Citation: MEI Yong-Jun, HAN Yi-Xiu, ZHOU Hong, YAO Lin, JIANG Bo. Synergism between Hydrophobically Modified Polyacrylic Acid and Wormlike Micelles[J]. Acta Physico-Chimica Sinica, ;2012, 28(07): 1751-1756. doi: 10.3866/PKU.WHXB201204233 shu

Synergism between Hydrophobically Modified Polyacrylic Acid and Wormlike Micelles

MEI Yong-Jun ^1,2 ,
HAN Yi-Xiu ² ,
ZHOU Hong ² ,
YAO Lin ¹ ,
JIANG Bo ^1,

1.
1. College of Chemistry, Sichuan University, Chengdu 610065, P. R. China;
2. The Second Research Institute of Civil Aviation Administration of China, Chengdu 610041, P. R. China

Received Date: 15 January 2012
Available Online: 23 April 2012
Fund Project: 国家自然科学基金-民航联合基金(60979020, 60939001)资助项目 (60979020, 60939001)

The synergism between wormlike micelles formed from sodium oleate (NaOA) and hydrophobically modified polyacrylic acid (HMPA) was investigated according to their macroscopic performances and mesoscopic scales, using a combination of viscosity/rheology measurements and dissipative particle dynamics (DPD) molecular simulations. The rheology of NaOA wormlike micelles changed significantly following the addition of a small amount of HMPA, which verified the synergistic effect between them. A peak in the apparent viscosity was observed following an increase in the concentration of HMPA, suggesting that the synergistic effect was restricted by the composition of the mixture. A DPD simulation also confirmed that the solution composition had an influence on the root mean square (RMS) end-to-end distances of HMPA, with the observed value fluctuating according to NaOA and HMPA concentrations. The micellar morphology affected the RMS end-to-end distances of HMPA and the presence of NaOA micelles exerted a significant impact on the extension of HMPA at high HMPA concentrations. A proposed synergistic mechanism has been presented according to the experimental and simulation results.
- Hydrophobically modified polyacrylic acid,
- Wormlike micelle,
- Rheology,
- Apparent viscosity,
- Dissipative particle dynamics molecular simulation,
- Root mean square end-to-end distance
1. [1]
  
