Citation: CHANG Meng-Lei, LI Xin-Jun. Fabrication of Nanosheet/Nestlike Nanoarray Hierarchical TiO₂ Film for Dye-Sensitized Solar Cell[J]. Acta Physico-Chimica Sinica, ;2012, 28(06): 1368-1372. doi: 10.3866/PKU.WHXB201203161 shu

Fabrication of Nanosheet/Nestlike Nanoarray Hierarchical TiO₂ Film for Dye-Sensitized Solar Cell

CHANG Meng-Lei ^1,2 ,
LI Xin-Jun ^1,

1.
1. Key Laboratory of Renewable Energy and Gas Hydrate, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, P. R. China;
2. Graduate University of Chinese Academy of Sciences, Beijing 100049, P. R. China

Received Date: 17 February 2012
Available Online: 16 March 2012
Fund Project: 国家自然科学基金(51172233)与国家重点基础研究发展计划项目(973) (2009CB220002)资助 (51172233)与国家重点基础研究发展计划项目(973) (2009CB220002)

A hierarchical configuration of TiO₂ nanoarray film, comprising a nestlike TiO₂ nanoarray layer integrated with a nanosheet network overlayer, was constructed. The hierarchical TiO₂ film was obtained by the post-hydrothermal treatment with NaOH solution on hydrothermally synthesized TiO₂-derived nanostructured arrays grown on fluorine-doped tin oxide substrate (FTO). The TiO₂ films were characterized by field-emission scanning electron microscope (FE-SEM), X-ray diffraction (XRD), ultraviolet-visible (UV-Vis) diffuse reflectance spectroscopy, and absorbance spectroscopy. FE-SEM shows that the hierarchical TiO₂ film with a thickness of 1.5 μm is composed of a nanosheet overlayer (~0.2 μm height) and the nestlike nanoarray layer (~1.3 μm height). XRD patterns display that the TiO₂ films have pure anatase phase structure. UV-Vis spectra reveal enhanced light scattering and dye adsorption ability of the hierarchical TiO₂ film. For the dye-sensitized solar cell (DSSC) based on the nanosheet/nestlike nanoarray hierarchical TiO₂ film, a short-circuit current (J_sc) of 7.79 mA·cm^-2, open-circuit voltage (V_oc) of 0.80 V, fill factor (FF) of 0.40, and photoelectric conversion efficiency (η) of 2.48% are achieved. Within the dye-sensitized solar cell, the photoelectric conversion efficiency of the hierarchical TiO₂ film was nearly ten times higher than that of nanostructured array film.
- TiO₂,
- Nanosheet/nestlike nanoarray,
- Hydrothermal synthesis,
- Dye-sensitized solar cell,
- Photoelectric conversion
1. [1]
  (1) Oregan, B.; Grätzel, M. Nature 1991, 353, 737. doi: 10.1038/353737a0
2. [2]
  (2) Yu, J. G.; Fan, J. J.; Cheng, B. J. Power Sources 2011, 196, 7891. doi: 10.1016/j.jpowsour.2011.05.014
3. [3]
  (3) Santa-Nokki, H.; Kallioinen, J.; Kololuoma, T.; Tuboltsev, V.; Korppi-Tommola, J. J. Photoch. Photobiol. A 2006, 182, 187. doi: 10.1016/j.jphotochem.2006.02.011
4. [4]
  (4) Wang, W. L.; Lin, H.; Zhang, L. Z.; Li, X.; Cui, B.; Li, J. B. Acta Phys. -Chim. Sin. 2010, 26, 1249. [汪文立, 林红, 张罗正, 李鑫, 崔柏, 李建保. 物理化学学报, 2010, 26, 1249.]
5. [5]
  (5) Wang, H. E.; Zheng, L. X.; Liu, C. P.; Liu, Y. K.; Luan, C. Y.; Cheng, H.; Li, Y. Y.; Martinu, L.; Zapien, J. A.; Bello, I. J. Phys. Chem. C 2011, 115, 10419. doi: 10.1021/jp2011588
6. [6]
  (6) Du Pasquier, A.; Chen, H. H.; Lu, Y. C. Appl. Phys. Lett. 2006, 89.
7. [7]
  (7) Dong, X.; Tao, J.; Li, Y. Y.; Wang, T.; Zhu, H. Acta Phys. -Chim. Sin. 2009, 25, 1874. [董祥, 陶杰, 李莹滢, 汪涛, 朱宏. 物理化学学报, 2009, 25, 1874.]
8. [8]
  (8) Zhao, L.; Yu, J. G.; Fan, J. J.; Zhai, P. C.; Wang, S. M. Electrochem. Commun. 2009, 11, 2052. doi: 10.1016/j.elecom.2009.08.050
9. [9]
  (9) Mor, G. K.; Shankar, K.; Paulose, M.; Varghese, O. K.; Grimes, C. A. Nano Letters 2006, 6, 215. doi: 10.1021/nl052099j
10. [10]
