Citation: ZHENG Ning, ZHU Chun-Mei, SUN Bin, SHI Zu-Jin, LIU Yan, WANG Yuan. Nanocomposite Cathode Catalyst with High Methanol Tolerance and Durability[J]. Acta Physico-Chimica Sinica, ;2012, 28(10): 2263-2268. doi: 10.3866/PKU.WHXB201208171 shu

Nanocomposite Cathode Catalyst with High Methanol Tolerance and Durability

1.
Beijing National Laboratory for Molecular Sciences, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China

Received Date: 9 July 2012
Available Online: 17 August 2012
Fund Project: 国家自然科学基金(20803001, 20973003, 51121091, 21133001) (20803001, 20973003, 51121091, 21133001)国家重点基础研究专项经费(2011CB808702)资助。 (2011CB808702)

We report the preparation, characterization and elelctrocatalytic properties of a novel nanocomposite cathode catalyst (TiOPc-Pt/NSWCNH) which is assembled using Pt nanoclusters, TiOPc nanocrystal, and nitrogen-doped single walled carbon nanohorns (NSWCNHs) as building blocks. TiOPc-Pt/NSWCNH is characterized by inserting most of the Pt nanoparticles in nano-networks formed by stacking of NSWCNHs, and contacting of a part of the Pt nanoparticles with TiOPc nanocrystals. TiOPc-Pt/NSWCNH exhibits high electrocatalytic activity, excellent selectivity and durability for oxygen reduction reaction (ORR) in the presence of methanol. In an O₂-saturated HClO₄ aqueous solution containing methanol (0.5 mol·L^-1), the onset potential over the TiOPc-Pt/NSWCNH catalyst shifted by more than 260 mV toward positive relative to that over a commercial Pt/C-JM catalyst. The mass activity and specific activity for ORR over TiOPc-Pt/NSWCNH at 0.85 V (versus a reversible hydrogen electrode (RHE)) was 83.5 A·g^-1 and 0.294 mA·cm^-2, respectively, which were much higher than those of Pt/C-JM. Cyclic voltammetry accelerated aging tests (0.6-1.0 V for 15000 cycles) in an O₂-saturated HClO₄ aqueous solution containing methanol revealed that TiOPc-Pt/NSWCNH possessed a higher durability compared to TiOPc-Pt/C. The high methanol tolerance of TiOPc-Pt/NCNH may be mainly derived from the electron transfer from TiOPc nanocrystals to Pt nanoparticles. The nano-network and the high graphitization degree of NSWCNHs are responsible for the excellent durability of TiOPc-Pt/NSWCNH.
- Nanocomposite catalyst,
- Nitrogen-doped carbon nanohorns,
- Phthalocyanine,
- Durability,
- Methanol tolerance,
- Cathode of direct methanol fuel cells
1. [1]
  
