Citation: LIN Xue, GUAN Qing-Feng, LI Hai-Bo, LI Hong-Ji, BA Chun-Hua, DENG Hai-De. Bi_3.25Nd_0.75Ti₃O₁₂ Nanostructures: Controllable Synthesis and Visible-Light Photocatalytic Activities[J]. Acta Physico-Chimica Sinica, ;2012, 28(06): 1481-1488. doi: 10.3866/PKU.WHXB201203313 shu

Bi_3.25Nd_0.75Ti₃O₁₂ Nanostructures: Controllable Synthesis and Visible-Light Photocatalytic Activities

1.
1. School of Materials Science and Engineering, Jiangsu University, Zhenjiang 212013, Jiangsu Province, P. R. China;
2. College of Chemistry, Key Laboratory of Preparation and Application Environmentally Friendly Materials of the Ministry of Education, Jilin Normal University, Siping 136000, Jilin Province, P. R. China;
3. College of Physics, Jilin Normal University, Siping 136000, Jilin Province, P. R. China

Received Date: 13 February 2012
Available Online: 31 March 2012
Fund Project:

Neodymium-doped bismuth titanate (Bi_3.25Nd_0.75Ti₃O₁₂, BNdT) nanostructures with different morphologies were synthesized hydrothermally without using surfactant or template. Transmission electron microscopy (TEM) results showed that different morphologies could be fabricated simply by manipulating the concentration of OH^- ions during hydrothermal synthesis. Hydroxide ions played an important role in controlling the formation of seeds and the growth rate of BNdT particles. On the basis of structural analysis of samples obtained under different conditions, a possible mechanism for the formation of these distinctive morphologies was proposed. A UV-visible diffuse reflectance spectrum (UV-Vis DRS) of an as-prepared BNdT sample revealed that its band gap energy (E_g) was about 1.984 eV. BNdT photocatalysts exhibited higher photocatalytic activities for the degradation of methyl orange (MO) under visible light irradiation than those for traditional commercial P25 TiO₂ and N-doped TiO₂ (N-TiO₂). BNdT nanowires prepared using a hydroxide concentration of 10 mol·L^-1 showed the highest photocatalytic activity among the samples. Over this catalyst, 93.0% degradation of MO (0.01 mmol·L^-1) was obtained after irradiation with visible light for 360 min. In addition, there was no significant decrease in photocatalytic activity after the catalyst was used 4 times, indicating that BNdT is a stable photocatalyst for degradation of MO under visible light irradiation.
- Bismuth titanate,
- Neodymium doping,
- Nanostructure,
- Hydrothermal synthesis,
- Photocatalytic degradation,
- Visible light irradiation
1. [1]
  (1) Uyguner-Demirel, C. S.; Bekbolet, M. Chemosphere 2011, 84, 1009. doi: 10.1016/j.chemosphere.2011.05.003
2. [2]
  (2) Yu, J. G.; Xiang, Q. J.; Zhou, M. H. Appl. Catal. B: Environ. 2009, 90, 595. doi: 10.1016/j.apcatb.2009.04.021
3. [3]