  (10) Sauvage, F.; Di Fonzo, F.; Bassi, A. L.; Casari, C. S.; Russo, V.; Divitini, G.; Ducati, C.; Bottani, C. E.; Comte, P.; Gräetzel, M. Nano Letters 2010, 10, 2562. doi: 10.1021/nl101198b
11. [11]
  (11) Zeng, Q. H.; Wu, L. Z.; Zhang, Y.; Qi, B.; Zhi, J. F. Scripta Mater 2010, 62, 810. doi: 10.1016/j.scriptamat.2010.01.054
12. [12]
  (12) Li, H. H.; Chen, R. F.; Ma, Z.; Zhang, S. L.; An, Z. F.; Huang, W. Acta Phys. -Chim. Sin. 2011, 27, 1017. [李欢欢, 陈润锋, 马琮, 张胜兰, 安众福, 黄维. 物理化学学报, 2011, 27, 1017.]
13. [13]
  (13) Zhang, Q. F.; Chou, T. R.; Russo, B.; Jenekhe, S. A.; Cao, G. Z., Angew. Chem. Int. Edit. 2008, 47, 2402. doi: 10.1002/anie.200704919
14. [14]
  (14) Yu, H.; Tian, B. Z.; Zhang, J. L. Chem. Eur. J. 2011, 17, 5499. doi: 10.1002/chem.201003437
15. [15]
  (15) Koo, H. J.; Kim, Y. J.; Lee, Y. H.; Lee, W. I.; Kim, K.; Park, N. G. Advanced Materials 2008, 20, 195. doi: 10.1002/adma.200700840
16. [16]
  (16) Liu, R. H.; Zhang, S.; Xia, X.Y.; Yun, D. Q.; Bian, Z. Q.; Zhao, Y. L. Acta Phys. -Chim. Sin. 2011, 27, 1701. [刘润花, 张森, 夏新元, 云大钦, 卞祖强, 赵永亮. 物理化学学报, 2011, 27, 1701.]
17. [17]
  (17) Kang, S. H.; Kim, J. Y.; Kim, H. S.; Koh, H. D.; Lee, J. S.; Sung, Y. E. J. Photochem. Photobiol. A 2008, 200, 294. doi: 10.1016/j.jphotochem.2008.08.010
18. [18]
  (18) Durr, M.; Bamedi, A.; Yasuda, A.; Nelles, G. Appl. Phys. Lett. 2004, 84, 3397. doi: 10.1063/1.1723685
19. [19]
  (19) Wang, Z. S.; Kawauchi, H.; Kashima, T.; Arakawa, H. Coordin. Chem. Rev. 2004, 248, 1381. doi: 10.1016/j.ccr.2004.03.006
20. [20]
  (20) Qiu, Y. C.; Chen, W.; Yang, S. H. Angew. Chem. Int. Ed. 2010, 49, 3675. doi: 10.1002/anie.200906933
21. [21]
  (21) Nazeeruddin, M. K.; Kay, A.; Rodicio, I.; Humphrybaker, R.; Muller, E.; Liska, P.; Vlachopoulos, N.; Grätzel, M. J. Am. Chem. Soc. 1993, 115, 6382. doi: 10.1021/ja00067a063
22. [22]
  (22) Rao, F.; Song, Z. T.; ng, Y. F.; Wu, L. C.; Feng, S. L.; Chen, B. Nanotechnology 2008, 19, 445706. doi: 10.1088/0957-4484/19/44/445706
1. [1]
  Xiaoyao YIN , Wenhao ZHU , Puyao SHI , Zongsheng LI , Yichao WANG , Nengmin ZHU , Yang WANG , Weihai SUN . Fabrication of all-inorganic CsPbBr₃ perovskite solar cells with SnCl₂ interface modification. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 469-479. doi: 10.11862/CJIC.20240309
2. [2]
  Han ZHANG , Jianfeng SUN , Jinsheng LIANG . Hydrothermal synthesis and luminescent properties of broadband near-infrared Na₃CrF₆ phosphor. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 349-356. doi: 10.11862/CJIC.20240098
3. [3]
  Hongye Bai , Lihao Yu , Jinfu Xu , Xuliang Pang , Yajie Bai , Jianguo Cui , Weiqiang Fan . Controllable Decoration of Ni-MOF on TiO2: Understanding the Role of Coordination State on Photoelectrochemical Performance. Chinese Journal of Structural Chemistry, 2023, 42(10): 100096-100096. doi: 10.1016/j.cjsc.2023.100096
4. [4]
  Pengyu Dong , Yue Jiang , Zhengchi Yang , Licheng Liu , Gu Li , Xinyang Wen , Zhen Wang , Xinbo Shi , Guofu Zhou , Jun-Ming Liu , Jinwei Gao . NbSe₂纳米片优化钙钛矿太阳能电池的埋底界面. Acta Physico-Chimica Sinica, 2025, 41(3): 2407025-. doi: 10.3866/PKU.WHXB202407025
5. [5]
  Zhiqiang Wang , Yajie Gao , Tianjun Wang , Wei Chen , Zefeng Ren , Xueming Yang , Chuanyao Zhou . Photocatalyzed oxidation of water on oxygen pretreated rutile TiO₂(110). Chinese Chemical Letters, 2025, 36(4): 110602-. doi: 10.1016/j.cclet.2024.110602
6. [6]
  Jiatong Li , Linlin Zhang , Peng Huang , Chengjun Ge . Carbon bridge effects regulate TiO₂–acrylate fluoroboron coatings for efficient marine antifouling. Chinese Chemical Letters, 2025, 36(2): 109970-. doi: 10.1016/j.cclet.2024.109970
7. [7]
