Citation: WANG Yue-Hui, SHEN Jian-Hong. Effects of Silver Nanoparticles with Different Electrical Properties on the Spectroscopic Properties of Methyl Orange[J]. Acta Physico-Chimica Sinica, ;2012, 28(06): 1313-1319. doi: 10.3866/PKU.WHXB201203292 shu

Effects of Silver Nanoparticles with Different Electrical Properties on the Spectroscopic Properties of Methyl Orange

WANG Yue-Hui ^1, ,
SHEN Jian-Hong ²

1.
1. Department of Chemistry and Biology, University of Electronic Science and Technology of China Zhongshan Institute, Zhongshan 528402, Guangdong Province, P. R. China;
2. School of Materials Science and Engineering, Henan University of Technology, Zhengzhou 450001, P. R. China

Received Date: 7 February 2012
Available Online: 29 March 2012
Fund Project: 国家自然科学基金(50272032) (50272032) 广东省自然科学基金(7300212) (7300212) 电子科技大学中山学院科研启动基金(407YKQ06) (407YKQ06)河南工业大学博士基金(150060)资助项目 (150060)

The effects of positive/negative silver nanoparticles on the spectroscopic properties of methyl orange (MO) in solution at different pH values were studied by UV-visible (UV-Vis) absorption spectroscopy and fluorometry. New complexes were formed by the strong electrostatic interaction between positive silver nanoparticles (P-Ag) and the MO so that UV-Vis absorption spectra showed the performance of the complexes. However, the UV-Vis absorption spectra only showed superposition of component peaks after addition of negative silver nanoparticles (N-Ag) to MO solution because of the weak interaction between N-Ag and MO induced by electrostatic repulsion. S₁→S₀ was significantly enhanced in the MO solution containing P-Ag. The largest and smallest fluorescence enhancement ratios were observed at pH 2.1 and 4.8, respectively. The fluorescence intensity of S₂→S₀ decreased and was almost independent of pH. Similar trends were observed for the MO solution containing N-Ag, except that the intensity of S₁→S₀ was slightly enhanced in the presence of a small amount of N-Ag. The effects of silver nanoparticles with different electrical properties on the spectroscopic properties of MO depend on the interaction between MO and the silver nanoparticles as well as local field enhancement and non-radiative energy transfer.
- Silver nanoparticle,
- Methyl orange,
- Local field enhancement,
- Fluorescence enhancement,
- Electrical property
1. [1]
  (1) Lakowicz, J. R. Anal . Biochem. 2001, 298, 1. doi: 10.1006/abio.2001.5377
2. [2]
  (2) Fu, Y.; Zhang, J.; Lakowicz, J. R. Biochem. Biophys. Res. Commun. 2008, 376, 712. doi: 10.1016/j.bbrc.2008.09.062
3. [3]
  (3) Szmacini, H.; Ray, K.; Lakowicz, J. R. Anal. Biochem. 2009, 385, 358. doi: 10.1016/j.ab.2008.11.025
4. [4]
  (4) Gryczynski, I.; Malicka, J.; Gryczynski, Z.; Lakowicz, J. R. Anal. Biochem. 2004, 324, 170. doi: 10.1016/j.ab.2003.09.036
5. [5]
  (5) Lakowicz, J. R. Anal. Biochem. 2005, 337, 171. doi: 10.1016/j.ab.2004.11.026
6. [6]
  (6) Zhang, Y.; Dragan, A.; Geddes, C. D. J. Phys. Chem. C 2009, 113, 12095. doi: 10.1021/jp9005668
7. [7]
  (7) Aslan, K.; Geddes, C. D. Anal. Chem. 2009, 81, 6913. doi: 10.1021/ac900973r
8. [8]
  (8) Aslan, K.; Weisenberg, M.; Hortle, E.; Geddes, C. D. J. Appl. Phys.2009, 106, 014313-1-3.
9. [9]
  (9) Aslan, K.; McDonald, K.; Michael, J. R. Zhang Y.; Zhang, Geddes, C. D.Chem. Phys. Lett. 2008, 464, 216. doi: 10.1016/j.cplett.2008.09.041
10. [10]
  (10) Dragan, A. I.; Zhang, Y.; Geddes, C. D. J. Fluoresc. 2009, 19, 369. doi: 10.1007/s10895-009-0460-4
11. [11]
  (11) Aslan, K.; Geddes, C. D. Appl. Phys. Lett. 2009, 94, 073104-1-3.
12. [12]
  (12) Wang, Y.; Zhou, X.; Wang, T.; Zhou, J. Maters. Lett. 2008, 62, 3582. doi: 10.1016/j.matlet.2008.04.005
