Citation: CAO Hong-Yan, WANG Jian-Li, YAN Sheng-Hui, LIU Zhi-Min, NG Mao-Chu, CHEN Yao-Qiang. Effect of Doping M (M = Mn, Y) into Ce_0.50Zr_0.50O₂ on the Properties of MnO_x/Ce_0.50-zZr_0.50-zM_2zO_y/Al₂O₃ for Catalytic Combustion of Ethyl Acetate[J]. Acta Physico-Chimica Sinica, ;2012, 28(08): 1936-1942. doi: 10.3866/PKU.WHXB201205173 shu

Effect of Doping M (M = Mn, Y) into Ce_0.50Zr_0.50O₂ on the Properties of MnO_x/Ce_0.50-zZr_0.50-zM_2zO_y/Al₂O₃ for Catalytic Combustion of Ethyl Acetate

1.
Key Laboratory of Green Chemistry & Technology of Ministry of Education, College of Chemistry, Sichuan University, Chengdu 610064, P. R. China

Received Date: 27 April 2012
Available Online: 17 May 2012
Fund Project: 国家自然科学基金(2077309、20803049)资助项目 (2077309、20803049)

The effect of doping M (M = Mn,Y) into ceria-zirconia solid solutions on the activity of MnO_x/Ce_0.50-zZr_0.50-zM_2zO_y/Al₂O₃ for catalytic combustion of ethyl acetate has been investigated. It is found that doping of Mn increases greatly the oxygen storage capacity (OSC) of the oxygen-storage materials (OSMs); doping of Y decreases obviously the reduction temperature of catalysts; the doping of Mn and Y combines the advantages of doping of Mn and Y. MnO_x/Ce_0.40Zr_0.40Mn_0.10Y_0.10O_y/ Al₂O₃ has the best catalytic performance. The complete conversion temperature of ethyl acetate over the catalyst is 513K and the temperature range between T_10% and T_100% is the smallest. This catalyst can be applied to abatement of ethyl acetate under conditions of wider range of inert concentration and higher gas hourly space velocity (GHSV). Results of H₂-temperature-programmed reduction(H₂-TPR)and X-ray diffraction (XRD) analyses show that MnO_x/Ce_0.40Zr_0.40Mn_0.10Y_0.10O_y/Al₂O₃ has lower reduction temperature and larger peak area. Mn and Y enter the lattice of ceria-zirconia solid solutions, which improves the textural properties and greatly promotes the MnO_x dispersion on the support surface.
- Volatile organic compounds,
- Catalytic combustion,
- Ethyl acetate,
- MnO_x,
- Ceria-Zirconia Solid solutions,
- Doping
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沈阳化工大学材料科学与工程学院沈阳 110142

Effect of Doping M (M = Mn, Y) into Ce0.50Zr0.50O2 on the Properties of MnOx/Ce0.50-zZr0.50-zM2zOy/Al2O3 for Catalytic Combustion of Ethyl Acetate

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通讯作者: 陈斌, bchen63@163.com

Effect of Doping M (M = Mn, Y) into Ce_0.50Zr_0.50O₂ on the Properties of MnO_x/Ce_0.50-zZr_0.50-zM_2zO_y/Al₂O₃ for Catalytic Combustion of Ethyl Acetate