Citation: CHEN Jing-Wei, REN Quan, WANG Xin-Qiang, YANG Xu-Dong, LI Ting-Bin, YANG Hong-Liang, ZHU Lu-Yi, ZHANG Jing-Nan, LI Guo-Chao. Third-Order Nonlinear Optical Properties of 1,3-Dithiole-2-thione- 4,5-dithiolate Compounds at Different Wavelengths[J]. Acta Physico-Chimica Sinica, ;2012, 28(04): 942-948. doi: 10.3866/PKU.WHXB201202201 shu

Third-Order Nonlinear Optical Properties of 1,3-Dithiole-2-thione- 4,5-dithiolate Compounds at Different Wavelengths

1.
1. Department of Optics, Shandong University, Jinan 250100, P. R. China;
2. State Key Laboratory of Crystal Materials, Shandong University, Jinan, 250100, P. R. China;
3. Department of Materials and Chemical Engineering, Taishan University, Tai'an 271021, Shandong Province, P. R. China

Received Date: 9 December 2011
Available Online: 20 February 2012
Fund Project: 国家自然科学基金(60778037, 50772059, 11004123) (60778037, 50772059, 11004123) 高等学校全国优秀博士学位论文专项资金(200539) (200539) 山东省自然科学基金(ZR2009GQ007) (ZR2009GQ007) 国家博士后科研基金(20100470040) (20100470040)山东省中青年科学家奖励基金(BS2011CL025)资助项目 (BS2011CL025)

Two novel 1,3-dithiole-2-thione-4,5-dithiolate compounds, benzyltriethylamine bis(2-thioxo-1,3- dithiole-4,5-dithiolato) aurate(III) (BTEAADT) and benzyltriethylamine bis(2-thioxo-1,3-dithiole-4,5- dithiolato) nickel(III) (BTEANDT), were prepared and their optical nonlinearities in acetonitrile solutions at 532 and 1064 nm were investigated using the Z-scan technique with picosecond laser pulses. The Z-scan curves revealed that BTEAADT exhibited mainly reverse saturable absorption at 532 nm, negligible nonlinear absorption at 1064 nm, and a self-defocusing effect at both wavelengths, which meant that the third-order nonlinear refractive index was negative. BTEANDT exhibited saturable absorption at 1064 nm, negligible nonlinear absorption at 532 nm, and a self-focusing effect at both wavelengths, which meant that the third-order nonlinear refractive index was positive. The reason for these different phenomena was analyzed. The third-order nonlinear refractive index, the third-order nonlinear absorption coefficient, the third-order nonlinear susceptibility, and the hyperpolarizability were obtained at 532 and 1064 nm. The nonlinear refractive indices were -1.685×10^-18 m²·W^-1 at 532 nm and -1.459×10^-18 m²·W^-1 at 1064 nm for BTEAADT and 1.452×10^-18 m²·W^-1 at 532 nm and 7.311×10^-18 m²·W^-1 at 1064 nm for BETANDT. The magnitudes of the third-order nonlinear absorption coefficient, the third-order nonlinear susceptibility, and the hyperpolarizability were 10^-11 m·W^-1, 10^-13 esu, and 10^-31 esu, respectively. All these results suggest that these materials are promising candidates for application in the nonlinear optical area.
- Organometallic coordination compound,
- Z-scan technique,
- Nonlinear optical property,
- Nonlinear optical materials,
- All-optical switching
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