13. [13]
  (13) Wang, Y.; Zhou, J.; Wang, T. Maters. Lett., 2008, 62, 1937. doi: 10.1016/j.matlet.2007.10.045
14. [14]
  (14) Wang,Y.;Zhou, J.; Wang, T. Chin. J. Inorg. Chem. 2008, 24, 409. [王悦辉, 周济, 王婷. 无机化学学报, 2008, 24, 409.]
15. [15]
  (15) Wang, Y.; Zhou, J.; Wang, T. Chin. J. Inorg. Chem . 2008, 24, 205. [王悦辉, 周济, 王婷. 无机化学学报, 2008, 24, 205.]
16. [16]
  (16) Nabika, H.; Deki, S. J. Phys. Chem. B 2003, 107, 9161. doi: 10.1021/jp035741b
17. [17]
  (17) Gryczynski, Z.; Borejdo, J.; Calander, N. Anal. Biochem. 2006, 356, 125. doi: 10.1016/j.ab.2006.05.007
18. [18]
  (18) Marchi, M. C.; Bilmes, S. A.; Bilmes, G. M. J. Colloid Interface Sci. 1999, 218, 112. doi: 10.1006/jcis.1999.6379
19. [19]
  (19) Weitz, D. A.; Garoff, S. J. Chem. Phys. 1983, 78, 5324. doi: 10.1063/1.445486
20. [20]
  (20) Wang,Y.; Zhu, Y.; Zhu, S. Spectroscopy and Spectral Analysis 2011, 31, 1295. [王悦辉, 朱一水, 朱朔萱. 光谱学与光谱分析, 2011, 31, 1295.]
21. [21]
  (21) Si, M. Z.; Wu, R. G.; Zhang, P. X. Chin. J. Chem. Phys. 2001, 14, 465. [司民真, 武荣国, 张鹏翔. 化学物理学报, 2001, 14, 465]
22. [22]
  (22) Wang, Y.; Zhu, Y.; Zhu, S. Chin. J. Inorg. Chem. 2010, 26, 1415. [王悦辉, 朱一水, 朱朔萱. 无机化学学报, 2010, 26, 1415.]
23. [23]
  (23) Umberto, C.; Natascia, C.; Morena, N. Langmuir 1999, 15, 4454. doi: 10.1021/la981672u
24. [24]
  (24) Olavi, S.; Adam, L. J . Phys. Chem. 1984, 88, 2641. doi: 10.1021/j150656a043
25. [25]
  (25) Zhang, A.; Fang,Y. Acta Phys. Snica. 2007, 56, 171.[张爱平, 方炎.物理学报, 2007, 56, 171.]
26. [26]
  (26) Wang, D. S.; Kerker, M. Phys. Rev. B 1982, 25, 2433. doi: 10.1103/PhysRevB.25.2433
27. [27]
  (27) Glass, A. M.; Liao, P. F.; Bergman, J. G.; Olson, D. H. Opt. Lett. 1980, 5, 368. doi: 10.1364/OL.5.000368
28. [28]
  (28) Wang,Y.; Zhou, J.; Shi, S. Chin. J. Inorg. Chem. 2006, 22, 1579. [王悦辉, 周济, 石士考. 无机化学学报, 2006, 22, 1579.]
29. [29]
  (29) Gryczynski, Z.; Borejdo, J.; Calander, N.; Gryczynski, Z.; Gryczynski, I. Anal. Biochem. 2006, 356, 125. doi: 10.1016/j.ab.2006.05.007
30. [30]
  (30) Lukomska, J.; Gryczynski, I.; Malicka, J.; Makowiec, S.; Lakowicz, J. R. Biopolymers 2006, 81, 249. doi: 10.1002/bip.20407
31. [31]
  (31) Huang, T.; Murray, R. W. Langmuir 2002, 18, 7077. doi: 10.1021/la025948g
32. [32]
  (32) Förster, T. Ann. Phys. 1948, 2, 55.
33. [33]
  (33) Lakowicz, J. R. Anal. Biochem. 2001, 298, 1. doi: 10.1006/abio.2001.5377
34. [34]
  (34) Zhang, A.; Fang, Y. J. Colloid Interface Sci. 2007, 305, 270. doi: 10.1016/j.jcis.2006.09.068
1. [1]
  Lijuan Wang , Yuping Ning , Jian Li , Sha Luo , Xiongfei Luo , Ruiwen Wang . Enhancing the Advanced Nature of Natural Product Chemistry Laboratory Courses with New Research Findings: A Case Study of the Application of Berberine Hydrochloride in Photodynamic Antimicrobial Films. University Chemistry, 2024, 39(11): 241-250. doi: 10.12461/PKU.DXHX202403017
2. [2]
  Heng Chen , Longhui Nie , Kai Xu , Yiqiong Yang , Caihong Fang . 两步焙烧法制备大比表面积和结晶性增强超薄g-C₃N₄纳米片及其高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406019-. doi: 10.3866/PKU.WHXB202406019
3. [3]
  Lei Shi . Nucleophilicity and Electrophilicity of Radicals. University Chemistry, 2024, 39(11): 131-135. doi: 10.3866/PKU.DXHX202402018
4. [4]
  Qianqian Liu , Xing Du , Wanfei Li , Wei-Lin Dai , Bo Liu . Synergistic Effects of Internal Electric and Dipole Fields in SnNb₂O₆/Nitrogen-Enriched C₃N₅ S-Scheme Heterojunction for Boosting Photocatalytic Performance. Acta Physico-Chimica Sinica, 2024, 40(10): 2311016-. doi: 10.3866/PKU.WHXB202311016
5. [5]
  Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H₂ production activity of BaTiO₃ nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
6. [6]
