Citation: FAN Hai-Bin, ZHANG Dong-Feng, GUO Lin. Fabrication, Formation Mechanism and the Photocatalytic Properties of Hierarchical Porous Hematite Networks[J]. Acta Physico-Chimica Sinica doi: 10.3866/PKU.WHXB201206122 shu

Fabrication, Formation Mechanism and the Photocatalytic Properties of Hierarchical Porous Hematite Networks

1.
School of Chemistry and Environment, Beihang University, Beijing 100191, P. R. China

Received Date: 2 May 2012
Available Online: 12 June 2012
Fund Project: 国家重点基础研究发展规划项目(973) (2010CB934700) (973) (2010CB934700) 国家自然科学基金(21173015) (21173015)中央高校基本科研基金(YWF-11-03-Q-085)资助 (YWF-11-03-Q-085)

Hierarchical porous hematite (HPH) network structures were successfully constructed using an improved polymerization induced colloid aggregation process with Fe(NO₃)₃·9H₂O as the raw material. The polymerization between urea and formaldehyde into urea-formaldehyde (UF) resin is the key factor for this construction. The UF resins appear to be advantageous in two respects: the UF oli mer hybrids with ferric hydroxide (Fe-UF) and UF polymer formed microcapsules (UFM) acted as templates to induce the aggregation of Fe-UF hybrids into mesoporous spheres. The further crosslink reactions among the hybrid spheres generate the network structure. After calcination, the decomposition of the UF resin and the UFM produces nanopores in the nanorod subunits and macropores in the network structure, respectively. The photodegradation activity of the unique structured HPH is four times that of the commercial hematite nanoparticles with rhodamine B (RhB) as pollutant.
- α-Fe₂O₃,
- Hierarchical porous structure,
- Polymerization induced colloid aggregation method,
- Photodegradation
1. [1]
  
  (1) Im, S. H.; Jeong, U. Y.; Xia, Y. N. Nat. Mater. 2005, 4 (9), 671.doi: 10.1038/nmat1448
2. [2]
  (2) Yuan, Z. Y.; Su, B. L. J. Mater. Chem. 2006, 16 (7), 663. doi: 10.1039/b512304f
3. [3]
  (3) Toberer, E. S.; Seshadri, R. Adv. Mater. 2005, 17 (18), 2244. doi: 10.1002/adma.200500668
4. [4]
  (4) Ishizuka, N.; Minakuchi, H.; Nakanishi, K.; Hirao, K.; Tanaka,N. Colloid Surf. A-Physicochem. Eng. Asp. 2001, 187, 273. doi: 10.1016/S0927-7757(01)00642-2
5. [5]
  (5) Du, J.; Lai, X. Y.; Yang, N. L.; Zhai, J.; Kisailus, D.; Su, F. B.;Wang, D.; Jiang, L. ACS Nano 2011, 5 (1), 590. doi: 10.1021/nn102767d
6. [6]
  (6) Toberer, E. S.; Schladt, T. D.; Seshadri, R. J. Am. Chem. Soc.2006, 128 (5), 1462. doi: 10.1021/ja0579412
7. [7]
  (7) Gao, G. D.; Li, J.; Zhang, A. Y.; An, X. H.; Zhou, L. Acta Phys. -Chim. Sin. 2010, 26, 2437. [高冠道, 李婧, 张爱勇,安晓红, 周蕾. 物理化学学报, 2010, 26, 2437.]
