Citation: CHE Qian, ZHANG Fang, ZHANG Xiao-Gang, LU Xiang-Jun, DING Bing, ZHU Jia-Jia. Preparation of Ordered Mesoporous Carbon/NiCo₂O₄ Electrode and Its Electrochemical Capacitive Behavior[J]. Acta Physico-Chimica Sinica, ;2012, 28(04): 837-842. doi: 10.3866/PKU.WHXB201202074 shu

Preparation of Ordered Mesoporous Carbon/NiCo₂O₄ Electrode and Its Electrochemical Capacitive Behavior

1.
College of Material Science & Engneering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, P. R. China

Received Date: 31 October 2011
Available Online: 7 February 2012
Fund Project: 国家自然科学基金(20873064) (20873064) 江苏省自然科学基金(BK2011030) (BK2011030)高等学校博士学科点专项科研基金(20060287026)资助项目 (20060287026)

OMC/NiCo₂O₄ composite was prepared by co-precipitation with ordered mesoporous carbon (OMC) as a support. The crystalline structure and morphology of the composite were investigated by X-ray diffraction (XRD), Fourier-transform infrared (FT-IR) spectroscopy, and transmission electron microscopy (TEM). TEM images showed that NiCo₂O₄ was uniformly coated on the OMC. Cyclic voltammetry and galvanostatic charge-discharge were used to investigate the electrochemical performance of the OMC/ NiCo₂O₄ composite. The specific capacitances of the OMC/NiCo₂O₄ composite with a mass fraction of 40% NiCo₂O₄ were 577.0 F·g^-1 at a current density of 1 A·g^-1 and 470.8 F·g^-1 at 8 A·g^-1. The specific capacitance remains at 508.4 F·g^-1 after 2000 cycles at a current density of 2 A·g^-1, with a capacitance retention of 92.7%.
- Supercapacitor,
- Ordered mesoporous carbon,
- NiCo₂O₄,
- Co-precipitation method
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沈阳化工大学材料科学与工程学院沈阳 110142

Preparation of Ordered Mesoporous Carbon/NiCo2O4 Electrode and Its Electrochemical Capacitive Behavior

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Preparation of Ordered Mesoporous Carbon/NiCo₂O₄ Electrode and Its Electrochemical Capacitive Behavior