Citation:
CHU Ling-Ling, GAO Yu-Rong, WU Ming-Xing, WANG Lin-Lin, MA Ting-Li. Fabrication and Application of a Carbon Counter Electrode with Excellent Adhesion Properties for Dye-Sensitized Solar Cells[J]. Acta Physico-Chimica Sinica,
;2012, 28(07): 1739-1744.
doi:
10.3866/PKU.WHXB201204232
-
The aim of this study was to resolve the poor bonding strength between carbon film and the conductive substrate in a carbon counter electrode. A carbon black-conductive carbon (Cb-CC) counter electrode was fabricated using a low-cost commercial conductive carbon paste (CC) as a binder and carbon black (Cb) as a catalyst. Film adhesion test results indicated that the introduction of the CC significantly improved the adhesion between Cb and the conductive substrate, as well as the conductivity and stability of the carbon counter electrode. The porous structure of the mixed CC and Cb carbon films was maintained as illustrated by scanning electron microscopy (SEM). Cyclic-voltammetry (CV) and electrochemical impedance spectroscopy (EIS) measurements showed that the catalytic activity of CC-Cb was superior to that of CC. A dye-sensitized solar cell (DSSC) based on the CC-Cb counter electrode exhibited an excellent photoelectrical performance, reaching an energy conversion efficiency of 6.54%. The amount of CC in the carbon counter electrode was further optimized. Consequently, when the mass ratio of Cb:CC reached 23:77, the corresponding DSSC yielded the highest energy conversion efficiency recorded in this study at 6.81% . In addition, long term stability testing showed that the photovoltaic parameters of the DSSC based on the CC-Cb counter electrode remained similar to the initial values following more than 700 h of light soaking. This work has laid the foundation for improving the stability and the industrialization of low-cost DSSCs.
-
-
-
[1]
(1) Snaith, H. J.; Schmidt-Mende, L. Adv. Mater. 2007, 19, 3187.doi: 10.1002/adma.200602903
-
[2]
(2) Papageorgiou, N.; Maier,W. F.; Grätzel, M. Electrochem. Soc.1997, 144, 876. doi: 10.1149/1.1837502
-
[3]
(3) Ma, T. L.; Fang, X. M.; Akiyama, M.; Inoue, K.; Noma, H.;Abe, E. Electroanal. Chem. 2004, 574, 77. doi: 10.1016/j.jelechem.2004.08.002
-
[4]
(4) Fang, X. M.; Ma, T. L.; Guan, G. Q.; Akiyama, M.; Kida, T.;Abe, E. J. Electroanal. Chem. 2004, 570, 257. doi: 10.1016/j.jelechem.2004.04.004
-
[5]
(5) Nazeeruddin, M. K.; Kay, A.; Rodicio, I.; Humphry-Baker, R.;Mueller, E.; Liska, P.; Vlachopoulos, M.; Grätzel, M. J. Am. Chem. Soc. 1993, 115, 6382. doi: 10.1021/ja00067a063
-
[6]
(6) Li, P. J.;Wu, J. H.; Lin, J. M.; Huang, M. L.; Lan, Z.; Li, Q. H.Electrochim. Acta 2008, 53, 4161. doi: 10.1016/j.electacta.2007.12.073
-
[7]
(7) Gao, F.;Wang, Y.; Shi, D.; Zhang, J.;Wang, M. K.; Jing, X. Y.;Humphry-Baker, R.;Wang, P.; Zakeeruddin, S. M.; Grätzel, M.J. Am. Chem. Soc. 2008, 130, 10720. doi: 10.1021/ja801942j
-
[8]
(8) Olsen, E.; Hagen, G.; Eric Lindquist, S. Sol. Energy Mater. Sol. Cells 2000, 63, 267. doi: 10.1016/S0927-0248(00)00033-7
-
[9]
(9) Gao, B.; Chen, S. Y.; Fu, Q. B.; Yuan, C. Z.; Zhang, X. G.Trans. Nonferrous Met. Soc. China 2009, 19, 1642. [高博,陈胜尧, 傅清宾, 原长洲, 张校刚. 中国有色金属学报, 2009,19, 1642.]
-
[10]
(10) Zhu, Q. F.; Zhang, H. Y.; Chen, Y. M.; Chen, Y. T.; Chen, L. C.;Yang, D. Y. Acta Optica Sinica 2008, 28, 1824. [朱清锋, 张海燕, 陈易明, 陈雨婷, 陈列春, 杨大勇. 光学学报, 2008, 28,1824.] doi: 10.3788/AOS20082809.1824
-
[11]
(11) Murakami, T. N.; Ito, S.;Wang, Q.; Nazeeruddin, M. K.;Bessho, T.; Cesar, I.; Liska, P.; Humphry-Baker, R.; Comte, P.;Pechy, P.; Grätzel, M. J. Electrochem. Soc. 2006, 153, 2255.doi: 10.1149/1.2358087
-
[12]
(12) Imoto, K.; Takahashi, K.; Yamaguchi, T.; Komura, T.;Nakamura, J.; Murata, K. Sol. Energy Mater. Sol. Cells 2003,79, 459. doi: 10.1016/S0927-0248(03)00021-7
-
[13]
(13) Wang, G.;Wang, L.; Xing,W.; Zhuo, S. Mater. Chem. Phys.2010, 123, 690. doi: 10.1016/j.matchemphys.2010.05.038
-
[14]
(14) Ramasamy, E.; Lee, J. Carbon 2010, 48, 3715. doi: 10.1016/j.carbon.2010.06.033
-
[15]
(15) Veerappan, G.; Bojan, K.; Rhee, S.W. Appl. Mater. Interfaces2011, 3, 857. doi: 10.1021/am101204f
-
[16]
(16) Han, J.; Kim, H.; Kim, D, Y.; Jo, S. M.; Jang, S. Y. Nano 2010,4, 3503.