  (3) Xu, D.; Gao, A. M.; Deng, W. L. Acta Phys. -Chim. Sin. 2008, 24 (7), 1219. [许迪, 高爱梅, 邓文礼. 物理化学学报, 2008, 24 (7), 1219.] doi: 10.3866/PKU.WHXB20080717
4. [4]
  (4) Xie, J.; Wang H.; Duan, M. Acta Phys. -Chim. Sin. 2011, 27 (1), 193. [谢娟, 王虎, 段明. 物理化学学报, 2011, 27 (1): 193.] doi: 10.3866/PKU.WHXB20110124
5. [5]
  (5) Yang, X. H.; Liu, C.; Liu, J. K.; Zhu, Z. C. Acta Phys. -Chim. Sin. 2011, 27 (12), 2939. [杨小红, 刘畅, 刘金库, 朱子春. 物理化学学报, 2011, 27 (12), 2939.] doi: 10.3866/PKU.WHXB20112939
6. [6]
  (6) Hu, Y. F.; Li, Y. X.; Peng, S. Q.; Lv, G. X.; Li, S. B. Acta Phys. -Chim. Sin., 2008, 24 (11), 2071. [胡元方, 李越湘, 彭绍琴, 吕功煊, 李树本. 物理化学学报, 2008, 24 (11), 2071.] doi: 10.3866/PKU.WHXB20081123
7. [7]
  (7) Li, A. C.; Li, G. H.; Zheng, Y.; Feng, L. L.; Zheng, Y. J. Acta Phys. -Chim. Sin. 2012, 28 (2), 457. [李爱昌, 李桂花, 郑琰, 冯玲玲, 郑彦俊. 物理化学学报, 2012, 28 (2), 457.] doi: 10.3866/PKU.WHXB201112081
8. [8]
  (8) Zhang, Q.; He, Y. Q.; Chen, X. G.; Hu, D. H.; Li, L. J.; Yin, T.; Ji, L. L.Acta Phys. -Chim. Sin. 2010, 26 (3), 654. [张琼, 贺蕴秋, 陈小刚, 胡栋虎, 李林江, 尹婷, 季伶俐. 物理化学学报, 2010, 26 (3), 654.] doi: 10.3866/PKU.WHXB20100318
9. [9]
  (9) Shen, J. J.; Liu, C.; Zhu, Y. D.; Li, W.; Feng, X.; Lu, X. H. Acta Phys. -Chim. Sin. 2009, 25 (5), 1013. [沈晶晶, 刘畅, 朱育丹, 李伟, 冯新, 陆小华. 物理化学学报, 2009, 25 (5), 1013.] doi: 10.3866/PKU.WHXB20090421
10. [10]
  (10) Ghorai, T. K.; Biswas, S. K.; Pramanik, P. Appl. Surf. Sci. 2008, 254, 7498. doi: 10.1016/j.apsusc.2008.06.042
11. [11]
  (11) Wang, H. Q.; Wu, Z. B.; Liu, Y.; Wang, Y. J. Chemosphere 2008, 74, 773.
12. [12]
  (12) Zhang, J. W.; Jin, Z. S.; Feng, C. X.; Yu, L. G.; Zhang, J. W.; Zhang, Z. J. J. Solid State Chem. 2011, 184, 3066. doi: 10.1016/j.jssc.2011.09.016
13. [13]
  (13) Liu, D. R.; Jiang, Y. S.; Gao, G. M. Chemosphere 2011, 83, 1546. doi: 10.1016/j.chemosphere.2011.01.033
14. [14]
  (14) Yu, J. Q.; Zhang, Y.; Kudo, A. J. Solid State Chem. 2009, 182, 223. doi: 10.1016/j.jssc.2008.10.021
15. [15]
  (15) Zhang, L.; Cao, X. F.; Chen, X. T.; Xue, Z. L. J. Colloid Interface Sci. 2011, 354, 630. doi: 10.1016/j.jcis.2010.11.042
16. [16]
  (16) Zhang, L. S.; Wang, H. L.; Chen, Z. G.; Wong, P. K.; Liu, J. S. Appl. Catal. B: Environ. 2011, 106, 1.
17. [17]
  (17) Hou, J. G.; Wang, Z.; Jiao, S. Q.; Zhu, H. M. J. Hazard. Mater. 2011, 192, 1772. doi: 10.1016/j.jhazmat.2011.07.013
18. [18]
  (18) Hou, J. G.; Cao, R.; Jiao, S. Q.; Zhu, H. M.; Kumar, R. V. Appl. Catal. B: Environ. 2011, 104, 399. doi: 10.1016/j.apcatb.2011.02.032
19. [19]
  (19) Thanabodeekij, N.; Gulari, E.; Wongkasemjit, S. Powder Technol. 2005, 160, 203. doi: 10.1016/j.powtec.2005.08.015
20. [20]
  (20) Hou, J. G.; Jiao, S. Q.; Zhu, H. M.; Kumar, R. V. J. Solid State Chem. 2011, 184, 154. doi: 10.1016/j.jssc.2010.11.017
21. [21]
  (21) Zhou, T. F.; Hu, J. C. Environ. Sci. Technol. 2010, 44, 8698. doi: 10.1021/es1019959
22. [22]