  Liang MA , Honghua ZHANG , Weilu ZHENG , Aoqi YOU , Zhiyong OUYANG , Junjiang CAO . Construction of highly ordered ZIF-8/Au nanocomposite structure arrays and application of surface-enhanced Raman spectroscopy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1743-1754. doi: 10.11862/CJIC.20240075
7. [7]
  Meng Lin , Hanrui Chen , Congcong Xu . Preparation and Study of Photo-Enhanced Electrocatalytic Oxygen Evolution Performance of ZIF-67/Copper(I) Oxide Composite: A Recommended Comprehensive Physical Chemistry Experiment. University Chemistry, 2024, 39(4): 163-168. doi: 10.3866/PKU.DXHX202308117
8. [8]
  Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu³⁺ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
9. [9]
  Jiakun BAI , Ting XU , Lu ZHANG , Jiang PENG , Yuqiang LI , Junhui JIA . A red-emitting fluorescent probe with a large Stokes shift for selective detection of hypochlorous acid. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1095-1104. doi: 10.11862/CJIC.20240002
10. [10]
  Yang YANG , Pengcheng LI , Zhan SHU , Nengrong TU , Zonghua WANG . Plasmon-enhanced upconversion luminescence and application of molecular detection. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 877-884. doi: 10.11862/CJIC.20230440
11. [11]
  Peipei Sun , Jinyuan Zhang , Yanhua Song , Zhao Mo , Zhigang Chen , Hui Xu . 引入内建电场增强光载流子分离以促进H₂的生产. Acta Physico-Chimica Sinica, 2024, 40(11): 2311001-. doi: 10.3866/PKU.WHXB202311001
12. [12]
  Zhuomin Zhang , Hanbing Huang , Liangqiu Lin , Jingsong Liu , Gongke Li . Course Construction of Instrumental Analysis Experiment: Surface-Enhanced Raman Spectroscopy for Rapid Detection of Edible Pigments. University Chemistry, 2024, 39(2): 133-139. doi: 10.3866/PKU.DXHX202308034
13. [13]
  Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169
14. [14]
  Yongming Guo , Jie Li , Chaoyong Liu . Green Improvement and Educational Design in the Synthesis and Characterization of Silver Nanoparticles. University Chemistry, 2024, 39(3): 258-265. doi: 10.3866/PKU.DXHX202309057
15. [15]
  Qin Hou , Jiayi Hou , Aiju Shi , Xingliang Xu , Yuanhong Zhang , Yijing Li , Juying Hou , Yanfang Wang . Preparation of Cuprous Iodide Coordination Polymer and Fluorescent Detection of Nitrite: A Comprehensive Chemical Design Experiment. University Chemistry, 2024, 39(8): 221-229. doi: 10.3866/PKU.DXHX202312056
16. [16]
  Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099
17. [17]
  Zhengyu Zhou , Huiqin Yao , Youlin Wu , Teng Li , Noritatsu Tsubaki , Zhiliang Jin . Synergistic Effect of Cu-Graphdiyne/Transition Bimetallic Tungstate Formed S-Scheme Heterojunction for Enhanced Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2024, 40(10): 2312010-. doi: 10.3866/PKU.WHXB202312010
18. [18]
  Haiyuan Wang , Yiming Tang , Haoran Guo , Guohui Chen , Yajing Sun , Chao Zhao , Zhen Zhang . Comprehensive Chemistry Experimental Teaching Design Based on the Integration of Science and Education: Preparation and Catalytic Properties of Silver Nanomaterials. University Chemistry, 2024, 39(10): 219-228. doi: 10.12461/PKU.DXHX202404067
19. [19]
  Yangrui Xu , Yewei Ren , Xinlin Liu , Hongping Li , Ziyang Lu . 具有高传质和亲和表面的NH₂-UIO-66基疏水多孔液体用于增强CO₂光还原. Acta Physico-Chimica Sinica, 2024, 40(11): 2403032-. doi: 10.3866/PKU.WHXB202403032
20. [20]
  Qin Hu , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . Ni掺杂构建电子桥及激活MoS₂惰性基面增强光催化分解水产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2406024-. doi: 10.3866/PKU.WHXB202406024

Get Citation

PDF

XML

Metrics

PDF Downloads(920)
Abstract views(2404)
HTML views(31)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142