Citation: CHE Qian, ZHANG Fang, ZHANG Xiao-Gang, LU Xiang-Jun, DING Bing, ZHU Jia-Jia. Preparation of Ordered Mesoporous Carbon/NiCo₂O₄ Electrode and Its Electrochemical Capacitive Behavior[J]. Acta Physico-Chimica Sinica, ;2012, 28(04): 837-842. doi: 10.3866/PKU.WHXB201202074 shu

Preparation of Ordered Mesoporous Carbon/NiCo₂O₄ Electrode and Its Electrochemical Capacitive Behavior

1.
College of Material Science & Engneering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, P. R. China

Received Date: 31 October 2011
Available Online: 7 February 2012
Fund Project: 国家自然科学基金(20873064) (20873064) 江苏省自然科学基金(BK2011030) (BK2011030)高等学校博士学科点专项科研基金(20060287026)资助项目 (20060287026)

OMC/NiCo₂O₄ composite was prepared by co-precipitation with ordered mesoporous carbon (OMC) as a support. The crystalline structure and morphology of the composite were investigated by X-ray diffraction (XRD), Fourier-transform infrared (FT-IR) spectroscopy, and transmission electron microscopy (TEM). TEM images showed that NiCo₂O₄ was uniformly coated on the OMC. Cyclic voltammetry and galvanostatic charge-discharge were used to investigate the electrochemical performance of the OMC/ NiCo₂O₄ composite. The specific capacitances of the OMC/NiCo₂O₄ composite with a mass fraction of 40% NiCo₂O₄ were 577.0 F·g^-1 at a current density of 1 A·g^-1 and 470.8 F·g^-1 at 8 A·g^-1. The specific capacitance remains at 508.4 F·g^-1 after 2000 cycles at a current density of 2 A·g^-1, with a capacitance retention of 92.7%.
- Supercapacitor,
- Ordered mesoporous carbon,
- NiCo₂O₄,
- Co-precipitation method
1. [1]
  (1) Conway, B. E. J. Electrochem. Soc. 1991, 138, 1539.
2. [2]
  (2) Miller, J. R. Electrochim. Acta 2006, 52, 1703.
3. [3]
  (3) Liu, C.; Li, F.; Ma, L. P.; Cheng, H. M. Adv. Mater. 2010, 22, E28.
4. [4]
  (4) Zhang, F.; Yuan, C. Z.; Zhang, X. G.; Zhang, L. J.; Xu, K. Acta Phys. - Chim. Sin. 2010, 26 (12), 3175. [张方, 原长洲, 张校刚, 章罗江, 徐科. 物理化学学报, 2010, 26 (12), 3175.]
5. [5]
  (5) Yuan, C. Z.; Gao, B.; Shen, L. F.; Yang, S. D. ; Hao, L. ; Lu, X. J.; Zhang, F.; Zhang, L. J.; Zhang, X. G. Nanoscale 2011, 3, 529.
6. [6]
  (6) Hwang, S.W.; Hyun, S. H. J. Non-Cryst. Solids 2004, 347, 238.
7. [7]
  (7) Kim, N. D.; Kim,W.; Joo, J. B.; Oh, S.; Kim, P.; Kim, Y.; Yi, J. J. Power Sources 2008, 180, 671.
8. [8]
  (8) Li,W.; Chen, D.; Li, Z.; Shi, Y.;Wan, Y.; Huang, J.; Yang, J.; Zhao, D.; Jiang, Z. Electrochem. Commun. 2007, 9, 569.
9. [9]
  (9) Hu, C. C.; Chang, K. H.; Lin, M. C.;Wu, Y. T. Nano Lett. 2006, 6, 2690.
10. [10]
  (10) Sugimoto,W.; Iwata, H.; Yokoshima, K.; Murakami, Y.; Takasu, Y. J. Phys. Chem. B 2005, 109, 7330.
11. [11]
  (11) Wu, Z. S.; Ren,W. C.;Wang, D.W.; Li, F.; Liu, B. L.; Cheng, H. M. ACS Nano 2010, 4, 5835.
12. [12]
  (12) Xia, X. H.; Tu, J. P.; Mai, Y. J.;Wang, X. L.; Gu, C. D.; Zhao, X. B. J. Mater. Chem. 2011, 21, 9319.
13. [13]
  (13) Cao, C. Y.; Guo.W.; Cui, Z. M.; Song,W. G.; Cai,W. J. Mater. Chem. 2011, 21, 3204.
14. [14]
  (14) Hu, C. C.; Chen,W. C.; Chang, K. H. J. Electrochem. Soc. 2004, 151, A281.
15. [15]
