Citation: RAN Ke, CHEN Qing, ZUO Jian-Min. Fabrication and Structure Characterization of Quasi-2-Dimensional Amorphous Carbon Structures[J]. Acta Physico-Chimica Sinica, ;2012, 28(07): 1551-1555. doi: 10.3866/PKU.WHXB201205093 shu

Fabrication and Structure Characterization of Quasi-2-Dimensional Amorphous Carbon Structures

RAN Ke ^1,2 ,
CHEN Qing ^1, ,
ZUO Jian-Min ^2,

1.
1. Key Laboratory for Physics and Chemistry of Nanodevices, Department of Electronics, School of Electronics Engineering and Computer Science, Peking University, Beijing 100871;
2. Department of Material Science and Engineering, University of Illinois at Urbana-Champaign, Illinois 61801, USA

Received Date: 17 April 2012
Available Online: 9 May 2012
Fund Project: 国家自然科学基金(60925003) (60925003) 科技部重大研究计划(2012CB932702) (2012CB932702)美国能源部(DEFG02-01ER45923)资助项目 (DEFG02-01ER45923)

Quasi-2-dimensional total amorphous and half-amorphous carbon structures are fabricated from single-layer or few-layer of graphene via high-energy electron beam irradiation. Sample structures before and after electron beam irradiation are recorded by high resolution imaging and coherent nano-area electron diffraction using transmission electron microscopy (TEM). The atomic pair distribution functions of the sample are obtained from electron diffraction patterns. In the quasi-2-dimensional amorphous carbon material, the carbon hexa nal ring structure is not the main structural feature anymore, and the low order nearest distances between carbon atoms are slightly different from that in perfect graphene. Although the sample shows a long-range disordered atomic arrangement, it still holds short-range order and even middle-range order extending to 0.5 nm, as many zigzag carbon chains remain after electron beam irradiation.
- Graphene,
- Quasi-2 dimensional amorphous structure,
- Electron beam irradiation,
- High resolution imaging,
- Electron diffraction,
- Atomic pair distribution function
1. [1]
  
