Citation: LI Qiang, ZHAO Hui, JIANG Rui, GUO Li-Fan. Synthesis and Electrochemical Properties of La_1.6Sr_0.4Ni_1-xCu_xO₄ as Cathode Materials for Intermediate Temperature Solid Oxide Fuel Cells[J]. Acta Physico-Chimica Sinica doi: 10.3866/PKU.WHXB201206272 shu

Synthesis and Electrochemical Properties of La_1.6Sr_0.4Ni_1-xCu_xO₄ as Cathode Materials for Intermediate Temperature Solid Oxide Fuel Cells

1.
Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education, School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080, P. R. China

Received Date: 21 May 2012
Available Online: 27 June 2012
Fund Project: 黑龙江省教育厅(12521396)资助项目 (12521396)

Cathodic materials La_1.6Sr_0.4Ni_1-xCu_xO₄ (x=0.2, 0.4, 0.6, 0.8), for an intermediate temperature solid oxide fuel cell (IT-SOFC), were prepared by a glycine-nitrate process and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM). Results showed that no reaction occurred between the La_1.6Sr_0.4Ni_1-xCu_xO₄ electrode and the Ce_0.9Gd_0.1O_1.95 (C ) electrolyte at 1000 °C, and that the electrode formed od contact with the electrolyte after sintering at 1000 °C for 4 h. Electrochemical AC impedance spectroscopy measurements were used to study cathodic performance. The La_1.6Sr_0.4Ni_0.4Cu_0.6O₄ cathode gave the lowest polarization resistance (R_p) of 0.35 Ω·cm² at 750 ° C in air. Electrode properties of La_1.6Sr_0.4Ni_1-xCu_xO₄ were studied under various temperatures and oxygen partial pressures. The two main oxygen reduction processes at the cathode are the oxygen ion transfer from the triple phase boundary to C electrolyte, and the charge transfer process. Charge transfer is the major rate limiting step for La_1.6Sr_0.4Ni_1-xCu_xO₄ cathode. The La_1.6Sr_0.4Ni_0.4Cu_0.6O₄ cathode exhibited the lowest overpotential, about 45 mV for a current density of 45 mA·cm^-2 at 700 °C in air. This preliminary work showed that the present La_1.6Sr_0.4Ni_1-xCu_xO₄ materials may be potential cathodes for use in IT-SOFCs.
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1.
沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis and Electrochemical Properties of La1.6Sr0.4Ni1-xCuxO4 as Cathode Materials for Intermediate Temperature Solid Oxide Fuel Cells

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通讯作者: 陈斌, bchen63@163.com

Synthesis and Electrochemical Properties of La_1.6Sr_0.4Ni_1-xCu_xO₄ as Cathode Materials for Intermediate Temperature Solid Oxide Fuel Cells