  (1) Shao, M. H.; Sasaki, K.; Adzic, R. R. J. Am. Chem. Soc. 2006,128, 3526. doi: 10.1021/ja060167d
2. [2]
  (2) Liu, Y.; Zheng, N.; Chao,W.; Liu, H.;Wang, Y. Electrochim. Acta 2010, 55, 5617. doi: 10.1016/j.electacta.2010.04.092
3. [3]
  (3) Li,W. Z.; Zhou,W. J.; Li, H. Q.; Zhou, Z. H.; Zhou, B.; Sun, G.Q.; Xin, Q. Electrochim. Acta 2004, 49, 1045. doi: 10.1016/j.electacta.2003.10.015
4. [4]
  (4) Gao, M. R.; Gao, Q.; Jiang, J.; Cui, C. H.; Yao,W. T.; Yu, S. H.Angew. Chem. Int. Edit. 2011, 50, 4905. doi: 10.1002/anie.v50.21
5. [5]
  (5) Wang,W. M.; Huang, Q. H.; Liu, J. Y.; Zou, Z. Q.; Zhao, M. Y.;Vogel,W.; Yang, H. J. Catal. 2009, 266, 156. doi: 10.1016/j.jcat.2009.06.004
6. [6]
  (6) Liu, S. H.; Zheng, F. S.;Wu, J. R. Appl. Catal. B: Environ.2011, 81, 108.
7. [7]
  (7) Wen, Z. H.; Liu, J.; Li, J. H. Adv. Mater. 2008, 20, 745.
8. [8]
  (8) Jasinski, R. Nature 1964, 201, 1212. doi: 10.1038/2011212a0
9. [9]
  (9) Vante, N. A.; Tributsch, H. Nature 1986, 323, 431. doi: 10.1038/323431a0
10. [10]
  (10) Liu, Y.; Ishihara, A.; Mitsushima, S.; Kamiya, N.; Ota, K.J. Electrochem. Soc. 2007, 154, B664.
11. [11]
  (11) Zheng, Y.; Jiao, Y.; Chen, J.; Liu, J.; Liang, J.; Du, A. J.; Zhang,W. M.; Zhu, Z. H.; Smith, S. C.; Jaroniec, M.; Lu, G. Q.; Qiao,S. Z. J. Am. Chem. Soc. 2011, 133, 20116. doi: 10.1021/ja209206c
12. [12]
  (12) Li, X. G.; Han, F.; Xing,W.; Tang, Y.W.; Lu, T. H. Acta Phys. -Chim. Sin. 2003, 19, 380. [李旭光, 韩飞, 邢巍,唐亚文, 陆天虹. 物理化学学报, 2003, 19, 380.] doi: 10.3866/PKU.WHXB20030422
13. [13]
  (13) Kwon, K. Y. J.; Sa, Y. J.; Cheon, J. Y.; Joo, S. H. Langmuir2012, 28, 991. doi: 10.1021/la204130e
14. [14]
  (14) Zheng, N.; Liu, Y.;Wang, Y. Chem. Res. Chin. Univ. 2011, 32,748.
15. [15]
  (15) Iijima, S. Nature 1991, 354, 56. doi: 10.1038/354056a0
16. [16]
  (16) Yoshitake, T.; Shimakawa,Y.; Kuroshima, S.; Kimura, H.;Ichihashi, T.; Kubo, Y.; Kasuya, D.; Takahashi, K.; Kokai, F.;Yudasaka, M.; Iijima, S. Physica B: Condensed Matter 2002,323, 124. doi: 10.1016/S0921-4526(02)00871-2
17. [17]
  (17) Kosaka, M.; Kuroshima, S.; Kobayashi, K.; Sekino, S.;Ichihashi, T.; Nakamura, S.; Yoshitake, T.; Kubo, Y. J. J. Phys. Chem. C 2009, 113, 8660.
18. [18]
  (18) Zhou, Y. K.; Neyerlin, K.; Olson,T. S.; Pylypenko, S.; Bult, J.;Dinh, H. N.; Gennett, T.; Shao, Z. P.; O'Hayre, R. Energy Environ. Sci. 2010, 3, 1437. doi: 10.1039/c003710a
19. [19]
  (19) Ma, G. X.; Jia, R. G.; Zhao, J. H.;Wang, Z. J.; Song, C.; Jia, S.P.; Zhu, Z. P. J. Phys. Chem. C 2011, 115, 25148. doi: 10.1021/jp208257r
20. [20]
  (20) Zhao, Y. C.; Zhan, L.; Tian, J. N.; Nie, S. L.; Ning, Z. Acta Phys. -Chim. Sin. 2011, 27, 91. [赵彦春, 占璐, 田建袅,聂素连, 宁珍. 物理化学学报, 2011, 27, 91.] doi: 10.3866/PKU.WHXB20110128
21. [21]
  (21) Zhang, L.W.; Zheng, N.; Gao, A.; Zhu, C. M.;Wang, Z. Y.;Wang, Y.; Shi, Z. J.; Liu, Y. J. Power Sources doi: 10.1016/j.jpowsour.2012.08.009.
22. [22]
  (22) Li, N.;Wang, Z. Y.; Zhao, K. K.; Shi, Z. J.; Gu, Z. N.; Xu, S. K.Carbon 2010, 48, 1580. doi: 10.1016/j.carbon.2009.12.055
23. [23]
  (23) Liang, D. J.; Peng,W. L.;Wang, Y. Adv. Mater. doi: 10.1002/adma.201201720
24. [24]
  (24) Wang, Y.; Deng, K.; Gui, L. L.; Tang, Y. Q.; Zhou, J.W.; Cai, L.Y.; Qiu, J. B.; Ren, D. Y.;Wang, Y. Q. J. Colloid Interface Sci.1999, 213, 270. doi: 10.1006/jcis.1999.6132
25. [25]
  (25) Wang, Y.; Ren, J.W.; Deng, K.; Gui, L. L.; Tang, Y. Q. Chem. Mater. 2000, 12, 1622. doi: 10.1021/cm0000853
26. [26]
  (26) Pylypenko, S.; Queen, A.; Olson, T. S.; Dameron, A.; O'Neill,K.; Neyerlin, K.; Pivovar, B.; Dinh, H. N.; Ginley, D. S.;Gennett, T. J. Phys. Chem. C 2011, 115, 13676. doi: 10.1021/jp112236n
27. [27]
  (27) Enokida, T.; Hirohashi, R.; Nakamura, T. J. Imaging Sci. 1990,34, 234.
28. [28]
  (28) Sheppard, S. A.; Campbell, S. A.; Smith, J. R.; Lloyd, G.W.;Ralph, T. R.;Walsh, F. C. Analyst 1998, 123, 1923. doi: 10.1039/a803310b
29. [29]
  (29) Michaelson, H. B. J. Appl. Phys. 1977, 48, 4729. doi: 10.1063/1.323539
30. [30]