  (22) Cheng, H. F.; Huang, B. B.; Dai, Y.; Qin, X. Y.; Zhang, X. Y.; Wang, Z. Y.; Jiang, M. H. J. Solid State Chem. 2009, 182, 2274. doi: 10.1016/j.jssc.2009.06.006
23. [23]
  (23) Lin, X.; Guan, Q. F.; Liu, Y.; Li, H. B. Chin. Phys. B 2010, 19, 107701. doi: 10.1088/1674-1056/19/10/107701
24. [24]
  (24) Lin, X.; Guan, Q. F.; Li, H. B.; Liu, Y.; Zou, G. T. Sci. China-Phys. Mech. Astron. 2012, 55, 33. doi: 10.1007/s11433-011-4574-8
25. [25]
  (25) Xu, J. J.; Chen, M. D.; Fu, D. G. Appl. Surf. Sci. 2011, 257, 7381. doi: 10.1016/j.apsusc.2011.02.030
26. [26]
  (26) Xu, J.; Wang, W. Z.; Shang, M.; Gao, E. P.; Zhang, Z. J.; Ren, J. J. Hazard. Mater. 2011, 196, 426. doi: 10.1016/j.jhazmat.2011.09.010
27. [27]
  (27) Yu, H. G.; Yu, J. G.; Cheng, B. Chemosphere 2007, 66, 2050. doi: 10.1016/j.chemosphere.2006.09.080
28. [28]
  (28) Wang, Z. Z.; Qi, Y. J.; Qi, H. Y.; Lu, C. J.; Wang, S. M. J Mater Sci: Mater Electron 2010, 21, 523. doi: 10.1007/s10854-009-9950-z
29. [29]
  (29) Yao, W. F.; Xu, X. H.; Wang, H.; Zhou, J. T.; Yang, X. N.; Zhang, Y.; Shang, S. X.; Huang, B. B. Appl. Catal. B: Environ. 2004, 52, 109. doi: 10.1016/j.apcatb.2004.04.002
30. [30]
  (30) Xu, G. C.; Pan, L.; Guan, Q. F.; Zou, G. T. Acta Physica Sinica 2006, 55, 3080. [徐国成潘玲, 关庆丰, 邹广田. 物理学报, 2006, 55, 3080.] doi: 10.3321/j.issn:1000-3290.2006.06.073
31. [31]
  (31) Hou, Y. D.; Wang, X. C.; Wu, L.; Chen, X. F.; Ding, Z. X.; Wang, X. X.; Fu, X. Z. Chemosphere 2008, 72, 414. doi: 10.1016/j.chemosphere.2008.02.035
32. [32]
  (32) Jiang, X. P.; Lin, M.; Tu, N.; Chen, C.; Zhou, S. L.; Zhan, H. Q. J. Alloy. Compd. 2011, 509, 9346. doi: 10.1016/j.jallcom.2011.07.034
33. [33]
  (33) Yang, J. H.; Zheng, J. H.; Zhai, H. J.; Yang, L. L.; Lang, J. H.; Gao M. J. Alloy. Compd. 2009, 481, 628. doi: 10.1016/j.jallcom.2009.03.108
34. [34]
  (34) Arrouvel, C.; Digne, M.; Breysse, M.; Toulhoat, H.; Raybaud, P. J. Catal. 2004, 222, 152. doi: 10.1016/j.jcat.2003.10.016
35. [35]
  (35) Hou, L.; Hou, Y. D.; Song, X. M.; Zhu, M. K.; Wang, H.; Yan, H. Mater. Res. Bull. 2006, 41, 1330. doi: 10.1016/j.materresbull.2005.12.010
36. [36]
  (36) Zhu, X. Q.; Zhang, J. L.; Chen, F. Chemosphere 2010, 78, 1350. doi: 10.1016/j.chemosphere.2010.01.002
37. [37]
  (37) to, T.; Noguchi, Y.; Soga, M.; Miyayama, M. Mater. Res. Bull. 2005, 40, 1044. doi: 10.1016/j.materresbull.2005.02.025
38. [38]
  (38) Cai, M. Q.; Yin, Z.; Zhang, M. S.; Li, Y. Z. Chem. Phys. Lett. 2004, 399, 89. doi: 10.1016/j.cplett.2004.09.143
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沈阳化工大学材料科学与工程学院沈阳 110142

Bi3.25Nd0.75Ti3O12 Nanostructures: Controllable Synthesis and Visible-Light Photocatalytic Activities

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Bi_3.25Nd_0.75Ti₃O₁₂ Nanostructures: Controllable Synthesis and Visible-Light Photocatalytic Activities