Citation: ZHANG Rong-Bin, LIANG Lei, ZENG Xian-Rong, SHANG Jin-Yan, WANG Tao, CAI Jian-Xin. Catalytic Properties of Ni /MWCNT and La-Promoted Ni /MWCNT for Methanation of Carbon Dioxide Reaction[J]. Acta Physico-Chimica Sinica, ;2012, 28(08): 1951-1956. doi: 10.3866/PKU.WHXB201206041 shu

Catalytic Properties of Ni /MWCNT and La-Promoted Ni /MWCNT for Methanation of Carbon Dioxide Reaction

1.
Department of Chemistry, Nanchang University, Nanchang 310031, P. R. China

Received Date: 20 February 2012
Available Online: 4 June 2012
Fund Project: 国家自然科学基金(21166018) (21166018)江西省教育厅科技项目(GJJ10291)资助 (GJJ10291)

Nickel multiwalled carbon nanotubes (Ni/MWCNT) and lanthanum-promoted Ni/MWCNT were successfully synthesized by impregnation. Methanation of carbon dioxide was used as a probe to evaluate their catalytic performance. N₂-BET, temperature programmed reduction (TPR), X-ray powder diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) were used to study the advantageous effects of La on the structure, surface composition, reduction properties and reaction performance of Ni/MWCNT. It was found that La-promoted Ni/MWCNT catalysts showed better catalytic activity for the reaction than the un-promoted. The addition of La to Ni/MWCNT improves the concentration and dispersion of the active NiO component on the catalyst surface, thus weakening the interaction between support and NiO species, which in turn improves the electron density at the NiO species. As a consequence, the adsorption of reactants was enhanced and the activity improved. Moreover, the sequence in which La was added was also studied in this work. Ni-La/MWCNT, in which La was impregnated onto the MWCNT first, shows better catalytic performance than La-Ni/MWCNT, where the Ni was impregnated first.
- Nickel catalysts,
- MWCNT,
- Lanthanum,
- Carbon dioxide methanation
1. [1]
  
