Citation: ZHU Xu-Fei, HAN Hua, MA Hong-Tu, LU Chao, QI Wei-Xing, XU Chen. Influence of Reducer on the Nanopore Structure of Porous Anodic Alumina[J]. Acta Physico-Chimica Sinica doi: 10.3866/PKU.WHXB201208151 shu

Influence of Reducer on the Nanopore Structure of Porous Anodic Alumina

ZHU Xu-Fei ^1, ,
HAN Hua ^2, ,
MA Hong-Tu ² ,
LU Chao ¹ ,
QI Wei-Xing ¹ ,
XU Chen ¹

1.
1 Key Laboratory of Soft Chemistry and Functional Materials of Education Ministry, Nanjing University of Science & Technology, Nanjing 210094, P. R. China;
2 The National Engineering and Technology Research Center for ASIC Design, Institute of Automation, Chinese Academy of Sciences, Beijing 100190, P. R. China

Received Date: 28 May 2012
Available Online: 15 August 2012
Fund Project: 国家自然科学基金(61171043, 51077072) (61171043, 51077072)国家科技重大专项资金(2009ZX01021-002)资助项目 (2009ZX01021-002)

In recent years, attention has been focused on adjustment and control of the nanostructures of porous anodic alumina (PAA) and porous anodic TiO₂ nanotubes (PATNT). Because the formation mechanism of PAA and PATNT is still unclear, it is difficult to adjust the nanostructures of PAA and PATNT. To validate the novel viewpoint of the nanopore resulting from an oxygen bubble mold, an innovative chemical approach was used to adjust the PAA nanostructures. One successful approach is to use a reducer to absorb the oxygen bubbles in the nanopores. A novel anodic alumina film was obtained in a mixed solution of the reducer and oxalic acid. The influence of the reducer on the PAA nanostructures which formed in H₃PO₄ solution was investigated in detail. The experimental results showed that the regularity and the diameters of the nanopores in the PAA decreased as the reducer content increased. The differences in the voltage-time curves between electrolytes with and without the reducer were analyzed quantitatively. The results showed that the conductivity of the anodic oxide film that formed in the electrolyte with the reducer was better than that in the electrolyte without the reducer. When aluminum anodizes in a sealed case, oxygen bubbles are easily absorbed by the reducer, the oxygen bubble mold effect disappears, and a compact alumina film is obtained. Overall, these results clearly demonstrate that nanopores result from the oxygen bubble mold effect.
- Nanoporous material,
- Anodization,
- Electrolyte,
- Reducer,
- Formation mechanism
1. [1]
  
