Citation: HU Wen-Liang, XU Gang, MA Jian-Wei, XIONG Bin, SHI Ji-Fu. Optical and Phase Transition Properties of Ti_xV_1-xO₂ Thin Films[J]. Acta Physico-Chimica Sinica, ;2012, 28(06): 1533-1538. doi: 10.3866/PKU.WHXB201203191 shu

Optical and Phase Transition Properties of Ti_xV_1-xO₂ Thin Films

HU Wen-Liang ^1,2,3 ,
XU Gang ^1,2, ,
MA Jian-Wei ^1,2,4 ,
XIONG Bin ^1,2,3 ,
SHI Ji-Fu ^1,2

1.
1. Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, P. R. China;
2. Key Laboratory of Renewable Energy and Gas Hydrate, Chinese Academy of Sciences, Guangzhou 510640, P. R. China;
3. Graduate University of Chinese Academy of Sciences, Beijing 100049, P. R. China;
4. Civil Engineering Institute, Northeast Petroleum University, Daqing 163318, Heilongjiang Province, P. R. China

Received Date: 13 December 2011
Available Online: 19 March 2012
Fund Project: 国家自然科学基金(51102235) (51102235) 广东省产学研结合计划(2010B090400109) (2010B090400109)广东省中国科学院全面战略合作计划(2011B090300044)资助项目 (2011B090300044)