  (1) Bai, M. G.; Tao, X. M.;Wu, Q. Y.; Huang, Z. J.; Li, Y. L.; Yin,Y. X.; Dai, X. Y. Acta Phys. -Chim. Sin. 2009, 25, 2455. [白玫瑰, 陶旭梅, 吴青友, 黄志军, 李育亮, 印永祥, 戴晓雁. 物理化学学报, 2009, 25, 2455.] doi: 10.3866/PKU.WHXB20091207
2. [2]
  (2) Chen, J. X.; Qiu, Y. J.; Zhang, J. Y.; Su,W. H. Acta Phys. -Chim. Sin. 2004, 20, 76. [陈吉祥, 邱业君, 张继炎, 苏万华. 物理化学学报, 2004, 20, 76.] doi: 10.3866/PKU.WHXB20040116
3. [3]
  (3) Wu, Y.; Chan, C.W. Expert Syst. Appl. 2009, 36, 9949. doi: 10.1016/j.eswa.2009.01.064
4. [4]
  (4) Alphen, K.; van Rujiven, J.; Kasa, S.; Hekkert, M.; Turkenburg,W. Energy Policy 2009, 37, 43. doi: 10.1016/j.enpol.2008.07.029
5. [5]
  (5) Walspurger, S.; Boels, L.; Cobden, P. D.; Eizinga, G. D.; Haije,W. G.; van den Brink, R.W. ChemSusChem. 2008, No. 1, 643.
6. [6]
  (6) Song, C. S. Catal. Today 2006, 115(1-4), 2. doi: 10.1016/j.cattod.2006.02.029
7. [7]
  (7) Omae, I. Catal. Today 2006, 115 (1-4), 33.
8. [8]
  (8) Guo, X. M.; Mao, D. S.; Lu, G. Z.;Wang, S. Acta Phys. -Chim. Sin. 2012, 28, 170. [郭晓明, 毛东森, 卢冠忠, 王嵩. 物理化学学报, 2012, 28, 170.] doi: 10.3866/PKU.WHXB201228170
9. [9]
  (9) Peebles, D. E.; odman, J. M.; White, J. M. J. Phys. Chem.1983, 87 (22), 4378.
10. [10]
  (10) Yamasaki, M. H.; Habazaki, H.; Asami, K.; Izumiya, K.;Hashimoto, K. Catal. Commun. 2006, 7 (1), 24. doi: 10.1016/j.catcom.2005.08.005
11. [11]
  (11) Melián-Cabrera, I.; Granados, M. L.; Fierro, J. L. G. J. Catal.2002, 210 (2), 273.
12. [12]
  (12) Inui, T.; Takeguchi, T. Catal. Today 1991, 10 (1), 95. doi: 10.1016/0920-5861(91)80077-M
13. [13]
  (13) Chang, F.W.; Kuo, M. S.; Tsay, M. T.; Hsieh, M. C. Appl. Catal. A 2003, 247 (2), 309.
14. [14]
  (14) Du, G.; Lim, S.; Yang, Y.;Wang, C.; Pfefferle, L.; Haller, G. L.J. Catal. 2007, 249 (2), 370. doi: 10.1016/j.jcat.2007.03.029
15. [15]
  (15) Liu, X. H.; Miao, Y.; Li, X. L.; Sheng, S. S. Acta Phys. -Chim. Sin. 1995, 11, 746. [刘新华, 苗茵, 李晓丽, 盛世善. 物理化学学报, 1995, 11, 746.] doi: 10.3866/PKU.WHXB19950816
16. [16]
  (16) Vance, C. K.; Bartholomew, C. H. Appl. Catal. 1983, 7, 169.doi: 10.1016/0166-9834(83)80005-0
17. [17]
  (17) Tang, Y. C.; Yang, D.; Qin, F.; Hu, J. H. J. Solid State Chem.2009, 182 (8), 2279. doi: 10.1016/j.jssc.2009.05.036
18. [18]
  (18) Li,W.; Liang, C.; Zhou,W.; Qiu, J.; Zhou, Z.; Sun, G.; Xin, Q.J. Phys. Chem. B 2003, 107 (28), 6292.
19. [19]
  (19) Yang, S. D.; Zhang, X. G.; Huang, J. S.; Sun, J. Y. Acta Phys. -Chim. Sin. 2007, 23, 1224. [杨苏东, 张校刚, 黄建书,孙景玉. 物理化学学报, 2007, 23, 1224.] doi: 10.3866/PKU.WHXB20070816
20. [20]
  (20) Jin, Y. X.; Liu, Z. J.; Chen,W. X.; Xu, Z. D. Acta Phys. -Chim. Sin. 2002, 18, 459. [金亚旭, 刘宗健, 陈卫祥, 徐铸德. 物理化学学报, 2002, 18, 459.] doi: 10.3866/PKU.WHXB20020516
21. [21]
  (21) He, Q. G.; Yuan, X. Z.; Yuan, X. X.; Ma, Z. F. Electrochemistry2004, 10, 51. [和庆钢, 袁晓姿, 原鲜霞, 马紫峰. 电化学,2004, 10, 51.]
22. [22]
  (22) Wang,W. D.; Philippe, S.; Philippe, K.; Joaquim, L. F. J. Mol. Catal. A: Chem. 2005, 235, 194. doi: 10.1016/j.molcata.2005.02.027
23. [23]
  (23) Chaudhary, S.; Kim, J. H.; Singh, K. V.; Ozkan, M. Nano Lett.2004, 4, 2415. doi: 10.1021/nl048498g
24. [24]
  (24) Song, H. L.; Yang, J.; Zhao, J.; Chou, L. J. Chin. J. Catal. 2010,31, 21. [宋焕玲, 杨建, 赵军, 丑凌军. 催化学报, 2010,31, 21.] doi: 10.1016/S1872-2067(09)60036-X
25. [25]
  (25) Cao, L. X.; Chen, Y. X.; Li,W. Z. Nat. Gas Chem. Industry1996, 21, 22. [曹立新, 陈燕馨, 李文钊. 天然气化工, 1996,21, 22.]
26. [26]
  (26) Qiu, Y. J.; Chen, J. X.; Zhang, J. Y. J. Fuel Chem. Tech. 2006,34, 450. [邱业君, 陈吉祥, 张继炎. 燃料化学学报, 2006, 34,450.]
27. [27]
  (27) Gao, J.; Hou, Z. Y.; Guo, J. Z.; Zhu, Y. H.; Zheng, X. M. Catal. Today 2008, 131, 278. doi: 10.1016/j.cattod.2007.10.019
28. [28]
  (28) Zhang, Y. H.; Xiong, G. X.; Sheng, S. S.; Liu, S. L.; Yang,W. S.Acta Phys. -Chim. Sin. 1999, 15, 735. [张玉红, 熊国兴, 盛世善, 刘盛林, 杨维慎. 物理化学学报, 1999, 15, 735.] doi: 10.3866/PKU.WHXB19990813
29. [29]
  (29) Luo, L. T.; Li, S. J.; Feng, G. F.; Li, F. Y. React. Kinet. Catal. Lett. 2002, 75 (2), 289.
30. [30]
  (30) Deng, G. F.; Guo, N. X.; Luo, L. T.; Li, F. Y. J. Chin. Rare Earth2002, 23, 18. [邓庚凤, 郭年祥, 罗来涛, 李凤仪. 稀土, 2002,23, 18.]
31. [31]
  (31) Chen, R. T.; Deng, G. C.; Jiang, Q. Chem. Res. Appl. 1995,No. 1, 1. [陈荣梯, 邓国才, 江琦. 化学研究与应用, 1995,No. 1, 1.]
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