  (1) Zhang, H.; Hu, Y. J.;Wu, P.; Zhang, H.; Cai, C. X. Acta Phys. -Chim. Sin. 2012, 28, 1545. [张华, 胡耀娟, 吴萍,张卉, 蔡称心. 物理化学学报, 2012, 28, 1545.] doi: 10.3866/PKU.WHXB201203026
2. [2]
  (2) Zhang,W. G.; Shang, Y. P.; Liu, L. N.; Yao, S.W.;Wang, H. Z.Acta Phys. -Chim. Sin. 2011, 27, 900. [张卫国, 尚云鹏, 刘丽娜, 姚素薇, 王宏智. 物理化学学报, 2011, 27, 900.] doi: 10.3866/PKU.WHXB20110344
3. [3]
  (3) Guo, Y. Y.;Wang, M.; Mao, X. B.; Jiang, Y. X.;Wang, C.; Yang,Y. L. Acta Phys. -Chim. Sin. 2010, 26, 2037. [郭元元, 汪明,毛晓波, 蒋月秀, 王琛, 杨延莲. 物理化学学报, 2010, 26,2037.] doi: 10.3866/PKU.WHXB20100734
4. [4]
  (4) Santos, A.; Balderrama, V. S.; Alba, M.; Formentin, P.; Ferre-Borrull, J.; Pallarès, J.; Marsal, L. F. Adv. Mater. 2012, 24, 1050.doi: 10.1002/adma.v24.8
5. [5]
  (5) Chen,W.; Jin, B.; Hu, Y. L.; Lu, Y.; Xia, X. H. Small 2012, 7,1001.
6. [6]
  (6) Ding, J. N.; Zhu, Y.; Yuan, N. Y.; Ding, G. Q. Thin Solid Films2012, 520, 4321. doi: 10.1016/j.tsf.2012.02.030
7. [7]
  (7) Dong, H. Q.; Pan, X.; Xie, Q.; Meng, Q. Q.; Gao, J. R.;Wang, J.G. Acta Phys. -Chim. Sin. 2012, 28, 44. [董华青, 潘西,谢琴, 孟强强, 高建荣, 王建国. 物理化学学报, 2012, 28,44.] doi: 10.3866/PKU.WHXB20122844
8. [8]
  (8) Li, H. H.; Chen, R. F.; Ma, C.; Zhang, S. L.; An, Z. F.; Huang,W. Acta Phys. -Chim. Sin. 2011, 27, 1017. [李欢欢, 陈润锋,马琮, 张胜兰, 安众福, 黄维. 物理化学学报, 2011, 27,1017.] doi: 10.3866/PKU.WHXB20110514
9. [9]
  (9) Wang, D. A.; Yu, B.;Wang, C.W.; Zhou, F.; Liu,W. M. Adv. Mater. 2009, 21, 1964. doi: 10.1002/adma.v21:19
10. [10]
  (10) Li, D. D.; Zhao, L.; Jiang, C. H.; Lu, J. G. Nano Lett. 2010, 10,2766. doi: 10.1021/nl1004493
11. [11]
  (11) Lin, J.; Chen, J. F.; Chen, X. F. Electrochem. Commun. 2010,12, 1062. doi: 10.1016/j.elecom.2010.05.027
12. [12]
  (12) Lee, K.; Kim, D.; Roy, P.; Paramasivam, I.; Birajdar, B. I.;Spiecker, E.; Schmuki, P. J. Am. Chem. Soc. 2010, 132, 1478.doi: 10.1021/ja910045x
13. [13]
  (13) Xu, X. J.; Fang, X. S.; Zhai, T. Y.; Zeng, H. B.; Liu, B. D.; Hu,X. Y.; Bando, Y.; lberg, D. Small 2011, 7, 445. doi: 10.1002/smll.201001849
14. [14]
  (14) Lee,W.; Ji, R.; Gösele, U.; Pippel, E.; Nielsch, K. Nat. Mater.2006, 5, 741. doi: 10.1038/nmat1717
15. [15]
  (15) Lee,W.; Schwirn, K.; Steinhart, M.; Pippel, E.; Scholz, R.;Gösele, U. Nat. Nanotechnol. 2008, 3, 234. doi: 10.1038/nnano.2008.54
16. [16]
  (16) Ye, Q. M.; Song, Y.; Liu, P.; Hu, J. J. Prog. Chem. 2011, 23,2617. [叶秋梅, 宋晔, 刘鹏, 胡隽隽. 化学进展, 2011, 23,2617.]
17. [17]
  (17) Li, S. Q.; Yin, J. B.; Zhang, G. M. Sci. China Chem. 2010, 53,1068. [李仕琦, 尹建波, 张耿民. 中国科学: 化学, 2010, 53,1068.] doi: 10.1007/s11426-010-0155-3
18. [18]
  (18) Lin, J.; Liu, K.; Chen, X. F. Small 2011, 7, 1784. doi: 10.1002/smll.v7.13
19. [19]
  (19) Li, Y.; Ling, Z. Y.; Hu, X.; Liu, Y. S.; Chang, Y. J. Mater. Chem.2011, 21, 9661. doi: 10.1039/c1jm10781j
20. [20]
  (20) Li, Y.; Ling, Z. Y.; Hu, X.; Liu, Y. S.; Chang, Y. Chem. Commun. 2011, 47, 2173. doi: 10.1039/c0cc04907g
21. [21]
  (21) Bolger, C. T.; Fois, G.; Petkov, N.; Sassiat, N.; Burke, M.;Quinn, A. J.; Cross, G. L.W.; Holmes, J. D. Nanotechnology2012, 23, 175602. doi: 10.1088/0957-4484/23/17/175602
22. [22]
  (22) Sulka, G. D.; Hnida, K. Nanotechnology 2012, 23, 075303.doi: 10.1088/0957-4484/23/7/075303
23. [23]
  (23) Cui, J.W.;Wu, Y. C.;Wang, Y.; Zheng, H. M.; Xu, G. Q.;Zhang, X. Y. Appl. Surf. Sci. 2012, 258, 5305. doi: 10.1016/j.apsusc.2012.01.099
24. [24]
  (24) Holubowitch, N.; Nagle, L. C.; Rohan, J. F. Solid State Ionics2012, 216, 110. doi: 10.1016/j.ssi.2012.03.016
25. [25]
  (25) Romero, V.; Vega, V.; García, J.; Prida, V. M.; Hernando, B.;Benavente, J. J. Colloid Interface Sci. 2012, 376, 40. doi: 10.1016/j.jcis.2012.02.066
