Citation: CHEN Wei, GAO Han-Yang, YANG Yu, LIN Pei-Bin, YUAN Jian, SHANGGUAN Wen-Feng, SU Jia-Chun, SUN Yang-Zhou. Polymerizable Complex Synthesis of Protonated Form of Layered Perovskite K_0.5La_0.5Bi₂Ta₂O₉ for Water Splitting into Hydrogen[J]. Acta Physico-Chimica Sinica doi: 10.3866/PKU.WHXB201208011 shu

Polymerizable Complex Synthesis of Protonated Form of Layered Perovskite K_0.5La_0.5Bi₂Ta₂O₉ for Water Splitting into Hydrogen

1.
1 Research Center for Combustion and Environmental Technology, Shanghai Jiao Tong University, Shanghai 200240, P. R. China;
2 CNOOC New Energy Investment Co. Ltd. Beijing 100016, P. R. China

Received Date: 6 July 2012
Available Online: 1 August 2012
Fund Project: 国家重点基础研究发展计划(973计划)(2009CN220000) (973计划)(2009CN220000)国家自然科学基金(20973110)资助项目 (20973110)

The protonated layered perovskite oxide H_1.9K_0.3La_0.5Bi_0.1Ta₂O₇ (HKLBT) was prepared from K_0.5La_0.5Bi₂Ta₂O₉ (KLBT) by H ion-exchange, and subsequently characterized by thermogravimetric analysis (TG-DSC), X-ray diffraction (XRD), UV-Vis diffuse reflectance spectroscopy (DRS), and X-ray photoelectron spectroscopy (XPS). The effects of the calcining temperature on the material's photocatalytic activity were also investigated. Results showed that HKLBT with high crystalline quality could be synthesized at low temperatures and that HKLBT prepared from KLBT calcined at 900℃ exhibited the greatest photocatalytic activity, with an average water splitting hydrogen evolution rate of 236.6 μmol·h^-1 in pure water. The time course of water splitting indicated HKLBT has ability to split water into hydrogen and oxygen with long-term stability.
- Photocatalysis,
- Water splitting,
- Layered perovskite,
- Acid treatment
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Polymerizable Complex Synthesis of Protonated Form of Layered Perovskite K0.5La0.5Bi2Ta2O9 for Water Splitting into Hydrogen

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通讯作者: 陈斌, bchen63@163.com

Polymerizable Complex Synthesis of Protonated Form of Layered Perovskite K_0.5La_0.5Bi₂Ta₂O₉ for Water Splitting into Hydrogen