  (1) Bjerke, A. E.; Griffiths, P. R.; Theiss,W. Anal. Chem. 1999, 71,1967. doi: 10.1021/ac981093u
2. [2]
  (2) Camara, G. A.; mes, J. F.; Bergamaski, K.; Teixeira-Neto, E.;Nart, F. C. J. Electroanal. Chem. 2008, 617, 171. doi: 10.1016/j.jelechem.2008.02.005
3. [3]
  (3) Sato, T.; Okaya, K.; Yano, H.;Wanatabe, M.; Uchida, H. ACS Catal. 2012, 2, 450. doi: 10.1021/cs200550t
4. [4]
  (4) Zhang, P.;Wang, L. F.; Xu, J. C. Spectroscopy and Spectral Analysis 2003, 23, 46. [张平, 王乐夫, 徐建昌. 光谱学与光谱分析, 2003, 23, 46.]
5. [5]
  (5) Lin,W. F.; Iwasita, T.; Vielstich,W. J. Phys. Chem. B 1999, 103,3250. doi: 10.1021/jp984491+
6. [6]
  (6) Harstein, A.; Kirtley, J. R.; Tsang, J. C. Phys. Rev. Lett. 1980,45, 201. doi: 10.1103/PhysRevLett.45.201
7. [7]
  (7) Osawa, M. Bull. Chem. Soc. Jpn. 1997, 70, 2861. doi: 10.1246/bcsj.70.2861
8. [8]
  (8) Fano, U. Phys. Rev. 1961, 6, 1866.
9. [9]
  (9) Lu, G. Q.; Sun, S. G.; Cai, L. R.; Chen, S. P.; Tian, Z.W.Langmuir 2000, 16, 778. doi: 10.1021/la990282k
10. [10]
  (10) Miki, A.; Ye, S.; Osawa, M. Chem. Commun. 2002, 1500.
11. [11]
  (11) Chen, Y. X.; Miki, A.; Ye, S.; Sakai, H.; Osawa, M. J. Am. Chem. Soc. 2003, 125, 3680. doi: 10.1021/ja029044t
12. [12]
  (12) Huo, S. J.; Xue, X. K.; Yan, Y. G.; Li, Q. X.; Ma, M.; Cai,W.B.; Xu, Q. J.; Osawa, M. J. Phys. Chem. B 2006, 110, 4162. doi: 10.1021/jp0566966
13. [13]
  (13) Huo, S. J.; Xue, X. K.; Li, Q. X.; Xu, S. F.; Cai,W. B. J. Phys. Chem. B 2006, 110, 25721. doi: 10.1021/jp064036a
14. [14]
  (14) Cai, L. R.; Sun, S. G.; Xia, S. Q.; Chen, F.; Zheng, M. S.; Chen,S. P.; Lu, G. Q. Acta Phys. -Chim. Sin. 1999, 15, 1023. [蔡丽蓉, 孙世刚, 夏盛清, 陈芳, 郑明森, 陈声培, 卢国强. 物理化学学报, 1999, 15, 1023.] doi: 10.3866/PKU.WHXB19991113
15. [15]
  (15) ng, H.; Sun, S. G.; Li, J. T.; Chen, Y. J.; Chen, S. P.Electrochim. Acta 2003, 48, 2933. doi: 10.1016/S0013-4686(03)00358-X
16. [16]
  (16) Chen, Q. S.; Sun, S. G.; Yan, J.W.; Li, J. T.; Zhou, Z. Y.Langmuir 2006, 22, 10575. doi: 10.1021/la0615037
17. [17]
  (17) Ortiz, R.; Cuesta, A.; Marquez, O. P.; Gutierrez, C.J. Electroanal. Chem. 1999, 465, 234. doi: 10.1016/S0022-0728(99)00099-6
18. [18]
  (18) Orozco, G.; Gutierrez, C. J. Electroanal. Chem. 2000, 484, 64.doi: 10.1016/S0022-0728(00)00062-0
19. [19]
  (19) Lin,W. G.; Sun, S. G.; Zhou, Z. Y.; Chen, S. P.;Wang, H. C.J. Phys. Chem. B 2002, 106, 11778. doi: 10.1021/jp025917u
20. [20]
  (20) Chen, Z.; Sun, S. G.; Ding, N.; Zhou, Z. Y. Chin. Sci. Bull.2001, 46, 1439. doi: 10.1007/BF03187026
21. [21]
  (21) Chen, Q. S.; Sun, S. G.; Zhou, Z. Y.; Chen, Y. X.; Deng, S. B.Phys. Chem. Chem. Phys. 2008, 10, 3645.
22. [22]
  (22) ng, H.; Sun, S. G.; Chen, Y. J.; Chen, S. P. J. Phys. Chem. B2004, 108, 11575. doi: 10.1021/jp0375822
23. [23]
  (23) Chen, Y. J.; Sun, S. G.; Chen, S. P.; Li, J. T.; ng, H. Langmuir2004, 20, 9920. doi: 10.1021/la048484q
24. [24]
  (24) Feltham, A. M.; Spiro, M. Chem. Rev. 1971, 71, 177. doi: 10.1021/cr60270a002
25. [25]
  (25) Su, Z. F.; Sun, S. G.;Wu, C. X.; Cai, Z. P. J. Chem. Phys. 2008,129, 044707. doi: 10.1063/1.2953441
26. [26]
  (26) Krauth, O.; Fahsold, G.; Pucci, A. J. Mol. Struct. 1999, 482,237. doi: 10.1016/S0022-2860(98)00851-5
27. [27]
  (27) Krauth, O.; Fahsold, G.; Pucci, A. J. Chem. Phys. 1999, 110,3113. doi: 10.1063/1.477907
28. [28]
  (28) Wu, C. X.; Lin, H.; Chen, Y. J.; Li,W. X.; Sun, S. G. J. Chem. Phys. 2004, 121, 1553. doi: 10.1063/1.1763135
29. [29]
  (29) Wu, C. X.; Zhao,W.; Iwamoto, M.; Ouyang, Z. C. J. Chem. Phys. 2000, 112, 10548. doi: 10.1063/1.481688
1. [1]
  Zijian Zhao , Yanxin Shi , Shicheng Li , Wenhong Ruan , Fang Zhu , Jijun Jiang . A New Exploration of the Preparation of Polyacrylic Acid by Free Radical Polymerization Based on the Concept of Green Chemistry. University Chemistry, 2024, 39(5): 315-324. doi: 10.3866/PKU.DXHX202311094
2. [2]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
3. [3]
  Shule Liu . Application of SPC/E Water Model in Molecular Dynamics Teaching Experiments. University Chemistry, 2024, 39(4): 338-342. doi: 10.3866/PKU.DXHX202310029
4. [4]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
5. [5]
  Yaling Chen . Basic Theory and Competitive Exam Analysis of Dynamic Isotope Effect. University Chemistry, 2024, 39(8): 403-410. doi: 10.3866/PKU.DXHX202311093
6. [6]
  Jinfu Ma , Hui Lu , Jiandong Wu , Zhongli Zou . Teaching Design of Electrochemical Principles Course Based on “Cognitive Laws”: Kinetics of Electron Transfer Steps. University Chemistry, 2024, 39(3): 174-177. doi: 10.3866/PKU.DXHX202309052