26. [26]
  (26) Roy, P.; Berger, S.; Schmuki, P. Angew. Chem. Int. Edit. 2011,50, 2904. doi: 10.1002/anie.201001374
27. [27]
  (27) Su, Z. X.; Zhou,W. Z. J. Mater. Chem. 2011, 21, 8955. doi: 10.1039/c0jm04587j
28. [28]
  (28) Mazzarolo, A.; Curioni, M.; Vicenzo, A.; Skeldon, P.;Thompson, G. E. Electrochim. Acta 2012, 75, 288. doi: 10.1016/j.electacta.2012.04.114
29. [29]
  (29) Re nini, D.; Satka, A.; Jaroenworaluck, A.; Allsopp, D.W. E.;Bowen, C. R.; Stevens, R. Electrochim. Acta 2012, 74, 244.doi: 10.1016/j.electacta.2012.04.076
30. [30]
  (30) Li, Y.; Ling, Z. Y.; Hu, X.; Liu, Y. S.; Chang, Y. RSC Adv. 2012,2, 5164. doi: 10.1039/c2ra01050j
31. [31]
  (31) Patermarakis, G.; Diakonikolaou, J. J. Solid State Electrochem.2012, doi: 10.1007/s10008-012-1683-x
32. [32]
  (32) Zhu, X. F.; Han, H.; Song, Y.; Duan,W. Q. Acta Phys. -Chim. Sin. 2012, 28, 1291. [朱绪飞, 韩华, 宋晔, 段文强. 物理化学学报, 2012, 28, 1291.] doi: 10.3866/PKU.WHXB201204093
33. [33]
  (33) Wang, F.;Wei, Q. S.; Zhang, Y. L.;Wu, K.; Xie, Y. C. Acta Phys. -Chim. Sin. 2004, 20, 1134. [王凡, 卫庆硕, 张玉玲,吴凯, 谢有畅. 物理化学学报, 2004, 20, 1134.] doi: 10.3866/PKU.WHXB20040915
34. [34]
  (34) Yin, Y. X.; Jin, Z. G.; Tan, X.; Hou, F.; Zhao, L. Acta Phys. -Chim. Sin. 2008, 24, 2133. [阴育新, 靳正国, 谭欣,侯峰, 赵林. 物理化学学报, 2008, 24, 2133.] doi: 10.3866/PKU.WHXB20081133
35. [35]
  (35) Zhu, X. F.; Liu, L.; Song, Y.; Jia, H.; Yu, H.; Xiao, X.; Yang, X.L. Monatsh. Chem. 2008, 139, 999. doi: 10.1007/s00706-008-0893-5
36. [36]
  (36) Zhu, X. F.; Song, Y.; Liu, L.;Wang, C.; Zheng, J.; Jia, H.;Wang,X. Nanotechnology 2009, 20, 475303. doi: 10.1088/0957-4484/20/47/475303
37. [37]
  (37) Coz, F. L.; Arurault, L.; Datas, L. Mater. Charact. 2010, 61,283. doi: 10.1016/j.matchar.2009.12.008
38. [38]
  (38) nzalez-Rovira, L.; Lopez-Haro, M.; Hungria, A. B.; Amrani,E. K.; Sanchez, J. M.; Calvino, J. J.; Botana, F. J. Corrosion Sci.2010, 52, 3763. doi: 10.1016/j.corsci.2010.07.027
39. [39]
  (39) Skeldon, P.; Thompson, G. E.; Garcia-Vergara, S. J.; Iglesias-Rubianes, L.; Blanco-Pinzon, C. E. Electrochem. Solid St. 2006,9, B47.
40. [40]
  (40) Garcia-Vergara, S. J.; Skeldon, P.; Thompson, G. E.; Habazaki,H. Electrochim. Acta 2006, 52, 681. doi: 10.1016/j.electacta.2006.05.054
41. [41]
  (41) Zhu, X. F.; Song, Y.; Yu, H. D; Jia, H. B.; Yang, X. L.; Xiao, Y.H.; Lu, L. D.;Wang, X. Chinese Journal of Vacuum Science and Technology 2009, 29, 90. [朱绪飞, 宋晔, 俞华栋, 贾红兵,杨修丽, 肖迎红, 陆路德, 汪信. 真空科学与技术学报, 2009,29, 90.]
42. [42]
  (42) Schwirn, K.; Lee,W.; Hillebrand, R.; Steinhart, M.; Nielsch, K.;Gösele, U. ACS Nano 2008, 2, 302. doi: 10.1021/nn7001322
43. [43]
  (43) Lee,W.; Scholz, R.; Gösele, U. Nano Lett. 2008, 8, 2155.doi: 10.1021/nl080280x
44. [44]
  (44) Patermarakis, G.; Moussoutzanis, K. Electrochim. Acta 2009,54, 2434. doi: 10.1016/j.electacta.2008.11.064
45. [45]
  (45) Zhu, X. F.; Liu, L.; Zhao, B. C. The Chinese Journal of Nonferrous Metals 2003, 13, 1031. [朱绪飞, 刘霖, 赵宝昌.中国有色金属学报, 2003, 13, 1031.] doi: 10.3321/j.issn:1004-0609.2003.04.042
1. [1]
  Shengjuan Huo , Xiaoyan Zhang , Xiangheng Li , Xiangning Li , Tianfang Chen , Yuting Shen . Unveiling the Marvels of Titanium: Popularizing Multifunctional Colored Titanium Product Films. University Chemistry, doi: 10.3866/PKU.DXHX202310127
2. [2]
  Jiahe LIU , Gan TANG , Kai CHEN , Mingda ZHANG . Effect of low-temperature electrolyte additives on low-temperature performance of lithium cobaltate batteries. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20250023
3. [3]