  (30) Ma, Y.;Wen, Y. Q.;Wang, J. X.; Shang, Y. L.; Du, S. S.; Pan, L.D.; Li, G.; Yang, L. M.; Gao, H. J.; Song, Y. L. J. Phys. Chem. C2009, 113, 8548.
1. [1]
  Shitao Fu , Jianming Zhang , Cancan Cao , Zhihui Wang , Chaoran Qin , Jian Zhang , Hui Xiong . Study on the Stability of Purple Cabbage Pigment. University Chemistry, 2024, 39(4): 367-372. doi: 10.3866/PKU.DXHX202401059
2. [2]
  Jiaxi Xu , Yuan Ma . Influence of Hyperconjugation on the Stability and Stable Conformation of Ethane, Hydrazine, and Hydrogen Peroxide. University Chemistry, 2024, 39(11): 374-377. doi: 10.3866/PKU.DXHX202402049
3. [3]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
4. [4]
  Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H₂ production activity of BaTiO₃ nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
5. [5]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
6. [6]
  Xuyang Wang , Jiapei Zhang , Lirui Zhao , Xiaowen Xu , Guizheng Zou , Bin Zhang . Theoretical Study on the Structure and Stability of Copper-Ammonia Coordination Ions. University Chemistry, 2024, 39(3): 384-389. doi: 10.3866/PKU.DXHX202309065
7. [7]
  Xiaoning TANG , Junnan LIU , Xingfu YANG , Jie LEI , Qiuyang LUO , Shu XIA , An XUE . Effect of sodium alginate-sodium carboxymethylcellulose gel layer on the stability of Zn anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1452-1460. doi: 10.11862/CJIC.20240191
8. [8]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
9. [9]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
10. [10]
  Dan Li , Hui Xin , Xiaofeng Yi . Comprehensive Experimental Design on Ni-based Catalyst for Biofuel Production. University Chemistry, 2024, 39(8): 204-211. doi: 10.3866/PKU.DXHX202312046
11. [11]
  Jing SU , Bingrong LI , Yiyan BAI , Wenjuan JI , Haiying YANG , Zhefeng Fan . Highly sensitive electrochemical dopamine sensor based on a highly stable In-based metal-organic framework with amino-enriched pores. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1337-1346. doi: 10.11862/CJIC.20230414
12. [12]
  Jinyi Sun , Lin Ma , Yanjie Xi , Jing Wang . Preparation and Electrocatalytic Nitrogen Reduction Performance Study of Vanadium Nitride@Nitrogen-Doped Carbon Composite Nanomaterials: A Recommended Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(4): 184-191. doi: 10.3866/PKU.DXHX202310094
13. [13]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
14. [14]
  Shuang Yang , Qun Wang , Caiqin Miao , Ziqi Geng , Xinran Li , Yang Li , Xiaohong Wu . Ideological and Political Education Design for Research-Oriented Experimental Course of Highly Efficient Hydrogen Production from Water Electrolysis in Aerospace Perspective. University Chemistry, 2024, 39(11): 269-277. doi: 10.12461/PKU.DXHX202403044
15. [15]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
16. [16]
  Chi Li , Jichao Wan , Qiyu Long , Hui Lv , Ying Xiong . N-Heterocyclic Carbene (NHC)-Catalyzed Amidation of Aldehydes with Nitroso Compounds. University Chemistry, 2024, 39(5): 388-395. doi: 10.3866/PKU.DXHX202312016
17. [17]
  Jingzhao Cheng , Shiyu Gao , Bei Cheng , Kai Yang , Wang Wang , Shaowen Cao . 4-氨基-1H-咪唑-5-甲腈修饰供体-受体型氮化碳光催化剂的构建及其高效光催化产氢研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406026-. doi: 10.3866/PKU.WHXB202406026
18. [18]
  Jingke LIU , Jia CHEN , Yingchao HAN . Nano hydroxyapatite stable suspension system: Preparation and cobalt adsorption performance. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1763-1774. doi: 10.11862/CJIC.20240060
19. [19]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349
20. [20]
  Fengqiao Bi , Jun Wang , Dongmei Yang . Specialized Experimental Design for Chemistry Majors in the Context of “Dual Carbon”: Taking the Assembly and Performance Evaluation of Zinc-Air Fuel Batteries as an Example. University Chemistry, 2024, 39(4): 198-205. doi: 10.3866/PKU.DXHX202311069

Get Citation

PDF

XML

Metrics

PDF Downloads(746)
Abstract views(2097)
HTML views(6)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142