Citation: YANG Yi, YE Wei, CHEN Xiao. Preparation and Controlled Assembly of Asymmetric Janus Particles[J]. Acta Physico-Chimica Sinica doi: 10.3866/PKU.WHXB201208222 shu

Preparation and Controlled Assembly of Asymmetric Janus Particles

1.
Key Laboratory for Colloid and Interface Chemistry, Ministry of Education, Shandong University, Jinan 250100, P. R. China

Received Date: 18 July 2012
Available Online: 22 August 2012
Fund Project: 国家自然科学基金(20973104, 21033005) (20973104, 21033005)山东省自然科学基金(2009ZRB01147)资助项目 (2009ZRB01147)

Janus particles have different or asymmetric hemispheres both in structure and chemical properties. These particles have attracted increasing attention because of their unique characteristics and potential in applications as drug carriers, electronic components, and stabilizers for emulsions. Controlled fabrication of organized aggregates using these Janus particles as novel building blocks is becoming well concerned. Several assembly strategies, including bulk, interfacial and environmental modulated organization, have been developed based on the amphiphilic modification and functionality of Janus particles. This review summarizes recent progress on the preparation, modification, and assembly techniques for Janus particles. Some novel methods, including one-step synthesis, self-assembly of polymers, and seed directed growth, are discussed in detail and compared. Trends for designing new functional Janus particles and their potential applications are identified.
- Janus particle,
- Surface modification,
- Asymmetry,
- Amphiphilicity,
- Assembly
1. [1]
  
  (1) De Gennes, P. G. Angew. Chem. Int. Edit. 1992, 31, 842.doi: 10.1002/(ISSN)1521-3773
2. [2]
  (2) Binks, B. P. Curr. Opinion Colloid Interface Sci. 2002, 7, 21.doi: 10.1016/S1359-0294(02)00008-0
3. [3]
  (3) Takei, H.; Shimizu, N. Langmuir 1997, 13, 1865.
4. [4]
  (4) Liang, F. X.; Liu, J. G.; Zhang, C. G.; Qu, X. Z.; Li, J. L.; Yang,Z. Z. Chem. Commun. 2011, 47, 1231. doi: 10.1039/c0cc03599h
5. [5]
  (5) Tanaka, T.; Okayama, M.; Minami, H.; Okubo, M. Langmuir2010, 26, 11732. doi: 10.1021/la101237c
6. [6]
  (6) Liu, Y.; Li,W.; Perez, T.; Gunton, J. D.; Brett, G. Langmuir2012, 28, 3. doi: 10.1021/la2032303
7. [7]
  (7) Choi, J. S. ; Jun, Y.W.; Yeon, S. I.; Kim, H. C.; Shin, J. S.;Cheon, J.W. J. Am. Chem. Soc. 2006, 128, 15982. doi: 10.1021/ja066547g
8. [8]
  (8) Jiang, S.; Chen, Q.; Tripathy, M.; Luijten, E.; Schweizer, K. S.;Granick, S. Adv. Mater. 2010, 22, 1060. doi: 10.1002/adma.200904094
9. [9]
  (9) Howse, J. R.; Jones, R. A.; Ryan, A. J.; ugh, T.; Vafabakhsh,R.; lestanian, R. Phys. Rev. Lett. 2007, 99, 048102. doi: 10.1103/PhysRevLett.99.048102
10. [10]
  (10) Dupont, J.; Liu, G. J. Soft Matter 2010, 6, 3654. doi: 10.1039/c0sm00044b
11. [11]
  (11) Tanaka, T.; Okayama, M.; Kitayama, Y.; Kagawa, Y.; Okubo, M.Langmuir 2010, 26, 7843. doi: 10.1021/la904701r
12. [12]
  (12) Wang, Q.; Yang, X. L.; Yang, Y. J.; Xu, H. B. Chin. J. Appl. Chem. 2010, 27, 745. [王芹, 杨祥良, 杨亚江, 徐辉碧. 应用化学, 2010, 27, 745.]
13. [13]
  (13) Chen, Y. H.;Wang, C. Y.; Li, Y.; Tong, Z. Prog. Chem. 2009, 21,615. [陈云华, 王朝阳, 李煜, 童真. 化学进展, 2009, 21,615.]
14. [14]
  (14) Lattuada, M.; Hatton, T. A. Nano Today 2011, 6, 286. doi: 10.1016/j.nantod.2011.04.008
15. [15]
  (15) Kim, S. H.; Lim, J. M.; Lee, S. K.; Heo, C. J.; Yang, S. M. Soft Matter 2010, 6, 1092. doi: 10.1039/b920611f
16. [16]
  (16) Yuan, Y.; Zhang, M. Z.; Zhang, H.; Ni, P. H. Acta Chim. Sin.2010, 68, 1537. [袁媛, 张明祖, 张虎, 倪沛红. 化学学报, 2010, 68, 1537.]
