Citation: ZHU Qiu-Feng, ZHANG Rong-Jun, HE De-Hua. Effect of CaO Modification on Performance of CuZnAlZr Catalyst in Synthesis of Higher Alcohols from Synthesis Gas[J]. Acta Physico-Chimica Sinica, ;2012, 28(06): 1461-1466. doi: 10.3866/PKU.WHXB201203302 shu

Effect of CaO Modification on Performance of CuZnAlZr Catalyst in Synthesis of Higher Alcohols from Synthesis Gas

1.
Innovative Catalysis Program, Key Laboratory of Organic Optoelectronics and Molecular Engineering of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, P. R. China

Received Date: 7 January 2012
Available Online: 30 March 2012
Fund Project: 国家高技术研究发展计划(863)(2007AA05Z332)资助项目 (863)(2007AA05Z332)

CaO modified CuZnAlZr mixed oxide catalysts were prepared by mechanical mixing and co-precipitation methods, and their catalytic performances for CO hydrogenation to higher alcohols were investigated using a continuous flow high-pressure fixed-bed micro-reactor. The catalysts were characterized by X-ray diffraction (XRD), N₂-adsorption-desorpotion, temperature-programmed reduction of H₂ (H₂-TPR), and temperature-programmed desorption of CO₂ (CO₂-TPD). The results showed that doping with CaO did not alter the textural properties of the catalyst, but increased the number of basic sites. Furthermore, the CaO-modified CuZnAlZr catalysts possessed both weak and medium strength basic sites, while unmodified CuZnAlZr catalyst possessed only weak basic sites. Catalytic performance, assessed by CO hydrogenation to C₂₊ alcohols, was improved in the CaO-doped CuZnAlZr catalyst relative to the undoped catalyst.
- CaO modification,
- CuZnAlZr catalyst,
- Synthesis gas,
- Higher alcohol
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