Citation: CONG Yan-Qing, LI Zhe, WANG Qi, ZHANG Yi, XU Qian, FU Fang-Xia. Enhanced Photoeletrocatalytic Activity of TiO₂ Nanotube Arrays Modified with Simple Transition Metal Oxides (Fe₂O₃, CuO, NiO)[J]. Acta Physico-Chimica Sinica, ;2012, 28(06): 1489-1496. doi: 10.3866/PKU.WHXB201203221 shu

Enhanced Photoeletrocatalytic Activity of TiO₂ Nanotube Arrays Modified with Simple Transition Metal Oxides (Fe₂O₃, CuO, NiO)

1.
College of Environmental Science and Engineering, Zhejiang ngshang University, Hangzhou 310012, P. R. China

Received Date: 9 January 2012
Available Online: 22 March 2012
Fund Project: 国家自然科学基金(20976162, 21103149, 20906079) (20976162, 21103149, 20906079) 浙江省自然科学基金(R5100266) (R5100266)浙江省科技厅重大专项(2010C13001)资助项目 (2010C13001)

Composite electrodes consisting of highly ordered, vertically oriented TiO₂ nanotube (TiO₂-NT) arrays modified with Fe₂O₃, CuO, and NiO nanoparticles were successfully fabricated by a simple electrochemical anodization and electrodeposition method. Field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), and UV-Vis diffuse reflectance spectroscopy were used to characterize the structure and optical properties of the resulting Fe₂O₃/TiO₂-NT, CuO/TiO₂-NT, and NiO/TiO₂-NT composite electrodes. The photoelectrochemical (PEC) activities of the composite electrodes were evaluated using phenol as a model pollutant. Results indicated that transition metal oxide nanoparticles were deposited on the mouth, tube wall, and base of the TiO₂-NTs. The PEC activity of the composite electrodes was over twice that of an unmodified TiO₂-NT electrode. The Fe₂O₃/TiO₂-NT electrode showed the highest absorption intensity in the visible light region. After treatment for 120 min, the phenol removal efficiency using the Fe₂O₃/TiO₂-NT anode could reach 96%, while it was only 41% for the unmodified TiO₂-NT anode. Moreover, the Fe₂O₃/TiO₂-NT electrode tended to generate intermediates of low toxicity. The higher PEC activity of the composite electrodes was attributed to the presence of hetero-nanostructures with high interfacial area comprised of TiO₂-NTs and transition metal oxide nanoparticles, which efficiently facilitated electron transfer and inhibited the recombination of photogenerated electron- hole pairs.
- TiO₂ nanotube,
- Fe₂O₃,
- CuO,
- NiO,
- Photoelectrocatalysis,
- Visible light
1. [1]
  (1) Shannon, M. A.; Bohn, P. W.; Elimelech, M.; Georgiadis, J. G.; Marinas, B. J.; Mayes, A. M. Nature 2008, 452, 301. doi: 10.1038/nature06599
2. [2]
  (2) Batzill, M. Energy Environ. Sci. 2011, 4, 3275. doi: 10.1039/c1ee01577j
3. [3]
  (3) Fujishima, A.; Honda, K. Nature 1972, 238, 37. doi: 10.1038/238037a0
4. [4]
  (4) Khan, S. U. M.; Al-Shahry, M.; Ingler, W. B. Science 2002, 297, 2243. doi: 10.1126/science.1075035
5. [5]
  (5) Yang, H. G.; Sun, C. H.; Qiao, S. Z.; Zou, J.; Liu, G.; Smith, S. C.; Cheng, H. M.; Lu, G. Q. Nature 2008, 453, 638. doi: 10.1038/nature06964
6. [6]
  (6) Chen, X. B.; Liu, L.; Yu, P. Y.; Mao, S. S. Science 2011, 331, 746. doi: 10.1126/science.1200448
7. [7]
  (7) Park, J. H.; Kim, S.; Bard, A. J. Nano Lett. 2006, 6, 24. doi: 10.1021/nl051807y
8. [8]
  (8) Ozcan, O.; Yukruk, F.; Akkaya, E. U.; Uner, D. Appl. Catal. B: Environ. 2007, 71, 291. doi: 10.1016/j.apcatb.2006.09.015
9. [9]
  (9) Zhao, W.; Sun, Y. L.; Castellano, F. N. J. Am. Chem. Soc. 2008, 130, 12566. doi: 10.1021/ja803522v
10. [10]
  (10) Shang, J.; Chai, M.; Zhu, Y. F. Environ. Sci. Technol. 2003, 37, 4494. doi: 10.1021/es0209464