17. [17]
  (17) Lee, R. S.;Wu, K. P. J. Polymer Sci. Part A 2011, 49, 3163.doi: 10.1002/pola.24753
18. [18]
  (18) Perro, A.; Reculusa, S.; Ravaine, S.; Lami, E. B.; Duguet, E.J. Mater. Chem. 2005, 15, 3745. doi: 10.1039/b505099e
19. [19]
  (19) Erhardt, R.; Böker, A.; Zettl, H.; Kaya, H.; Hintzen,W. P.;Krausch, G.; Abetz, V.; Müller, A. Macromolecules 2001, 34,1069. doi: 10.1021/ma000670p
20. [20]
  (20) Liu, Y. F.; Abetz, V.; Müller, A. Macromolecules 2003, 36, 7894.doi: 10.1021/ma0345551
21. [21]
  (21) Walther, A.; André, X.; Drechsler, M.; Abetz, V.; Müller, A. H.E. J. Am. Chem. Soc. 2007, 129, 6187. doi: 10.1021/ja068153v
22. [22]
  (22) Walther, A.; Drechsler, M.; Müller, A. H. E. Soft Matter 2009, 5,385. doi: 10.1039/b812321g
23. [23]
  (23) Yu, H.; Chen, M.; Rice, P. M.;Wang, S. X.; White, R. L.; Sun,S. H. Nano Lett. 2005, 5, 378.
24. [24]
  (24) Wang, C.;Wei, Y. J.; Jiang, H. Y.; Sun, S. H. Nano Lett. 2009, 9,4544. doi: 10.1021/nl903077t
25. [25]
  (25) Huang, J. M.; Sun, Y. H.; Huang, S. H.; Yu, K.; Zhao, Q.; Peng,F.; Yu, H.;Wang, H. J.; Yang, J. J. Mater. Chem. 2011, 21,17930. doi: 10.1039/c1jm13045e
26. [26]
  (26) Kuang, H, M.; Deng, Z. X.; Li, C. H.; Sun, X. M.; Zhuang, J.;Li, Y. D. Acta Phys. -Chim. Sin. 2002, 18, 477. [匡汉茂, 邓兆祥, 李春辉, 孙晓明, 庄京, 李亚栋. 物理化学学报, 2002, 18,477.] doi: 10.3866/PKU.WHXB20020520
27. [27]
  (27) Mokari, T.; Sztrum, C. G.; Salant, A.; Rabani, E.; Banin, U. Nat. Mater. 2005, 4, 855. doi: 10.1038/nmat1505
28. [28]
  (28) Maynadié, J.; Salant, A.; Falqui, A.; Respaud, M.; Shaviv, E.;Banin, U.; Soulantica, K.; Chaudret, B. Angew. Chem . Int. Edit.2009, 48, 1814. doi: 10.1002/anie.v48:10
29. [29]
  (29) Wang, C.; Daimon, H.; Sun, S. H. Nano Lett. 2009, 9, 1493. doi: 10.1021/nl8034724
30. [30]
  (30) Habas, S. E.; Lee, H.; Yang, P. Nat. Mater. 2007, 6, 692. doi: 10.1038/nmat1957
31. [31]
  (31) Shi,W. L.; Zeng, H.; Sahoo, Y.; Ohulchanskyy, T. Y.; Ding, Y.;Wang, Z. L.; Swihart, M.; Prasad, P. N. Nano Lett. 2006, 6, 875.doi: 10.1021/nl0600833
32. [32]
  (32) Gu, H.W.; Zheng, R. K.; Zhang, X. X.; Xu, B. J. Am. Chem. Soc. 2004, 126, 5664. doi: 10.1021/ja0496423
33. [33]
  (33) Gu, H.W.; Yang, Z. M.; Gao, J. H.; Chang, C. K.; Xu, B. J. Am. Chem. Soc. 2005, 127, 34. doi: 10.1021/ja045220h
34. [34]
  (34) Hong, L.; Jiang, S.; Granick, S. Langmuir 2006, 22, 9495.doi: 10.1021/la062716z
35. [35]
  (35) Jiang, S.; Granick, S. Langmuir 2008, 24, 2438. doi: 10.1021/la703274a
36. [36]
  (36) Liu, B.; Zhang, C. L.; Liu, J. G.;Qu, X. Z.; Yang, Z. Z. Chem. Commun. 2009, 3871.