  (15) Yu, L. Q.; Chen, S. L.; Chang, S.; Li, Y. H.; Gao, Y. Y.;Wang, G. L.; Cao, D. X. Acta Phys .-Chim. Sin. 2011, 27 (3), 615. [于丽秋, 陈书礼, 常莎, 李云虎, 高胤义, 王贵领, 曹殿学. 物理化学学报.2011, 27 (3), 615.]
16. [16]
  (16) Wei, T. Y.;Chen, C. H.; Chien, H. C.; Lu, S. Y.; Hu, C. C. Adv. Mater. 2010, 22, 347.
17. [17]
  (17) Gupta V.; Gupta S.; Miura N. J. Power Sources 2010, 195, 3757.
18. [18]
  (18) Yin,W. Y.; Chen, X.; Cao, M. H.; Hu, C.W.;Wei, B. Q. J. Phys. Chem. C. 2009, 113, 15897.
19. [19]
  (19) Lu, B. P.; Bai, J.; Bo, X. J.; Zhu, L. D.; Guo, L. P. Electrochim. Acta 2010, 55, 8724.
20. [20]
  (20) Cui, B.; Lin, H.; Li, J. B.; Li, X.; Yang, J.; Tao, J. Adv. Funct. Mater. 2008, 18, 1441.
21. [21]
  (21) Singh, R. N.; Koenig, J. F.; Poillerat, G.; Chartier, P. J. Electrochem. Soc. 1990, 137, 1408.
22. [22]
  (22) Chi, B.; Lin, H.; Li, J.;Wang, N.; Yang, J. Int. J. Hydrog. Energy 2006, 31, 1210.
23. [23]
  (23) Aboutalebi, S. H.; Chidembo, A. T.; Chidembo, Salari, M.; Konstantinov, K.;Wexler, D.; Liu, H. K.; Dou, S. X. Energy Environ. Sci. 2011, 4, 1855.
24. [24]
  (24) Meher, S. K.; Justin, P.; Rao, G. R. ACS Appl. Mater. Interfaces 2011, 3, 2063.
25. [25]
  (25) Wang, Y. G.; Li, H. Q.; Xia, Y. Y. Adv. Mater. 2006, 18, 2619.
1. [1]
  Jin CHANG . Supercapacitor performance and first-principles calculation study of Co-doping Ni(OH)₂. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1697-1707. doi: 10.11862/CJIC.20240108
2. [2]
  Yanhui XUE , Shaofei CHAO , Man XU , Qiong WU , Fufa WU , Sufyan Javed Muhammad . Construction of high energy density hexagonal hole MXene aqueous supercapacitor by vacancy defect control strategy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1640-1652. doi: 10.11862/CJIC.20240183
3. [3]
  Zhaomei LIU , Wenshi ZHONG , Jiaxin LI , Gengshen HU . Preparation of nitrogen-doped porous carbons with ultra-high surface areas for high-performance supercapacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 677-685. doi: 10.11862/CJIC.20230404
4. [4]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
5. [5]
  Jiahong ZHENG , Jingyun YANG . Preparation and electrochemical properties of hollow dodecahedral CoNi₂S₄ supported by MnO₂ nanowires. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1881-1891. doi: 10.11862/CJIC.20240170
6. [6]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
7. [7]
  Wen LUO , Lin JIN , Palanisamy Kannan , Jinle HOU , Peng HUO , Jinzhong YAO , Peng WANG . Preparation of high-performance supercapacitor based on bimetallic high nuclearity titanium-oxo-cluster based electrodes. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 782-790. doi: 10.11862/CJIC.20230418
8. [8]
  Kuaibing Wang , Honglin Zhang , Wenjie Lu , Weihua Zhang . Experimental Design and Practice for Recycling and Nickel Content Detection from Waste Nickel-Metal Hydride Batteries. University Chemistry, 2024, 39(11): 335-341. doi: 10.12461/PKU.DXHX202403084
9. [9]
  Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
10. [10]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
11. [11]
