Citation: ZHENG Bin, ZHANG An-Feng, LIU Min, DING Fan-Shu, DAI Cheng-Yi, SONG Chun-Shan, GUO Xin-Wen. Properties of the Nano-Particle Fe-based Catalyst for the Hydrogenation of Carbon Dioxide to Hydrocarbons[J]. Acta Physico-Chimica Sinica, ;2012, 28(08): 1943-1950. doi: 10.3866/PKU.WHXB201206051 shu

Properties of the Nano-Particle Fe-based Catalyst for the Hydrogenation of Carbon Dioxide to Hydrocarbons

1.
1. State Key Laboratory of Fine Chemicals, Department of Catalysis Chemistry and Engineering, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, P. R. China;
2. EMS Energy Institute and Department of Energy and Mineral Engineering, Pennsylvania State University, University Park, Pennsylvania, 16802, USA

Received Date: 10 March 2012
Available Online: 5 June 2012

Combining co-precipitation-gelation, mechanical mixing and impregnation methods, a series of catalysts of FeK-M/γ-Al₂O₃(M=Cd or Cu) have been attained. The catalysts were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), N₂ physisorption, X-ray diffraction (XRD) and temperature-programmed reduction of hydrogen (H₂-TPR). The hydrogenation of carbon dioxide over these catalysts was also investigated in a fixed bed. Given a reaction time of 100 h, CO₂ conversion over a 15%Fe/10%K/γ-Al₂O₃ catalyst reached 51.3 %, with a selectivity towards C₂₊ of 62.6 % at 3 MPa, 673 K, a space velocity of 3600 h-1 and at a molar ratio of H₂/CO₂ of 3. At the lower Fe content of 2.5%, the selectivity towards C₂₊ was still greater than 60.0%. Increasing the potassium content from 0% to 10%, increased the selectivity towards C₂-C₄⁼ and the molar ratio of C₂-C₄⁼ /C₂-C₄⁰ increased to 3.6. The addition of Cd and Cu improved the reduction and catalytic activities. Specifically, Cu improved the molar ratio of C₂-C₄⁼ /C₂-C₄⁰ from 3.6 to 5.4, and the Cd increased the selectivity of C₅₊ by 12%.
- Carbon dioxide,
- Hydrogenation,
- Fe-based catalyst,
- Precipitation,
- Light hydrocarbons
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