37. [37]
  (37) Liu, B.;Wei,W.; Qu, X. Z.; Yang, Z. Z. Angew. Chem. Int. Edit.2008, 47, 3973.
38. [38]
  (38) Suzuki, D.; Tsuji, S.; Kawaguchi, H. J. Am. Chem. Soc. 2007,129, 8088. doi: 10.1021/ja072258w
39. [39]
  (39) Duan, C. Y.; Zhou, J. F.;Wu, Z. S.; Dang, H. X. Acta Phys. -Chim. Sin. 2003, 19, 1049. [段春英, 周静芳, 吴志申,党鸿辛. 物理化学学报, 2003, 19, 1049.] doi: 10.3866/PKU.WHXB20031113
40. [40]
  (40) Wang, B. B.; Li, B.; Zhao, B.; Li, C. Y. J. Am. Chem. Soc. 2008,130, 11594. doi: 10.1021/ja804192e
41. [41]
  (41) Zhang, L.; Zhang, F.; Dong,W. F.; Song, J. F.; Huo, Q. S.; Sun,H. B. Chem. Commun. 2011, 47, 1225. doi: 10.1039/c0cc03946b
42. [42]
  (42) Li, Z. T.; Cheng, E. J.; Huang,W. X.; Zhang, T.; Yang, Z. Q.;Liu, D. S.; Tang, Z. Y. J. Am. Chem. Soc. 2011, 133, 15284.doi: 10.1021/ja205712a
43. [43]
  (43) Chen, T.; Yang, M. X.;Wang, X. J.; Tan, L. H.; Chen, H. Y.J. Am. Chem. Soc. 2008, 130, 11858. doi: 10.1021/ja8040288
44. [44]
  (44) Chen, T.; Chen, G.; Xing, S. G.;Wu, T.; Chen, H. Y. Chem. Mater. 2010, 22, 3826. doi: 10.1021/cm101155v
45. [45]
  (45) Jiang, S.; Schultz, M. J.; Chen, Q.; Moore, J. S.; Granick, S.Langmuir 2008, 24, 10073. doi: 10.1021/la800895g
46. [46]
  (46) Perro, A.; Reculusa, S.; Pereira, F.; Delville, M. H.; Min taud,C.; Duguet, E.; Lami, E. B.; Ravaine, S. Chem. Commun. 2005,5542.
47. [47]
  (47) Liu, L. Y.; Ren, M.W.; Yang,W. T. Langmuir 2009, 25, 11048.doi: 10.1021/la901364a
48. [48]
  (48) Teo, B. M.; Suh, S. K.; Hatton, T. A.; Ashokkumar, M.; Grieser,F. Langmuir 2011, 27, 30. doi: 10.1021/la104284v
49. [49]
  (49) Liang, F. X.; Shen, K.; Qu, X. Z.; Zhang, C. L.;Wang, Q.; Li, J.L.; Liu, J. G.; Yang, Z. Z.; Angew. Chem. Int. Edit. 2011, 123,2427.
50. [50]
  (50) Hong, L.; Cacciuto, A.; Luijten, E.; Granick, S. Langmuir 2008,24, 621. doi: 10.1021/la7030818
51. [51]
  (51) Dendukuri, D.; Hatton, T. A.; Doyle, P. S. Langmuir 2007, 23,4669. doi: 10.1021/la062512i
52. [52]
  (52) Biji, P.; Sarangi, N. K.; Patnaik, A. Langmuir 2010, 26, 14047.doi: 10.1021/la102371v
53. [53]
  (53) Chen, Q.; Whitmer, J. K.; Jiang, S.; Bae, S. C.; Luijten, E.;Granick, S. Science 2011, 331, 199. doi: 10.1126/science.1197451
54. [54]
  (54) Rosenthal, G.; Gubbins, K, E.; Klapp, S. H. L. J. Chem. Phys.2012, 136, 174901. doi: 10.1063/1.4707954
55. [55]
  (55) Zhao, N. N.; Liu, K.; Greener, J.; Nie, Z.; Kumacheva, E. Nano Lett. 2009, 9, 3077. doi: 10.1021/nl901567a
56. [56]
  (56) Zhao, N. N.; Vickery, J.; Guerin, G.; Park, J. I.;Winnik, M. A.;Kumacheva, E. Angew. Chem. Int. Edit. 2011, 50, 4606. doi: 10.1002/anie.201004915
57. [57]
  (57) Herrikhuyzen, J. V.; Portale, G.; Gielen, J. C.; Christianen, P. C.M.; Sommerdijk, N. A. J. M.; Meskers, S. C. J.; Schenning, A.P. H. J. Chem. Commun. 2008, 697.