8. [8]
  (8) Li, H. N.; Zhang, L.; Dai, H. X.; He, H. Inorg. Chem. 2009, 48 (10), 4421. doi: 10.1021/ic900132k
9. [9]
  (9) Amutha, R.; Muruganandham, M.; Sathish, M.; Akilandeswari,S.; Suri, R. P. S.; Repo, E.; Sillanpää, M. J. Phys. Chem. C2011, 115 (14), 6367. doi: 10.1021/jp200301g
10. [10]
  (10) Jiang, Z. T.; Zuo, Y. M. Anal. Chem. 2001, 73 (3), 686. doi: 10.1021/ac001008u
11. [11]
  (11) Peng, X.; Zhang, Q. X.; Cheng, X.; Cao, D. P. Acta Phys. -Chim. Sin. 2011, 27, 2065. [彭璇, 张勤学, 成璇, 曹达鹏. 物理化学学报, 2011, 27, 2065.] doi: 10.3866/PKU.WHXB20110919
12. [12]
  (12) Cho, C. Y.; Moon, J. H. Adv. Mater. 2011, 23 (26), 2971.doi: 10.1002/adma.201101042
13. [13]
  (13) Barakat, T.; Rooke, J. C.; Tidahy, H. L.; Hosseini, M.; Cousin,R.; Lamonier, J. F.; Giraudon, J. M.; DeWeireld, G.; Su, B. L.;Siffert, S. ChemSusChem 2011, 4 (10), 1420. doi: 10.1002/cssc.201100282
14. [14]
  (14) Lee, J.; Kim, J.; Jia, H. F.; Kim, M. I.; Kwak, J. H.; Jin, S. M.;Dohnalkova, A.; Park, H. G.; Chang, H. N.;Wang, P.; Grate, J.W.; Hyeon, T. Small 2005, 1 (7), 744. doi: 10.1002/smll.200500035
15. [15]
  (15) Ma, G. X.; Zhong, Q. D.; Lu, X. G.; Lu, T. H. Acta Phys. -Chim. Sin. 2009, 25, 2061. [马国仙, 钟庆东, 鲁雄刚, 陆天虹. 物理化学学报, 2009, 25, 2061.] doi: 10.3866/PKU.WHXB20091037
16. [16]
  (16) Croce, F.; Epifanio, A. D.; Hassoun, J.; Deptula, A.; Olczac, T.;Scrosati, B. Electrochem. Solid State Lett. 2002, 5 (3), A47.
17. [17]
  (17) Wang, J. H.; Li, B.;Wu, H. Y.; Guo, Y. Z. Acta Phys. -Chim. Sin.2008, 24, 681. [王剑华, 李斌, 吴海燕, 郭玉忠. 物理化学学报, 2008, 24, 681.] doi: 10.3866/PKU.WHXB20080423
18. [18]
  (18) Cheng, F.; Tao, Z.; Liang, J.; Chen, J. Chem. Mater. 2008, 20 (3), 667. doi: 10.1021/cm702091q
19. [19]
  (19) Li, J. S.; Gu, J.; Ling, X. F.; Sun, X. Y.; Shen, J. Y.; Han,W. Q.;Wang, L. J. Acta Phys. -Chim. Sin. 2011, 27, 1772. [李健生,顾娟, 凌晓凤, 孙秀云, 沈锦优, 韩卫清, 王连军. 物理化学学报, 2011, 27, 1772.] doi: 10.3866/PKU.WHXB20110613
20. [20]
  (20) Tsung, C. K.; Fan, J.; Zheng, N. F.; Shi, Q. H.; Forman, A. J.;Wang, J. F.; Stucky, G. D. Angew. Chem. Int. Edit. 2008, 47 (45), 8682. doi: 10.1002/anie.200802487
21. [21]
  (21) Li, L. L.; Xu, J.; Yuan, Q.; Li, Z. X.; Song,W. G.; Yan, C. H.Small 2009, 5 (23), 2730. doi: 10.1002/smll.200900901
22. [22]