  Liang MA , Honghua ZHANG , Weilu ZHENG , Aoqi YOU , Zhiyong OUYANG , Junjiang CAO . Construction of highly ordered ZIF-8/Au nanocomposite structure arrays and application of surface-enhanced Raman spectroscopy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1743-1754. doi: 10.11862/CJIC.20240075
12. [12]
  Tiejun Su . The Construction and Application of the Calculation Formula for Endpoint Error in Precipitation Titration: A Case Study of the Mohr Method. University Chemistry, 2024, 39(11): 384-387. doi: 10.12461/PKU.DXHX202402039
13. [13]
  Binyang Qin , Mengqi Wang , Shimei Wu , Yining Li , Chilin Liu , Yufei Zhang , Haosen Fan . Carbon dots confined nanosheets assembled NiCo₂S₄@CDs cross-stacked architecture for enhanced sodium ion storage. Chinese Chemical Letters, 2024, 35(7): 108921-. doi: 10.1016/j.cclet.2023.108921
14. [14]
  Ziheng Zhuang , Xiao Xu , Kin Shing Chan . Superdrugs for Superbugs. University Chemistry, 2024, 39(9): 128-133. doi: 10.3866/PKU.DXHX202309040
15. [15]
  Dong-Xue Jiao , Hui-Li Zhang , Chao He , Si-Yu Chen , Ke Wang , Xiao-Han Zhang , Li Wei , Qi Wei . Layered (C5H6ON)2[Sb2O(C2O4)3] with a large birefringence derived from the uniform arrangement of π-conjugated units. Chinese Journal of Structural Chemistry, 2024, 43(6): 100304-100304. doi: 10.1016/j.cjsc.2024.100304
16. [16]
  Xiuzheng Deng , Changhai Liu , Xiaotong Yan , Jingshan Fan , Qian Liang , Zhongyu Li . Carbon dots anchored NiAl-LDH@In₂O₃ hierarchical nanotubes for promoting selective CO₂ photoreduction into CH₄. Chinese Chemical Letters, 2024, 35(6): 108942-. doi: 10.1016/j.cclet.2023.108942
17. [17]
  Ke Wang , Jia Wu , Shuyi Zheng , Shibin Yin . NiCo Alloy Nanoparticles Anchored on Mesoporous Mo2N Nanosheets as Efficient Catalysts for 5-Hydroxymethylfurfural Electrooxidation and Hydrogen Generation. Chinese Journal of Structural Chemistry, 2023, 42(10): 100104-100104. doi: 10.1016/j.cjsc.2023.100104
18. [18]
  Tong Zhou , Xue Liu , Liang Zhao , Mingtao Qiao , Wanying Lei . Efficient Photocatalytic H₂O₂ Production and Cr(VI) Reduction over a Hierarchical Ti₃C₂/In₄SnS₈ Schottky Junction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309020-. doi: 10.3866/PKU.WHXB202309020
19. [19]
  Shuangxi Li , Huijun Yu , Tianwei Lan , Liyi Shi , Danhong Cheng , Lupeng Han , Dengsong Zhang . NO_x reduction against alkali poisoning over Ce(SO₄)₂-V₂O₅/TiO₂ catalysts by constructing the Ce⁴⁺–SO₄²⁻ pair sites. Chinese Chemical Letters, 2024, 35(5): 108240-. doi: 10.1016/j.cclet.2023.108240
20. [20]
  Yi YANG , Shuang WANG , Wendan WANG , Limiao CHEN . Photocatalytic CO₂ reduction performance of Z-scheme Ag-Cu₂O/BiVO₄ photocatalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 895-906. doi: 10.11862/CJIC.20230434

Get Citation

PDF

XML

Metrics

PDF Downloads(1782)
Abstract views(2141)
HTML views(5)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation of Ordered Mesoporous Carbon/NiCo2O4 Electrode and Its Electrochemical Capacitive Behavior

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation of Ordered Mesoporous Carbon/NiCo₂O₄ Electrode and Its Electrochemical Capacitive Behavior