  Aoyu Huang , Jun Xu , Yu Huang , Gui Chu , Mao Wang , Lili Wang , Yongqi Sun , Zhen Jiang , Xiaobo Zhu . Tailoring Electrode-Electrolyte Interfaces via a Simple Slurry Additive for Stable High-Voltage Lithium-Ion Batteries. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202408007
4. [4]
  Feiya Cao , Qixin Wang , Pu Li , Zhirong Xing , Ziyu Song , Heng Zhang , Zhibin Zhou , Wenfang Feng . Magnesium-Ion Conducting Electrolyte Based on Grignard Reaction: Synthesis and Properties. University Chemistry, doi: 10.3866/PKU.DXHX202308094
5. [5]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240201
6. [6]
  Xiufang Wang , Donglin Zhao , Kehua Zhang , Xiaojie Song . “Preparation of Carbon Nanotube/SnS₂ Photoanode Materials”: A Comprehensive University Chemistry Experiment. University Chemistry, doi: 10.3866/PKU.DXHX202308025
7. [7]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240028
8. [8]
  Yongjie ZHANG , Bintong HUANG , Yueming ZHAI . Research progress of formation mechanism and characterization techniques of protein corona on the surface of nanoparticles. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240247
9. [9]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20230402
10. [10]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20230454
11. [11]
  Hailian Tang , Siyuan Chen , Qiaoyun Liu , Guoyi Bai , Botao Qiao , Fei Liu . Stabilized Rh/hydroxyapatite Catalyst for Furfuryl Alcohol Hydrogenation: Application of Oxidative Strong Metal-Support Interactions in Reducing Conditions. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202408004
12. [12]
  Jinyi Sun , Lin Ma , Yanjie Xi , Jing Wang . Preparation and Electrocatalytic Nitrogen Reduction Performance Study of Vanadium Nitride@Nitrogen-Doped Carbon Composite Nanomaterials: A Recommended Comprehensive Chemistry Experiment. University Chemistry, doi: 10.3866/PKU.DXHX202310094
13. [13]
  Jiaxin Su , Jiaqi Zhang , Shuming Chai , Yankun Wang , Sibo Wang , Yuanxing Fang . Optimizing Poly(heptazine imide) Photoanodes Using Binary Molten Salt Synthesis for Water Oxidation Reaction. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202408012
14. [14]
  Yuejiao An , Wenxuan Liu , Yanfeng Zhang , Jianjun Zhang , Zhansheng Lu . Revealing Photoinduced Charge Transfer Mechanism of SnO₂/BiOBr S-Scheme Heterostructure for CO₂ Photoreduction. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202407021
15. [15]
  Yunting Shang , Yue Dai , Jianxin Zhang , Nan Zhu , Yan Su . Something about RGO (Reduced Graphene Oxide). University Chemistry, doi: 10.3866/PKU.DXHX202306050
16. [16]
  Junli Liu . Practice and Exploration of Research-Oriented Classroom Teaching in the Integration of Science and Education: a Case Study on the Synthesis of Sub-Nanometer Metal Oxide Materials and Their Application in Battery Energy Storage. University Chemistry, doi: 10.12461/PKU.DXHX202404023
17. [17]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20230350
18. [18]
  Yongmei Liu , Lisen Sun , Zhen Huang , Tao Tu . Curriculum-Based Ideological and Political Design for the Experiment of Methanol Oxidation to Formaldehyde Catalyzed by Electrolytic Silver. University Chemistry, doi: 10.3866/PKU.DXHX202308020
19. [19]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20230447
20. [20]
  Yi Li , Zhaoxiang Cao , Peng Liu , Xia Wu , Dongju Zhang . Revealing the Coloration and Color Change Mechanisms of the Eriochrome Black T Indicator through Computational Chemistry and UV-Visible Absorption Spectroscopy. University Chemistry, doi: 10.12461/PKU.DXHX202405154

Get Citation

PDF

XML

Metrics

PDF Downloads(957)
Abstract views(1960)
HTML views(35)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142