  (22) Yuan, Q.; Duan, H. H.; Li, L. L.; Li, Z. X.; Duan,W. T.; Zhang,L. S.; Song,W. G.; Yan, C. H. Adv. Mater. 2010, 22 (13), 1475.doi: 10.1002/adma.200904223
23. [23]
  (23) Meng, Y.; Gu, D.; Zhang, F. Q.; Shi, Y. F.; Yang, H. F.; Li, Z.;Yu, C. Z.; Tu, B.; Zhao, D. Y. Angew. Chem. Int. Edit. 2005, 44 (43), 7053. doi: 10.1002/anie.200501561
24. [24]
  (24) Lee, J.; Orilall, M. C.;Warren, S. C.; Kamperman, M.; Disalvo,F. J.;Wiesner, U. Nat. Mater. 2008, 7 (3), 222. doi: 10.1038/nmat2111
25. [25]
  (25) Niu, D. C.; Ma, Z.; Li, Y. S.; Shi, J. L. J. Am. Chem. Soc. 2010,132 (43), 15144. doi: 10.1021/ja1070653
26. [26]
  (26) Gao, C. B.; Qiu, H. B.; Zeng,W.; Sakamoto, Y.; Terasaki, O.;Sakamoto, K.; Chen, Q.; Che, S. A. Chem. Mater. 2006, 18 (16),3904. doi: 10.1021/cm061107+
27. [27]
  (27) Li, G. X.;Wang, T.; He, J. P.; Zhou, J. H.; Xue, H. R.; Ma, Y.O.; Hu, Y. Y. Acta Phys. -Chim. Sin. 2011, 27, 248. [李国显,王涛, 何建平, 周建华, 薛海荣, 马一鸥, 胡园园. 物理化学学报, 2011, 27, 248.] doi: 10.3866/PKU.WHXB20110131
28. [28]
  (28) Dong, A. G.; Ren, N.; Tang, Y.;Wang, Y. J.; Zhang, Y. H.; Hua,W. M.; Gao, Z. J. Am. Chem. Soc. 2003, 125 (17), 4976. doi: 10.1021/ja029964b
29. [29]
  (29) Brezesinski, K.; Haetge, J.;Wang, J.; Mascotto, S.; Reitz, C.;Rein, A.; Tolbert, S. H.; Perlich, J.; Dunn, B.; Brezesinski, T.Small 2011, 7 (3), 407. doi: 10.1002/smll.201001333
30. [30]
  (30) Sadakane, M.; Sasaki, K.; Kunioku, H.; Ohtani, B.; Abe, R.;Ueda,W. J. Mater. Chem. 2010, 20 (9), 1811. doi: 10.1039/b922416e
31. [31]
  (31) Hu, J.; Abdelsalam, M.; Bartlett, P.; Cole, R.; Sugawara, Y.;Baumberg, J.; Mahajan, S.; Denuault, G. J. Mater. Chem. 2009,19 (23), 3855. doi: 10.1039/b900279k
32. [32]
  (32) Chen, X. Q.; Li, Z. S.; Ye, J. H.; Zou, Z. G. Chem. Mater. 2010,22 (12), 3583. doi: 10.1021/cm100751w
33. [33]
  (33) Wu, Q. Z.; Shen, Y.; Li, Y. G. Acta Phys. -Chim. Sin. 2003, 19,737. [邬泉周, 沈勇, 李玉光. 物理化学学报, 2003, 19,737.] doi: 10.3866/PKU.WHXB20030813
34. [34]
  (34) Davis, S. A.; Burkett, S. L.; Mendelson, N. H.; Mann, S. Nature1997, 385, 420. doi: 10.1038/385420a0
35. [35]
  (35) Liu, Z. T.; Fan, T. X.; Zhang,W.; Zhang, D. Microporous Mesoporous Mat. 2005, 85 (1-2), 82. doi: 10.1016/j.micromeso.2005.06.021
36. [36]
  (36) Biette, L.; Carn, F.; Maugey, M.; Achard, M. F.; Maquet, T.;Steunou, N.; Livage, T.; Serier, H.; Backov, R. Adv. Mater.2005, 17 (24), 2970. doi: 10.1002/adma.200501368