7. [7]
  Yeyun Zhang , Ling Fan , Yanmei Wang , Zhenfeng Shang . Development and Application of Kinetic Reaction Flasks in Physical Chemistry Experimental Teaching. University Chemistry, 2024, 39(4): 100-106. doi: 10.3866/PKU.DXHX202308044
8. [8]
  Xuzhen Wang , Xinkui Wang , Dongxu Tian , Wei Liu . Enhancing the Comprehensive Quality and Innovation Abilities of Graduate Students through a “Student-Centered, Dual Integration and Dual Drive” Teaching Model: A Case Study in the Course of Chemical Reaction Kinetics. University Chemistry, 2024, 39(6): 160-165. doi: 10.3866/PKU.DXHX202401074
9. [9]
  Dexin Tan , Limin Liang , Baoyi Lv , Huiwen Guan , Haicheng Chen , Yanli Wang . Exploring Reverse Teaching Practices in Physical Chemistry Experiment Courses: A Case Study on Chemical Reaction Kinetics. University Chemistry, 2024, 39(11): 79-86. doi: 10.12461/PKU.DXHX202403048
10. [10]
  Yiying Yang , Dongju Zhang . Elucidating the Concepts of Thermodynamic Control and Kinetic Control in Chemical Reactions through Theoretical Chemistry Calculations: A Computational Chemistry Experiment on the Diels-Alder Reaction. University Chemistry, 2024, 39(3): 327-335. doi: 10.3866/PKU.DXHX202309074
11. [11]
  Yue Wu , Jun Li , Bo Zhang , Yan Yang , Haibo Li , Xian-Xi Zhang . Research on Kinetic and Thermodynamic Transformations of Organic-Inorganic Hybrid Materials for Fluorescent Anti-Counterfeiting Application information: Introducing a Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(6): 390-399. doi: 10.3866/PKU.DXHX202403028
12. [12]
  You Wu , Chang Cheng , Kezhen Qi , Bei Cheng , Jianjun Zhang , Jiaguo Yu , Liuyang Zhang . ZnO/D-A共轭聚合物S型异质结高效光催化产H₂O₂及其电荷转移动力学研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406027-. doi: 10.3866/PKU.WHXB202406027
13. [13]
  Yan Li , Xinze Wang , Xue Yao , Shouyun Yu . Kinetic Resolution Enabled by Photoexcited Chiral Copper Complex-Mediated Alkene E→Z Isomerization: A Comprehensive Chemistry Experiment for Undergraduate Students. University Chemistry, 2024, 39(5): 1-10. doi: 10.3866/PKU.DXHX202309053
14. [14]
  Yujia Luo , Yunpeng Qi , Huiping Xing , Yuhu Li . The Use of Viscosity Method for Predicting the Life Expectancy of Xuan Paper-based Heritage Objects. University Chemistry, 2024, 39(8): 290-294. doi: 10.3866/PKU.DXHX202401037
15. [15]
  Pingping Zhu , Yongjun Xie , Yuanping Yi , Yu Huang , Qiang Zhou , Shiyan Xiao , Haiyang Yang , Pingsheng He . Excavation and Extraction of Ideological and Political Elements for the Virtual Simulation Experiments at Molecular Level: Taking the Project “the Simulation and Computation of Conformation, Morphology and Dimensions of Polymer Chains” as an Example. University Chemistry, 2024, 39(2): 83-88. doi: 10.3866/PKU.DXHX202309063
16. [16]
  Xiyuan Su , Zhenlin Hu , Ye Fan , Xianyuan Liu , Xianyong Lu . Change as You Want: Multi-Responsive Superhydrophobic Intelligent Actuation Material. University Chemistry, 2024, 39(5): 228-237. doi: 10.3866/PKU.DXHX202311059
17. [17]
  Guojie Xu , Fang Yu , Yunxia Wang , Meng Sun . Introduction to Metal-Catalyzed β-Carbon Elimination Reaction of Cyclopropenones. University Chemistry, 2024, 39(8): 169-173. doi: 10.3866/PKU.DXHX202401060
18. [18]
  Qingying Gao , Tao Luo , Jianyuan Su , Chaofan Yu , Jiazhu Li , Bingfei Yan , Wenzuo Li , Zhen Zhang , Yi Liu . Refinement and Expansion of the Classic Cinnamic Acid Synthesis Experiment. University Chemistry, 2024, 39(5): 243-250. doi: 10.3866/PKU.DXHX202311074
19. [19]
  Xingyang LI , Tianju LIU , Yang GAO , Dandan ZHANG , Yong ZHOU , Meng PAN . A superior methanol-to-propylene catalyst: Construction via synergistic regulation of pore structure and acidic property of high-silica ZSM-5 zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1279-1289. doi: 10.11862/CJIC.20240026
20. [20]
  Cunming Yu , Dongliang Tian , Jing Chen , Qinglin Yang , Kesong Liu , Lei Jiang . Chemistry “101 Program” Synthetic Chemistry Experiment Course Construction: Synthesis and Properties of Bioinspired Superhydrophobic Functional Materials. University Chemistry, 2024, 39(10): 101-106. doi: 10.12461/PKU.DXHX202408008

Get Citation

PDF

XML

Metrics

PDF Downloads(851)
Abstract views(2416)
HTML views(3)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142