  (1) Zachariasen,W. H. J. Am. Chem. Soc. 1932, 54, 3841. doi: 10.1021/ja01349a006
2. [2]
  (2) Novoselov, K. S.; Geim, A. K.; Morozov, S. V.; Jiang, D.;Zhang, Y.; Dubonos, S. V.; Gri rieva, I. V.; Firsov, A. A.Science 2004, 306, 666. doi: 10.1126/science.1102896
3. [3]
  (3) Mermin, N. D. Phys. Rev. 1968, 176, 250. doi: 10.1103/PhysRev.176.250
4. [4]
  (4) Li, X. S.; Cai,W.W.; An, J. H.; Kim, S. Y.; Nah, J. H.; Yang, D.X.; Piner, R.; Velamakanni, A.; Jung, I.; Tutuc, E.; Banerjee, S.K.; Colombo, L.; Ruoff, R. S. Science 2009, 324, 1312. doi: 10.1126/science.1171245
5. [5]
  (5) Hernandez, Y.; Nicolosi, V.; Lotya, M.; Blighe, F. M.; Sun, Z.Y.; De, S.; Mc vern, I. T.; Holland, B.; Byrne, M.; Gunko, Y.K.; Boland, J. J.; Niraj, P.; Duesberg, G.; Krishnamurthy, S.; odhue, R.; Hutchison, J.; Scardaci, V.; Ferrari, A. C.;Coleman, J. N. Nat. Nanotechnol. 2008, 3, 563.
6. [6]
  (6) Banhart, F.; Kotakoski, J.; Krasheninnikov, A. V. ACS Nano2011, 5, 26. doi: 10.1021/nn102598m
7. [7]
  (7) Hashimoto, A.; Suenaga, K.; Gloter, A.; Urita, K.; Iijima, S.Nature 2004, 430, 870. doi: 10.1038/nature02817
8. [8]
  (8) Girit, C. O.; Meyer, J. C.; Erni, R.; Rossell, M. D.; Kisielowski,C.; Yang, L.; Park, C. H.; Crommie, M. F.; Cohen, M. L.; Louie,S. G.; Zettl, A. Science 2009, 323, 1705. doi: 10.1126/science.1166999
9. [9]
  (9) Huang, P. Y.; Ruiz-Vargas, C. S.; van der Zande, A. M.;Whitney,W. S.; Levendorf, M. P.; Kevek, J.W.; Garg, S.; Alden,J. S.; Hustedt, C. J.; Zhu, Y.; Park, J.; McEuen, P. L.; Muller, D.A. Nature 2011, 469, 389. doi: 10.1038/nature09718
10. [10]
  (10) Lahiri, J.; Lin, Y.; Bozkurt, P.; Oleynik, I. I.; Batzill, M. Nat. Nanotechnol. 2010, 5, 326. doi: 10.1038/nnano.2010.53
11. [11]
  (11) Ying, H.;Wang, Z. Y.; Guo, Z. D.; Shi, Z. J.; Yang, S. F. Acta Phys. -Chim. Sin. 2011, 27, 1482. [应红, 王志永, 郭政铎,施祖进, 杨上峰. 物理化学学报, 2011, 27, 1482.] doi: 10.3866/PKU.WHXB20110630
12. [12]
  (12) mez-Navarro, C.; Meyer, J. C.; Sundaram, R. S.; Chuvilin,A.; Kurasch, S.; Burghard, M.; Kern, K.; Kaiser, U. Nano Lett.2010, 10, 1144. 10.1021/nl9031617
13. [13]
  (13) Chuvilin, A.; Kaiser, U.; Bichoutskaia, E.; Besley, N. A.;Khlobystov, A. N. Nat. Chem. 2010, 2, 450. doi: 10.1038/nchem.644
14. [14]
  (14) Ran, K.; Zuo, J. M.; Chen, Q.; Shi, Z. J. ACS Nano 2011, 4,3367.
15. [15]
  (15) Kotakoski, J.; Krasheninnikov, A. V.; Kaiser, U.; Meyer, J. C.Phys. Rev. Lett. 2011, 106, 105505. doi: 10.1103/PhysRevLett.106.105505
16. [16]
  (16) Warner, J. H.; Rummeli, M. H.; Ge, L.; Gemming, T.;Montanari, B.; Harrison, N. M.; Buchner, B.; Briggs, G. A. D.Nat. Nanotechnol. 2009, 4, 500. doi: 10.1038/nnano.2009.194
17. [17]
  (17) Novoselov, K. S.; Jiang, D.; Schedin, F.; Booth, T. J.;Khotkevich, V. V.; Morozov, S. V.; Geim, A. K. Proc. Natl. Acad. Sci. U. S. A. 2005, 102, 10451. doi: 10.1073/pnas.0502848102
18. [18]
  (18) Meyer, J. C.; Kisielowski, C.; Erni, R.; Rossell, M. D.;Crommie, M. F.; Zettl, A. Nano Lett. 2008, 8, 3582. doi: 10.1021/nl801386m
19. [19]
  (19) Egerton, R. F.; Li, P.; Malac, M. Micron 2004, 35, 399. doi: 10.1016/j.micron.2004.02.003
20. [20]
  (20) Krasheninnikov, A. V.; Banhart, F. Nat. Mater. 2007, 6, 723. doi: 10.1038/nmat1996
21. [21]
  (21) Zuo, J. M.; Gao, M.; Tao, J.; Li, B. Q.; Twesten, R.; Petrov, I.Microsc. Res. Techniq. 2004, 64, 347. doi: 10.1002/jemt.20096
22. [22]
  (22) Wen, J. G.; Mabon, J.; Lei, C. H.; Burdin, S.; Sammann, E.;Petrov, I.; Shah, A. B.; Chobpattana, V.; Zhang, J.; Ran, K.;Zuo, J. M.; Mishina, S.; Aoki, T. Microsc. Microanal. 2010, 16,183. doi: 10.1017/S1431927610000085
23. [23]
  (23) Cockayne, D. J. H. Annu. Rev. Mater. Sci. 2007, 37, 159. doi: 10.1146/annurev.matsci.35.082803.103337
24. [24]
  (24) Egami, T.; Billinge, J. L. Underneath the Bragg Peaks: Structural Analysis of Complex Materials; Pergamon:Amsterdam, 2003; pp 55-99.
25. [25]
  (25) Petkov, V.; Jeong, I. K.; Chung, J. S.; Thorpe, M. F.; Kycia, S.;Billinge, S. J. L. Phys. Rev. Lett. 1999, 83, 4089. doi: 10.1103/PhysRevLett.83.4089
26. [26]
  (26) Petkov, V.; Difrancesco, R. G.; Billinge, S. J. L.; Acharya, M.;Foley, H. C. Philos. Mag. B 1999, 79, 1519.
27. [27]
  (27) Billinge, S. J. L.; DiFrancesco, R. G.; Kwei, G. H.; Neumeier, J.J.; Thompson, J. D. Phys. Rev. Lett. 1996, 77, 715. doi: 10.1103/PhysRevLett.77.715
28. [28]
  (28) Jeong, I. K.; Proffen, T.; Mohiuddin-Jacobs, F.; Billinge, S. J. L.J. Phys. Chem. A 1999, 103, 921. doi: 10.1021/jp9836978
29. [29]
  (29) Ruan, C. Y.; Murooka, Y.; Raman, R. K.; Murdick, R. A.;Worhatch, R. J.; Pell, A. Microsc. Microanal. 2009, 15, 323.doi: 10.1017/S1431927609090709
30. [30]
  (30) Chen, H.; Zuo, J. M. Acta Materialia 2007, 5, 1617.
31. [31]
  (31) McKenzie, D. R.; Green, D. C.; Swift, P. D. Thin Solid Films1990, 193, 418. doi: 10.1016/S0040-6090(05)80052-5
32. [32]
  (32) Li, L.; Reich, S.; Robertson, J. Phys. Rev. B 2005, 72, 184109.doi: 10.1103/PhysRevB.72.184109
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