Citation: LI Wei-Bing, BU Yu-Yu, YU Jian-Qiang. Preparation of ZnO/In₂O₃ Composite Hollow Spheres and Their Photoelectrocatalytic Properties to Glucose Degradation[J]. Acta Physico-Chimica Sinica doi: 10.3866/PKU.WHXB201207101 shu

Preparation of ZnO/In₂O₃ Composite Hollow Spheres and Their Photoelectrocatalytic Properties to Glucose Degradation

1.
1. Faculty of Environment and Safety, Qingdao University of Science and Technology, Qingdao 266042, China;
2. Key Laboratory of New Fiber Materials and Modern Textile, Qingdao University, Qingdao 266071, Shandong Province, P. R. China

Received Date: 26 March 2012
Available Online: 10 July 2012
Fund Project: 国家自然科学基金(20973097) (20973097)国家重点基础研究发展规划项目(973) (2009CB220000)资助 (973) (2009CB220000)

A series of materials consisting of ZnO/In₂O₃ composite hollow spheres were successfully prepared by a two-step process involving D-glucose-assisted hydrothermal and annealing treatments. X-ray diffraction (XRD) patterns suggested that ZnO semiconductors formed in these materials were amorphous, the annealing temperatures were lower than 500 ℃, however, they converted to a wurtzite structure with higher annealing temperatures. Examination by scanning electron microscopy (SEM) and transmission electron microscopy (TEM) confirmed the hollow sphere morphology of these materials. In addition, the ZnO and In₂O₃ nanoparticles within the spheres were found to interact closely. The photoelectrocatalytic properties of these materials with regard to glucose decomposition were investigated by depositing samples onto indium tin oxide (ITO) glass to fabricate thin-film photoelectrodes. The highest photo-induced degradation current density was observed with the film annealed at 700 ℃. Photoluminescence (PL) spectra clearly showed quenching of the luminescence intensity of these ZnO/ In₂O₃ composite hollow spheres. The p-n junction at the interface between the ZnO and In₂O₃ nanoparticles evidently reduced the recombination of photogenerated electron and holes, enhancing electron transfer to the surface of the photoelectrode.
- ZnO/In₂O₃,
- Composite hollow sphere,
- Photoelectrochemical,
- Catalysis degradation
1. [1]
  
  (1) Shen,W. H.; Zhu, Y. F.; Dong, X. P.; Gu, J. L.; Shi, J. L. Chem. Lett. 2005, 34 (6), 840. doi: 10.1246/cl.2005.840
2. [2]
  (2) Wang, X.; Hu, P.; Yuan, F. L.; Yu, L. J. J. Phys. Chem. C 2007,111 (17), 6706.
3. [3]
  (3) Li, X. L.; Lou, T. J.; Sun, X. M.; Li, Y. D. Inorg. Chem. 2004,43 (17), 5442. doi: 10.1021/ic049522w
4. [4]
  (4) Wu, L. Z.; Zhi, J. F. Acta Phys. -Chim. Sin. 2007, 23, 1173.[吴良专, 只金芳. 物理化学学报, 2007, 23, 1173.] doi: 10.3866/PKU.WHXB20070807
5. [5]
  (5) Salgueirino-Maceira, V.; Spasova, M.; Farle, M. Adv. Funct. Mater. 2005, 15 (6), 1036. doi: 10.1002/adfm.200400469
6. [6]
  (6) Shiho, H.; Kawahashi, N. Colloid & Polymer Science 2000, 278 (3), 270. doi: 10.1007/s003960050043
7. [7]
  (7) Caruso, F.; Spasova, M.; Saigueirino-Maceira, V.; Liz-Marzan,L. M. Adv. Mater. 2001, 13 (14), 1090. doi: 10.1002/1521-4095(200107)13:14<1090::AID-ADMA1090>3.0.CO;2-H
8. [8]
  (8) Kawahashi, N.; Persson, C.; Matijevic, E. J. Mater. Chem. 1991,1 (4), 577. doi: 10.1039/jm9910100577
9. [9]
  (9) Xia, Y. D.; Mokaya, R. J. Mater. Chem. 2005, 15 (30), 3126.doi: 10.1039/b502558c
10. [10]
  (10) Sun, X. M.; Li, Y. D. Angew. Chem. Int. Edit. 2004, 43 (5), 597.doi: 10.1002/anie.200352386
11. [11]
  (11) Yu, S. H.; Cui, X. J.; Li, L. L.; Li, K.; Yu, B.; Antonietti, M.;Colfen, H. Adv. Mater. 2004, 16 (18), 1636. doi: 10.1002/adma.200400522
12. [12]
  (12) Titirici, M. M.; Antonieti, M.; Thomas, A. Chem. Mater. 2006,18, 3808. doi: 10.1021/cm052768u
13. [13]
  (13) Sakthivel, S.; Neppolian, B.; Shankar, M. V.; Arabindoo, B.;Palanichamy, M.; Murugesan, V. Sol. Energy Mater. Sol. Cells2003, 77, 65. doi: 10.1016/S0927-0248(02)00255-6
14. [14]
  (14) Khodja, A. A.; Sehili, T.; Pilichowski, J. F.; Boule, P.J. Photochem. Photobiol. A 2001, 141, 231. doi: 10.1016/S1010-6030(01)00423-3
15. [15]
  (15) Wang, X. Y.; Dong, G. F.; Qiao, J.; Duan, L.;Wang, L. D.; Qiu,Y. Acta Phys. -Chim. Sin. 2010, 26, 2049. [王小燕, 董桂芳,乔娟, 段炼, 王立铎, 邱勇. 物理化学学报, 2010, 26,2049.] doi: 10.3866/PKU.WHXB20100631
16. [16]
  (16) Xiao, L. X.; Duan, L. Q.; Chai, J. Y.;Wang, Y., Chen, Z. J.; Qu,B.; ng, Q. H. Acta Phys. -Chim. Sin. 2011, 27, 749. [肖立新, 段来强, 柴俊一, 王芸, 陈志坚, 曲波, 龚旗煌. 物理化学学报, 2011, 27, 749.] doi: 10.3866/PKU.WHXB20110310
17. [17]
  (17) Wang, Z. Y.; Huang, B. B.; Dai, Y.; Qin, X. Y.;Wang, P.; Liu, H.X.; Yu, J. X. J. Phys. Chem. C 2009, 113, 4612. doi: 10.1021/jp8107683
18. [18]
  (18) Zhang, S. Q.;Wen,W.; Zhang, H. Z.; Zhao, H. J. J. Photochem. Photobiol. A 2009, 208, 97. doi: 10.1016/j.jphotochem.2009.09.001
19. [19]
  (19) Wang, J.; Han, Y. H.; Feng, M. Z.; Chen, J. Z.; Li, X. J.; Zhang,S. Q. J. Mater. Sci. 2011, 46, 416. doi: 10.1007/s10853-010-4863-z
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1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation of ZnO/In2O3 Composite Hollow Spheres and Their Photoelectrocatalytic Properties to Glucose Degradation

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通讯作者: 陈斌, bchen63@163.com

Preparation of ZnO/In₂O₃ Composite Hollow Spheres and Their Photoelectrocatalytic Properties to Glucose Degradation