11. [11]
  (11) Asahi, R.; Morikawa, T.; Ohwaki, T.; Aoki, K.; Taga, Y. Science 2001, 293, 269. doi: 10.1126/science.1061051
12. [12]
  (12) Chen, X.; Burda, C. J. Phys. Chem. B 2004, 108, 15446. doi: 10.1021/jp0469160
13. [13]
  (13) Parida, K. M.; Sahu, N.; Tripathi, A. K.; Kamble, V. S. Environ. Sci. Technol. 2010, 44, 4155. doi: 10.1021/es903774j
14. [14]
  (14) Sangpour, P.; Hashemi, F.; Moshfegh, A. Z. J. Phys. Chem. C 2010, 114, 13955. doi: 10.1021/jp910454r
15. [15]
  (15) Zielinska-Jurek, A.; Kowalska, E.; Sobczak, J. W.; Lisowski, W.; Ohtani, B.; Zaleska, A. Appl. Catal. B: Environ. 2011, 101, 504. doi: 10.1016/j.apcatb.2010.10.022
16. [16]
  (16) Mogyorosi, K.; Kmetyko, A.; Czirbus, N.; Vereb, G.; Sipos, P.; Dombi, A. React. Kinet. Catal. Lett. 2009, 98, 215. doi: 10.1007/s11144-009-0052-y
17. [17]
  (17) Martin, C.; Martin, I.; Rives, V.; Palmisano, L.; Schiavello, M. J. Catal. 1992, 134, 434. doi: 10.1016/0021-9517(92)90333-D
18. [18]
  (18) Hou, Y.; Li, X. Y.; Zou, X. J.; Quan, X.; Chen, G. H. Environ. Sci. Technol. 2009, 43, 858. doi: 10.1021/es802420u
19. [19]
  (19) Dlamini, L. N.; Krause, R. W.; Kulkarni, G. U.; Durbach, S. H. Mater. Chem. Phys. 2011, 129, 406. doi: 10.1016/j.matchemphys.2011.04.033
20. [20]
  (20) Wang, N.; Li, X. Y.; Wang, Y. X.; Hou, Y.; Zou, X. J.; Chen, G. H. Mater. Lett. 2008, 62, 3691. doi: 10.1016/j.matlet.2008.04.052
21. [21]
  (21) Yasomanee, J. P.; Bandara, J. Sol. Energy Mater. Sol. Cells 2008, 92, 348. doi: 10.1016/j.solmat.2007.09.016
22. [22]
  (22) Chen, C. J.; Liao, C. H.; Hsu, K. C.; Wu, Y. T.; Wu, J. C. S. Catal. Commun. 2011, 12, 1307. doi: 10.1016/j.catcom.2011.05.009
23. [23]
  (23) Zhang, Y. G.; Ma, J. L.; Yu, Y. Environ. Sci. Technol. 2007, 41, 6264. doi: 10.1021/es070345i
24. [24]
  (24) Tahar, N. B.; Savall, A. J. J. Electrochem. Soc. 1998, 145, 3427. doi: 10.1149/1.1838822
25. [25]
  (25) Bard, A. J.; Faulker, L. R. Electrochemical Methods: Fundamentals and Applications, 2 nd Ed.; JohnWiley & Sons: New York, 2001; p 386.
26. [26]
  (26) Xu, Y.; Schoonen, M. A. A. Am. Miner. 2000, 85, 543.
1. [1]
  Jun Dong , Senyuan Tan , Sunbin Yang , Yalong Jiang , Ruxing Wang , Jian Ao , Zilun Chen , Chaohai Zhang , Qinyou An , Xiaoxing Zhang . Spatial confinement of free-standing graphene sponge enables excellent stability of conversion-type Fe₂O₃ anode for sodium storage. Chinese Chemical Letters, 2025, 36(3): 110010-. doi: 10.1016/j.cclet.2024.110010
2. [2]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
3. [3]
  Qin Li , Huihui Zhang , Huajun Gu , Yuanyuan Cui , Ruihua Gao , Wei-Lin Dai . In situ Growth of Cd_0.5Zn_0.5S Nanorods on Ti₃C₂ MXene Nanosheet for Efficient Visible-Light-Driven Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2025, 41(4): 100031-. doi: 10.3866/PKU.WHXB202402016
4. [4]
  Xinzhe HUANG , Lihui XU , Yue YANG , Liming WANG , Zhangyong LIU , Zhongjian WANG . Preparation and visible light responsive photocatalytic properties of BiSbO₄/BiOBr. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 284-292. doi: 10.11862/CJIC.20240212
5. [5]
  Xiufang Wang , Donglin Zhao , Kehua Zhang , Xiaojie Song . “Preparation of Carbon Nanotube/SnS₂ Photoanode Materials”: A Comprehensive University Chemistry Experiment. University Chemistry, 2024, 39(4): 157-162. doi: 10.3866/PKU.DXHX202308025
6. [6]
  Cailiang Yue , Nan Sun , Yixing Qiu , Linlin Zhu , Zhiling Du , Fuqiang Liu . A direct Z-scheme 0D α-Fe₂O₃/TiO₂ heterojunction for enhanced photo-Fenton activity with low H₂O₂ consumption. Chinese Chemical Letters, 2024, 35(12): 109698-. doi: 10.1016/j.cclet.2024.109698
