 氢电极支撑可逆固体氧化物电池性能及电化学不对称性优化. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202309037
4. [4]
  Hong Lu , Yidie Zhai , Xingxing Cheng , Yujia Gao , Qing Wei , Hao Wei . Advancements and Expansions in the Proline-Catalyzed Asymmetric Aldol Reaction. University Chemistry, doi: 10.3866/PKU.DXHX202310074
5. [5]
  Shihui Shi , Haoyu Li , Shaojie Han , Yifan Yao , Siqi Liu . Regioselectively Synthesis of Halogenated Arenes via Self-Assembly and Synergistic Catalysis Strategy. University Chemistry, doi: 10.3866/PKU.DXHX202312002
6. [6]
  Weina Wang , Lixia Feng , Fengyi Liu , Wenliang Wang . Computational Chemistry Experiments in Facilitating the Study of Organic Reaction Mechanism: A Case Study of Electrophilic Addition of HCl to Asymmetric Alkenes. University Chemistry, doi: 10.12461/PKU.DXHX202407022
7. [7]
  Shunliu Deng , Haifeng Su , Yaxian Zhu , Yuzhi Wang , Yuhua Weng , Zhaobin Chen , Shunü Peng , Yinyun Lü , Xinyi Hong , Yiru Wang , Xiaozhen Huang , Zhimin Lin , Lansun Zheng . Course Ideological and Political Design for Self-Building Experiments of Scientific Instruments: Taking the Construction, Debugging, and Application of Teaching Mass Spectrometer as an Example. University Chemistry, doi: 10.3866/PKU.DXHX202308002
8. [8]
  Zhiwen HUANG , Qi LIU , Jianping LANG . W/Cu/S cluster-based supramolecular macrocycles and their third-order nonlinear optical responses. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240184
9. [9]
  Cuicui Yang , Bo Shang , Xiaohua Chen , Weiquan Tian . Understanding the Wave-Particle Duality and Quantization of Confined Particles Starting from Classic Mechanics. University Chemistry, doi: 10.12461/PKU.DXHX202407066
10. [10]
  Jie ZHAO , Sen LIU , Qikang YIN , Xiaoqing LU , Zhaojie WANG . Theoretical calculation of selective adsorption and separation of CO₂ by alkali metal modified naphthalene/naphthalenediyne. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20230385
11. [11]
  Cheng PENG , Jianwei WEI , Yating CHEN , Nan HU , Hui ZENG . First principles investigation about interference effects of electronic and optical properties of inorganic and lead-free perovskite Cs₃Bi₂X₉ (X=Cl, Br, I). Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20230282
12. [12]
  Heng Chen , Longhui Nie , Kai Xu , Yiqiong Yang , Caihong Fang . 两步焙烧法制备大比表面积和结晶性增强超薄g-C₃N₄纳米片及其高效光催化产H₂O₂. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202406019
13. [13]
  Yaoyin Lou , Xiaoyang Jerry Huang , Kuang-Min Zhao , Mark J. Douthwaite , Tingting Fan , Fa Lu , Ouardia Akdim , Na Tian , Shigang Sun , Graham J. Hutchings . Stable core-shell Janus BiAg bimetallic catalyst for CO₂ electrolysis into formate. Chinese Chemical Letters, doi: 10.1016/j.cclet.2024.110300
14. [14]
  Yongming Guo , Jie Li , Chaoyong Liu . Green Improvement and Educational Design in the Synthesis and Characterization of Silver Nanoparticles. University Chemistry, doi: 10.3866/PKU.DXHX202309057
15. [15]
  Zihan Lin , Wanzhen Lin , Fa-Jie Chen . Electrochemical Modifications of Native Peptides. University Chemistry, doi: 10.12461/PKU.DXHX202406089
16. [16]
  Lei Shi . Nucleophilicity and Electrophilicity of Radicals. University Chemistry, doi: 10.3866/PKU.DXHX202402018
17. [17]
  Donghui PAN , Yuping XU , Xinyu WANG , Lizhen WANG , Junjie YAN , Dongjian SHI , Min YANG , Mingqing CHEN . Preparation and in vivo tracing of ⁶⁸Ga-labeled PM_2.5 mimetic particles for positron emission tomography imaging. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20230468
18. [18]
  Lina Liu , Xiaolan Wei , Jianqiang Hu . Exploration of Subject-Oriented Undergraduate Comprehensive Chemistry Experimental Teaching Based on the “STS Concept”: Taking the Experiment of Gold Nanoparticles as an Example. University Chemistry, doi: 10.12461/PKU.DXHX202405112
19. [19]
  Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202312014
20. [20]
  Zhuo WANG , Xiaotong LI , Zhipeng HU , Junqiao PAN . Three-dimensional porous carbon decorated with nano bismuth particles: Preparation and sodium storage properties. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240223

Get Citation

PDF

XML

Metrics

PDF Downloads(1947)
Abstract views(4481)
HTML views(25)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142