-
[17]
(17) Lee,W. J.; Ramasamy, E.; Lee, D. Y.; Song, J. S. Appl. Mater. Interfaces 2009, 1, 1145. doi: 10.1021/am800249k
-
[18]
(18) Ramasamy, E.; Lee,W. J.; Lee, D. Y.; Song, J. S. Electrochem. Commun. 2008, 10, 1087. doi: 10.1016/j.elecom.2008.05.013
-
[19]
(19) Hong,W.; Xu, Y.; Lu, G.; Li, C.; Shi, G. Electrochem. Commun.2008, 10, 1555.
-
[20]
(20) Wan, L.;Wang, S.;Wang, X. B.; Dong, B. H.; Xu, Z. X.; Zhang,X. H.; Yang, B.; Peng, S. M.;Wang, J. C.; Xu, C. H. Solid State Sci. 2011, 13, 468.
-
[21]
(21) Roy-Mayhew, J. D.; Bozym, D. J.; Punckt, C.; Aksay, I. A.Nano 2010, 4, 6203.
-
[22]
(22) Choi, H.; Kim, H.; Hwang, S.; Choi,W.; Jeon, M. Sol. Energy Mater. Sol. Cells 2011, 95, 323. doi: 10.1016/j.solmat.2010.04.044
-
[23]
(23) Li, J.; Sun, M. X.; Zhang, X. Y.; Cui, X. L. Acta Phys. -Chim. Sin. 2011, 27, 2255. [李靖, 孙明轩, 张晓艳, 崔晓莉. 物理化学学报, 2011, 27, 2255.] doi: 10.3866/PKU.WHXB20110901
-
[24]
(24) Joshi, P.; Xie, Y.; Ropp, M.; Galipeau, D.; Bailey, S.; Qiao, Q.Q. Energy Environ. Sci. 2009, 2, 426. doi: 10.1039/b815947p
-
[25]
(25) Wu, M. X.; Lin, X.;Wang, T. H.; Qiu, J. S.; Ma, T. L. Energy Environ. Sci. 2011, 4, 2308. doi: 10.1039/c1ee01059j
-
[26]
(26) Malara, F.; Manca, M.; De Marco, L.; Pareo, P.; Gigli, G. Appl. Mater. Interfaces 2011, 3, 3625. doi: 10.1021/am200838q
-
[27]
(27) Hu, L. B.; Choi, J.W.; Yang, Y.; Jeong, S. Mantia, F. L.; Cui, L.F.; Cui, Y. Proc. Natl. Acad. Sci. U. S. A. 2009, 106, 21490. doi: 10.1073/pnas.0908858106
-
[1]
-
-
-
[1]
Shitao Fu , Jianming Zhang , Cancan Cao , Zhihui Wang , Chaoran Qin , Jian Zhang , Hui Xiong . Study on the Stability of Purple Cabbage Pigment. University Chemistry, 2024, 39(4): 367-372. doi: 10.3866/PKU.DXHX202401059
-
[2]
Jiaxi Xu , Yuan Ma . Influence of Hyperconjugation on the Stability and Stable Conformation of Ethane, Hydrazine, and Hydrogen Peroxide. University Chemistry, 2024, 39(11): 374-377. doi: 10.3866/PKU.DXHX202402049
-
[3]
Hailian Tang , Siyuan Chen , Qiaoyun Liu , Guoyi Bai , Botao Qiao , Fei Liu . Stabilized Rh/hydroxyapatite Catalyst for Furfuryl Alcohol Hydrogenation: Application of Oxidative Strong Metal-Support Interactions in Reducing Conditions. Acta Physico-Chimica Sinica, 2025, 41(4): 100036-. doi: 10.3866/PKU.WHXB202408004
-
[4]
Bo YANG , Gongxuan LÜ , Jiantai MA . Corrosion inhibition of nickel-cobalt-phosphide in water by coating TiO2 layer. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 365-384. doi: 10.11862/CJIC.20240063
-
[5]
Yixuan Gao , Lingxing Zan , Wenlin Zhang , Qingbo Wei . Comprehensive Innovation Experiment: Preparation and Characterization of Carbon-based Perovskite Solar Cells. University Chemistry, 2024, 39(4): 178-183. doi: 10.3866/PKU.DXHX202311091
-
[6]
Xuyang Wang , Jiapei Zhang , Lirui Zhao , Xiaowen Xu , Guizheng Zou , Bin Zhang . Theoretical Study on the Structure and Stability of Copper-Ammonia Coordination Ions. University Chemistry, 2024, 39(3): 384-389. doi: 10.3866/PKU.DXHX202309065
-
[7]
Yipeng Zhou , Chenxin Ran , Zhongbin Wu . Metacognitive Enhancement in Diversifying Ideological and Political Education within Graduate Course: A Case Study on “Solar Cell Performance Enhancement Technology”. University Chemistry, 2024, 39(6): 151-159. doi: 10.3866/PKU.DXHX202312096
-
[8]
Yueguang Chen , Wenqiang Sun . “Carbon” Adventures. University Chemistry, 2024, 39(9): 248-253. doi: 10.3866/PKU.DXHX202308074