7. [7]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 736-750. doi: 10.11862/CJIC.20230346
8. [8]
  Ying Chen , Xingyuan Xia , Lei Tian , Mengying Yin , Ling-Ling Zheng , Qian Fu , Daishe Wu , Jian-Ping Zou . Constructing built-in electric field via CuO/NiO heterojunction for electrocatalytic reduction of nitrate at low concentrations to ammonia. Chinese Chemical Letters, 2024, 35(12): 109789-. doi: 10.1016/j.cclet.2024.109789
9. [9]
  Haojie Duan , Hejingying Niu , Lina Gan , Xiaodi Duan , Shuo Shi , Li Li . Reinterpret the heterogeneous reaction of α-Fe₂O₃ and NO₂ with 2D-COS: The role of SDS, UV and SO₂. Chinese Chemical Letters, 2024, 35(6): 109038-. doi: 10.1016/j.cclet.2023.109038
10. [10]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
11. [11]
  Yurong Tang , Yunren Shi , Yi Xu , Bo Qin , Yanqin Xu , Yunfei Cai . Innovative Experiment and Course Transformation Practice of Visible-Light-Mediated Photocatalytic Synthesis of Isoquinolinone. University Chemistry, 2024, 39(5): 296-306. doi: 10.3866/PKU.DXHX202311087
12. [12]
  Zhuoyan Lv , Yangming Ding , Leilei Kang , Lin Li , Xiao Yan Liu , Aiqin Wang , Tao Zhang . Light-Enhanced Direct Epoxidation of Propylene by Molecular Oxygen over CuO_x/TiO₂ Catalyst. Acta Physico-Chimica Sinica, 2025, 41(4): 100038-. doi: 10.3866/PKU.WHXB202408015
13. [13]
  Zhen Yao , Bing Lin , Youping Tian , Tao Li , Wenhui Zhang , Xiongwei Liu , Wude Yang . Visible-Light-Mediated One-Pot Synthesis of Secondary Amines and Mechanistic Exploration. University Chemistry, 2024, 39(5): 201-208. doi: 10.3866/PKU.DXHX202311033
14. [14]
  Liyong DU , Yi LIU , Guoli YANG . Preparation and triethylamine sensing performance of ZnSnO₃/NiO heterostructur. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 729-740. doi: 10.11862/CJIC.20240404
15. [15]
  Zhijie Zhang , Xun Li , Huiling Tang , Junhao Wu , Chunxia Yao , Kui Li . Cs₂CuBr₄ perovskite quantum dots confined in mesoporous CuO framework as a p-n type S-scheme heterojunction for efficient CO₂ photoconversion. Chinese Chemical Letters, 2024, 35(11): 109700-. doi: 10.1016/j.cclet.2024.109700
16. [16]
  Jie Li , Huida Qian , Deyang Pan , Wenjing Wang , Daliang Zhu , Zhongxue Fang . Efficient Synthesis of Anethaldehyde Induced by Visible Light. University Chemistry, 2024, 39(4): 343-350. doi: 10.3866/PKU.DXHX202310076
17. [17]
  Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V₂O₅/TiO₂ catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210
18. [18]
  Fei ZHOU , Xiaolin JIA . Co₃O₄/TiO₂ composite photocatalyst: Preparation and synergistic degradation performance of toluene. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2232-2240. doi: 10.11862/CJIC.20240236
19. [19]
  Runhua Chen , Qiong Wu , Jingchen Luo , Xiaolong Zu , Shan Zhu , Yongfu Sun . 缺陷态二维超薄材料用于光/电催化CO₂还原的基础与展望. Acta Physico-Chimica Sinica, 2025, 41(3): 2308052-. doi: 10.3866/PKU.WHXB202308052
20. [20]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469

Get Citation

PDF

XML

Metrics

PDF Downloads(1253)
Abstract views(3552)
HTML views(103)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Enhanced Photoeletrocatalytic Activity of TiO2 Nanotube Arrays Modified with Simple Transition Metal Oxides (Fe2O3, CuO, NiO)

Metrics

通讯作者: 陈斌, bchen63@163.com

Enhanced Photoeletrocatalytic Activity of TiO₂ Nanotube Arrays Modified with Simple Transition Metal Oxides (Fe₂O₃, CuO, NiO)