  Cailiang Yue , Nan Sun , Yixing Qiu , Linlin Zhu , Zhiling Du , Fuqiang Liu . A direct Z-scheme 0D α-Fe₂O₃/TiO₂ heterojunction for enhanced photo-Fenton activity with low H₂O₂ consumption. Chinese Chemical Letters, 2024, 35(12): 109698-. doi: 10.1016/j.cclet.2024.109698
8. [8]
  Xinyuan Shi , Chenyangjiang , Changyu Zhai , Xuemei Lu , Jia Li , Zhu Mao . Preparation and Photoelectric Performance Characterization of Perovskite CsPbBr₃ Thin Films. University Chemistry, 2024, 39(6): 383-389. doi: 10.3866/PKU.DXHX202312019
9. [9]
  Maosen Xu , Pengfei Zhu , Qinghong Cai , Meichun Bu , Chenghua Zhang , Hong Wu , Youzhou He , Min Fu , Siqi Li , Xingyan Liu . In-situ fabrication of TiO₂/NH₂−MIL-125(Ti) via MOF-driven strategy to promote efficient interfacial effects for enhancing photocatalytic NO removal activity. Chinese Chemical Letters, 2024, 35(10): 109524-. doi: 10.1016/j.cclet.2024.109524
10. [10]
  Kun Rong , Cuilian Wen , Jiansen Wen , Xiong Li , Qiugang Liao , Siqing Yan , Chao Xu , Xiaoliang Zhang , Baisheng Sa , Zhimei Sun . 层状MoS₂/Ti₃C₂T_x异质结光热转换材料用于太阳能驱动水蒸发. Acta Physico-Chimica Sinica, 2025, 41(6): 100053-. doi: 10.1016/j.actphy.2025.100053
11. [11]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
12. [12]
  Zeyuan WANG , Songzhi ZHENG , Hao LI , Jingbo WENG , Wei WANG , Yang WANG , Weihai SUN . Effect of I₂ interface modification engineering on the performance of all-inorganic CsPbBr₃ perovskite solar cells. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1290-1300. doi: 10.11862/CJIC.20240021
13. [13]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-. doi: 10.3866/PKU.WHXB202405016
14. [14]
  Yipeng Zhou , Chenxin Ran , Zhongbin Wu . Metacognitive Enhancement in Diversifying Ideological and Political Education within Graduate Course: A Case Study on “Solar Cell Performance Enhancement Technology”. University Chemistry, 2024, 39(6): 151-159. doi: 10.3866/PKU.DXHX202312096
15. [15]
  Guoqiang Chen , Zixuan Zheng , Wei Zhong , Guohong Wang , Xinhe Wu . 熔融中间体运输导向合成富氨基g-C₃N₄纳米片用于高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406021-. doi: 10.3866/PKU.WHXB202406021
16. [16]
  Zhengzheng LIU , Pengyun ZHANG , Chengri WANG , Shengli HUANG , Guoyu YANG . Synthesis, structure, and electrochemical properties of a sandwich-type {Co₆}-cluster-added germanotungstate. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1173-1179. doi: 10.11862/CJIC.20240039
17. [17]
  Juan CHEN , Guoyu YANG . A porous-layered aluminoborate built by mixed oxoboron clusters and AlO₄ tetrahedra. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 193-200. doi: 10.11862/CJIC.20240341
18. [18]
  Yixuan Gao , Lingxing Zan , Wenlin Zhang , Qingbo Wei . Comprehensive Innovation Experiment: Preparation and Characterization of Carbon-based Perovskite Solar Cells. University Chemistry, 2024, 39(4): 178-183. doi: 10.3866/PKU.DXHX202311091
19. [19]
  Fanxin Kong , Hongzhi Wang , Huimei Duan . Inhibition effect of sulfation on Pt/TiO2 catalysts in methane combustion. Chinese Journal of Structural Chemistry, 2024, 43(5): 100287-100287. doi: 10.1016/j.cjsc.2024.100287
20. [20]
  Jizhou Liu , Chenbin Ai , Chenrui Hu , Bei Cheng , Jianjun Zhang . 六氯锡酸铵促进钙钛矿太阳能电池界面电子转移及其飞秒瞬态吸收光谱研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2402006-. doi: 10.3866/PKU.WHXB202402006

Get Citation

PDF

XML

Metrics

PDF Downloads(1427)
Abstract views(3240)
HTML views(9)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Fabrication of Nanosheet/Nestlike Nanoarray Hierarchical TiO2 Film for Dye-Sensitized Solar Cell

Metrics

通讯作者: 陈斌, bchen63@163.com

Fabrication of Nanosheet/Nestlike Nanoarray Hierarchical TiO₂ Film for Dye-Sensitized Solar Cell