37. [37]
  (37) Sen, T.; Tiddy, G. J. T.; Casci, J. L.; Anderson, M.W. Angew. Chem. Int. Edit. 2003, 42 (38), 4649. doi: 10.1002/anie.200351479
38. [38]
  (38) Shi, Y. F.; Zhang, F.; Hu, Y. S.; Sun, X. H.; Zhang, Y. C.; Lee, H.I.; Chen, L. Q.; Stucky, G. D. J. Am. Chem. Soc. 2010, 132 (16),5552. doi: 10.1021/ja1001136
39. [39]
  (39) Ke, X. F.; Cao, J. M.; Zheng, M. B.; Chen, Y. P.; Liu, J. S. Acta Phys. -Chim. Sin. 2007, 23, 757. [柯行飞, 曹洁明, 郑明波, 陈勇平, 刘劲松. 物理化学学报, 2007, 23, 757.] doi: 10.3866/PKU.WHXB20070526
40. [40]
  (40) Dacquin, J. P.; Dhainaut, J.; Duprez, D.; Royer, S.; Lee, A. F.;Wilson, K. J. Am. Chem. Soc. 2009, 131 (36), 12896. doi: 10.1021/ja9056486
41. [41]
  (41) Yan, H.W.; Blanford, C. F.; Holland, B. T.; Smyrl,W. H.; Stein,A. Chem. Mater. 2000, 12 (4), 1134. doi: 10.1021/cm9907763
42. [42]
  (42) Sadakane, M.; Asanuma, T.; Kubo, J.; Ueda,W. Chem. Mater.2005, 17 (13), 3546. doi: 10.1021/cm050551u
43. [43]
  (43) Zhang, R.; Dai, H.; Du, Y.; Zhang, L.; Deng, J.; Xia, Y.; Zhao,Z.; Meng, X.; Liu, Y. Inorg. Chem. 2011, 50 (6), 2534. doi: 10.1021/ic1023604
44. [44]
  (44) Zhu, G.; Xu, H.; Xiao, Y.; Liu, Y.; Yuan, A.; Shen, X. ACS Appl. Mater. Interfaces 2012, 4 (2), 744. doi: 10.1021/am2013882
45. [45]
  (45) Shi, Y.; Li, X.; Hu, J. K.; Lu, J. H.; Ma, Y. C.; Zhang, Y. H.;Tang, Y. J. Mater. Chem. 2011, 21 (40), 16223. doi: 10.1039/c1jm11669j
46. [46]
  (46) Mao, D.; Yao, J. X.; Lai, X. Y.; Yang, M.; Du, J. A.;Wang, D.Small 2011, 7 (5), 578. doi: 10.1002/smll.201001728
47. [47]
  (47) Pattanayak, A.; Subramanian, A. Int. J. Appl. Ceram. Technol.2011, 8 (1), 94. doi: 10.1111/j.1744-7402.2009.02410.x
48. [48]
  (48) Pattanayak, A.; Subramanian, A. Powder Technol. 2009, 192 (3), 359. doi: 10.1016/j.powtec.2009.01.023
49. [49]
  (49) Blin, J. L.; Leonard, A.; Yuan, Z. Y.; Gi t, L.; Vantomme, A.;Cheetham, A. K.; Su, B. L. Angew. Chem. Int. Edit. 2003, 42 (25), 2872. doi: 10.1002/anie.200250816
50. [50]
  (50) Kang, Y. J.; Shan,W.;Wu, J. Y.; Zhang, Y. H.;Wang, X. Y.;Yang,W. L.; Tang, Y. Chem. Mater. 2006, 18 (7), 1861. doi: 10.1021/cm060084w
51. [51]
  (51) Han, L.; Shan, Z.; Chen, D. H.; Yu, X. J.; Yang, P. Y.; Tu, B.;Zhao, D. Y. J. Colloid Interface Sci. 2008, 318 (2), 315. doi: 10.1016/j.jcis.2007.10.026
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