58. [58]
  (58) Nørgaard, K.;Weygand, M.; Kjaer, K.; Brust, M.; Bjørnholm, T.Faraday Discuss. 2004, 125, 221. doi: 10.1039/b303117a
59. [59]
  (59) Xu, Q.; Kang, X.W.; Bo molni, R. A.; Chen, S.W. Langmuir2010, 26, 14923. doi: 10.1021/la102540n
60. [60]
  (60) He, J.; Hourwitz, M. J.; Liu, Y. J.; Perez, M. T.; Nie, Z. H.Chem. Commun. 2011, 47, 12450. doi: 10.1039/c1cc15603a
61. [61]
  (61) Guo, Y. Y.; Saei, S. H.; Izumi, C. M. S.; Moffitt, M. G. ACS Nano 2011, 3309.
62. [62]
  (62) Cheng, L.; Zhang, G. Z.; Zhu, L.; Dao, Y.; Chen, D. Y.; Jiang,M. Angew. Chem. Int. Edit. 2008, 47, 10171. doi: 10.1002/anie.v47:52
63. [63]
  (63) Walther, A.; Drechsler, M.; Rosenfeldt, S.; Harnau, L.; Ballauff,M.; Abetz, V.; Müller, A. H. E. J. Am. Chem. Soc. 2009, 131,4720. doi: 10.1021/ja808614q
64. [64]
  (64) Isojima, T.; Lattuada, M.; Vander Sande, J. B.; Hatton, T. A.ACS Nano 2008, 9, 1799.
65. [65]
  (65) Binks, B. P.; Lumsdon, S. O. I. Langmuir 2001, 17, 4540. doi: 10.1021/la0103822
66. [66]
  (66) Jiang, S.; Granick, S. J. Chem. Phys. 2007, 127, 161102. doi: 10.1063/1.2803420
67. [67]
  (67) Cheung, D. L.; Bon, S. Soft Matter 2009, 5, 3969. doi: 10.1039/b908462b
68. [68]
  (68) Miller,W. L.; Cacciuto, A. Phys. Rev. E 2009, 80, 1539.
69. [69]
  (69) Yang, M.;Wang,W.; Lieberwirth, I.;Wegner, G. J. Am. Chem. Soc. 2009, 131, 6283. doi: 10.1021/ja900739e
70. [70]
  (70) Brugarolas, T.; Park, B. J.; Lee, M. H.; Lee, D. Adv. Funct. Mater. 2011, 21, 3924. doi: 10.1002/adfm.v21.20
71. [71]
  (71) Sashuk, V.; Holyst, R.;Wojciechowski, T.; Fialkowski, M.J. Colloid Interface Sci. 2012, 375, 180. doi: 10.1016/j.jcis.2012.02.057
72. [72]
  (72) Ruhland, T. M.; Gröschel, A. H.;Walther, A.; Müller, A.Langmuir 2011, 27, 9807. doi: 10.1021/la201863x
73. [73]
  (73) Park, B. J.; Brugarolas, T.; Lee, D. Soft Matter 2011, 7, 6413.doi: 10.1039/c1sm05460k
74. [74]
  (74) Wang, Y. Z.; Fan, D. Q.; He, J. P.; Yang, Y. L. Colloid Polym. Sci. 2011, 289, 1885. doi: 10.1007/s00396-011-2506-9
75. [75]
  (75) Virgilio, N.; Favis, B. D. Macromolecules 2011, 44, 5850. doi: 10.1021/ma200647t
76. [76]
  (76) Yin, Y. Y.; Zhou, S. X.; You, B.;Wu, L. M. J. Polym. Sci. Part A2011, 49, 3272. doi: 10.1002/pola.v49.15
77. [77]
  (77) Gangwal, S.; Cayre, O. J.; Velev, O. D. Langmuir 2008, 24,13312.
78. [78]
  (78) Kretzschmar, I.; Song, J. H. Curr. Opin. Colloid Interface Sci.2011, 16, 84. doi: 10.1016/j.cocis.2011.01.002
79. [79]
  (79) Yuet, K. P.; Hwang, D. K.; Hagh oie, R.; Doyle, P. S.Langmuir 2010, 26, 4281. doi: 10.1021/la903348s
80. [80]
  (80) Smoukov, S. K.; Gangwal, S.; Marquez, M.; Velev, O. D. Soft Matter 2009, 5, 1285. doi: 10.1039/b814304h
81. [81]
  (81) Ren, B.; Ruditskiy, A.; Song, J. H.; Kretzschmar, I. Langmuir2012, 28, 1149. doi: 10.1021/la203969f
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