-
[9]
Xiaoning TANG , Junnan LIU , Xingfu YANG , Jie LEI , Qiuyang LUO , Shu XIA , An XUE . Effect of sodium alginate-sodium carboxymethylcellulose gel layer on the stability of Zn anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1452-1460. doi: 10.11862/CJIC.20240191
-
[10]
Pengyu Dong , Yue Jiang , Zhengchi Yang , Licheng Liu , Gu Li , Xinyang Wen , Zhen Wang , Xinbo Shi , Guofu Zhou , Jun-Ming Liu , Jinwei Gao . NbSe2纳米片优化钙钛矿太阳能电池的埋底界面. Acta Physico-Chimica Sinica, 2025, 41(3): 2407025-. doi: 10.3866/PKU.WHXB202407025
-
[11]
Jing SU , Bingrong LI , Yiyan BAI , Wenjuan JI , Haiying YANG , Zhefeng Fan . Highly sensitive electrochemical dopamine sensor based on a highly stable In-based metal-organic framework with amino-enriched pores. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1337-1346. doi: 10.11862/CJIC.20230414
-
[12]
Xuewei BA , Cheng CHENG , Huaikang ZHANG , Deqing ZHANG , Shuhua LI . Preparation and luminescent performance of Sr1-xZrSi2O7∶xDy3+ phosphor with high thermal stability. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 357-364. doi: 10.11862/CJIC.20240096
-
[13]
Renqing Lü , Shutao Wang , Fang Wang , Guoping Shen . Computational Chemistry Aided Organic Chemistry Teaching: A Case of Comparison of Basicity and Stability of Diazine Isomers. University Chemistry, 2025, 40(3): 76-82. doi: 10.12461/PKU.DXHX202404119
-
[14]
Baitong Wei , Jinxin Guo , Xigong Liu , Rongxiu Zhu , Lei Liu . Theoretical Study on the Structure, Stability of Hydrocarbon Free Radicals and Selectivity of Alkane Chlorination Reaction. University Chemistry, 2025, 40(3): 402-407. doi: 10.12461/PKU.DXHX202406003
-
[15]
Zeyuan WANG , Songzhi ZHENG , Hao LI , Jingbo WENG , Wei WANG , Yang WANG , Weihai SUN . Effect of I2 interface modification engineering on the performance of all-inorganic CsPbBr3 perovskite solar cells. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1290-1300. doi: 10.11862/CJIC.20240021
-
[16]
Jizhou Liu , Chenbin Ai , Chenrui Hu , Bei Cheng , Jianjun Zhang . 六氯锡酸铵促进钙钛矿太阳能电池界面电子转移及其飞秒瞬态吸收光谱研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2402006-. doi: 10.3866/PKU.WHXB202402006
-
[17]
Xiaoyao YIN , Wenhao ZHU , Puyao SHI , Zongsheng LI , Yichao WANG , Nengmin ZHU , Yang WANG , Weihai SUN . Fabrication of all-inorganic CsPbBr3 perovskite solar cells with SnCl2 interface modification. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 469-479. doi: 10.11862/CJIC.20240309
-
[18]
Xiaomei Ning , Liang Zhan , Xiaosong Zhou , Jin Luo , Xunfu Zhou , Cuifen Luo . Preparation and Electro-Oxidation Performance of PtBi Supported on Carbon Cloth: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(11): 217-224. doi: 10.3866/PKU.DXHX202401085
-
[19]
Bowen Yang , Rui Wang , Benjian Xin , Lili Liu , Zhiqiang Niu . C-SnO2/MWCNTs Composite with Stable Conductive Network for Lithium-based Semi-Solid Flow Batteries. Acta Physico-Chimica Sinica, 2025, 41(2): 100015-. doi: 10.3866/PKU.WHXB202310024
-
[20]
Yu'ang Liu , Yuechao Wu , Junyu Huang , Tao Wang , Xiaohong Liu , Tianying Yan . Computation of Absolute Electrode Potential of Standard Hydrogen Electrode Using Ab Initio Method. University Chemistry, 2025, 40(3): 215-222. doi: 10.12461/PKU.DXHX202407112
-
[1]
Metrics
- PDF Downloads(1019)
- Abstract views(2738)
- HTML views(16)