Ti_xV_1-xO₂ (0≤x≤1) thin films with different molar ratios of V/Ti were prepared on c-plane sapphire (0001) substrates by radio frequency magnetron sputtering. The microstructure and optical properties of the thin films were determined by X-ray diffraction (XRD), Raman spectroscopy, and UV-visible-near infrared (UV-Vis-NIR) spectroscopy. The width of the optical band gap was calculated and the integrated solar transmittance of the films was characterized. As the content of titanium was increased, infrared regulation and thermal hysteresis were gradually reduced until they disappeared. The results show that the band gap of the thin films broadens as the content of titanium increases, causing the optical absorption edge to exhibit a blue shift. Conversely, the band gap narrows as the proportion of vanadium is increased, which causes a red shift of the optical absorption edge.
- VO₂ thin film,
- TiO₂ thin film,
- Magnetron sputtering,
- Optical property,
- Phase transition property
1. [1]
  (1) Morin, F. J. Phys. Rev. Lett. 1959, 3, 34. doi: 10.1103/PhysRevLett.3.34
2. [2]
  (2) Cavalleri, A.; Tóth, Cs.; Siders, C. W.; Squier, J. A.; Ráksi, F.; Forget, P.; Kieffer, J. C. Phys. Rev. Lett. 2001, 87, 237401. doi: 10.1103/PhysRevLett.87.237401
3. [3]
  (3) Béteille, F.; Livage, J. J. Sol-Gel. Sci. Technol. 1998, 13, 915. doi: 10.1023/A:1008679408509
4. [4]
  (4) He, Y. F.; Xu, G.; Zhu, J.; Cheng, D. M.; Wang, C. P. Micronanoelectronic Technology. 2008, 45, 387. [何云富, 徐刚, 朱俊, 陈德明, 王春平.微纳电子技术, 2008, 45, 387.]
5. [5]
  (5) Xu, G.; Jin, P.; Tazawa, M.; Yoshimura, K. Sol. Energy Mater. Sol. Cells. 2004, 83, 29. doi: 10.1016/j.solmat.2004.02.014
6. [6]
  (6) Christmann, T.; Felde, B.; Niessner, W.; Schalch, D.; Scharmann, A. Thin Solid Films 1996, 287, 134. doi: 10.1016/S0040-6090(96)08770-6
7. [7]
  (7) Du, J.; Gao, Y. F.; Luo, H. G.; Zhang, Z. T.; Kang, L. T.; Chen, Z. Sol. Energy Mater. Sol. Cells 2011, 95, 1604. doi: 10.1016/j.solmat.2011.01.009
8. [8]
  (8) Burkhardt, W.; Christmann, T.; Franke, S.; Kriegseis, W.; Meister, D.; Meyer, B. K.; Niessner, W.; Schach, D.; Scharmann, A. Thin Solid Films 2002, 402, 226. doi: 10.1016/S0040-6090(01)01603-0
9. [9]
  (9) Soltani, M.; Chaker, M.; Haddad, E.; Kruzelecky, R. V.; Mar t, J. Appl. Phys. Lett. 2004, 85, 1958. doi: 10.1063/1.1788883
10. [10]
  (10) Du, J.; Gao, Y. F.; Luo, H. J.; Kang, L. T.; Zhang, Z. T.; Chen, Z.; Cao, C. X. Sol. Energy Mater. Sol. Cells. 2011, 95, 469. doi: 10.1016/j.solmat.2010.08.035
11. [11]
  (11) Kakiuchida, H.; Jin, P.; Tazawa, M. Thin Solid Films 2008, 516, 4563. doi: 10.1016/j.tsf.2007.05.096
12. [12]
  (12) Zhao, G. L.; Han, G. R.; Takahashi, M.; Yoko, T. Thin Solid Films 2002, 410, 14. doi: 10.1016/S0040-6090(02)00252-3
13. [13]
  (13) Fujishima, A.; Zhang, X. T.; Tryk, D. A. Surf. Sci. Rep. 2008, 63, 515. doi: 10.1016/j.surfrep.2008.10.001
14. [14]
  (14) Zhang, X. Y.; Chao, M. J.; Liang, E. J.; Hu, F.; Yuan, F. Journal of Inorganic Materials. 2009, 24, 34. [张晓勇, 晁明举, 梁二军, 胡帆, 袁斌. 无机材料学报, 2009, 24, 34.] doi: 10.3724/SP.J.1077.2009.00034
15. [15]
  (15) Zhang, X. R.; Lin, Y. H.; Zhang, J. F.; He, D. Q.; Wang, D. J. Acta Phys. -Chim. Sin. 2010, 26, 2733. [张晓茹, 林艳红, 张健夫, 何冬青, 王德军. 物理化学学报, 2010, 26, 2733.]
16. [16]
  (16) Lazarovits, B.; Kim, K.; Haule, K.; Kotliar, G. Phys. Rev. B. 2010, 81, 115117. doi: 10.1103/PhysRevB.81.115117
17. [17]
  (17) Béteille, F.; Morineau, R.; Livage, J.; Nagano, M. Mater. Res. Bull. 1997, 32, 1109. doi: 10.1016/S0025-5408(97)00084-6
18. [18]
  (18) Masih, D.; Yoshitake, H.; Izumi, Y. Appl. Catal. A-gen. 2007, 325, 276. doi: 10.1016/j.apcata.2007.02.037
19. [19]
  (19) Lim, J. W.; Yoo, S. J.; Park, S. H.; Yun, S. U.; Sung, Y. E. Sol. Energy Mater. Sol. Cells 2009, 93, 2069. doi: 10.1016/j.solmat.2009.03.008
20. [20]
  (20) Woodley, S. M. Chem. Phys. Lett. 2008, 453, 167. doi: 10.1016/j.cplett.2008.01.018
21. [21]
  (21) Guinneton, F.; Valmalette, J. C.; Gavarri, J. R. Optical Materials 2000, 15, 111. doi: 10.1016/S0925-3467(00)00023-9
22. [22]
  (22) Liang, J. R.; Hu, M.; Wang, X. D.; Li, G. K.; Ji, A.; Yang, F. H.; Liu, J.; Wu, N. J.; Chen, H. D. Acta Phys. -Chim. Sin. 2009, 25, 1523. [梁继然, 胡明, 王晓东, 李贵柯, 季安, 杨富华, 刘剑, 吴南健, 陈弘达. 物理化学学报, 2009, 25, 1523.]
23. [23]
  (23) Gurvitch, M.; Luryi, S.; Polyakov, A.; Shabalov, A.;Dudley, M.; Wang, G.; Ge, S.; Yakovlev, V. J. Appl. Phys. 2007, 102, 033504. doi: 10.1063/1.2764245
24. [24]
  (24) Oh, C.; Yoon, S.; Kim, S.; Han, J.; Chung, H.; Jeong, H. J. J. Pharmaceut. Biomed. 2010, 53, 762. doi: 10.1016/j.jpba.2010.05.008
25. [25]
  (25) Xiao, P.; Zheng, S. B.; You, J. L.; Jiang, G. C.; Chen, H.; Zeng, H. Spectroscopy and Spectral Analysis. 2007, 27, 936. [肖萍, 郑少波, 尤静林, 蒋国昌, 陈辉, 曾昊. 光谱学与光谱分析, 2007, 27, 936.]
26. [26]
  (26) Pan, X. Y.; Ma, X. M. Materials Science and Engineering. 2001, 19, 138. [潘晓燕, 马学鸣. 材料科学与工程, 2001, 19, 138.]
27. [27]
  (27) Sudakar, C.; Kharel, P.; Lawes, G.; Suryanarayanan, R.; Naik, R.; Naik, V. M. J. Phys.: Condens. Matter. 2007, 19, 026212. doi: 10.1088/0953-8984/19/2/026212
28. [28]
  (28) Ma, J. W.; Xu, G.; Miao, L.; Tazawa, M.; Tanemura, S. Jpn. J. Appl. Phys. 2011, 50, 020215. doi: 10.1143/JJAP.50.020215
29. [29]
  (29) Ding, S.; Liu, Y. L.; Siu, G. G. Acta Physica Sinica. 2005, 54, 4416. [丁硕, 刘玉龙, 萧季驹. 物理学报, 2005, 54, 4416.]
30. [30]
  (30) Xu, G.; Jin, P.; Tazawa, M.; Yoshimura, K. Jpn. J. Appl. Phys. 2004, 43, 186. doi: 10.1143/JJAP.43.186
31. [31]
  (31) Kang, L. T.; Gao, Y. F.; Luo, H. J.; Zhang, C.; Du, J.; Zhang, Z. T. ACS Appl. Mater. Interfaces 2011, 3, 135. doi: 10.1021/am1011172
32. [32]
  (32) Tauc, J.; Gri rivici, R.; Vancu, A. Phys. Stat. Sol. 1966, 15, 627. doi: 10.1002/pssb.19660150224
33. [33]
  (33) Tauc, J.; Menth, A. J. Non-Cryst. Solids. 1972, 8-10, 569.
34. [34]
  (34) Tauc, J. Amorphous and Liquid Semiconductors, 1st ed.; Plenum Press: New York, 1974; 171. doi: --- Either first page or author must be supplied.
35. [35]
  (35) Saffarini, G.; Saiter, J. M.; Schmitt, H. Optical Materials 2007, 29, 1143. doi: 10.1016/j.optmat.2006.05.003
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Optical and Phase Transition Properties of TixV1-xO2 Thin Films

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Optical and Phase Transition Properties of Ti_xV_1-xO₂ Thin Films