Citation: JIN Yu, CHEN Hong-Yuan, CHEN Ming-Hai, LIU Ning, LI Qing-Wen. Carbon Nanotube/Polyaniline/Graphene Composite Paper and Its Electrochemical Capacitance Behaviors[J]. Acta Physico-Chimica Sinica, ;2012, 28(03): 609-614. doi: 10.3866/PKU.WHXB201201162 shu

Carbon Nanotube/Polyaniline/Graphene Composite Paper and Its Electrochemical Capacitance Behaviors

JIN Yu ^1,2 ,
CHEN Hong-Yuan ^2,3 ,
CHEN Ming-Hai ^2, ,
LIU Ning ^1, ,
LI Qing-Wen ²

1.
1. School of Materials Science and Engineering, Hefei University of Technology, Hefei 230009, P. R. China;
2. Suzhou Institute of Nano-tech and Nano-bionics, Chinese Academy of Sciences, Suzhou 215123, Jiangsu Province, P. R. China;
3. Graduate University of Chinese Academy of Sciences, Beijing 100049, P. R. China

Received Date: 9 October 2011
Available Online: 16 January 2012
Fund Project: 苏州市科技项目(SYG201018) (SYG201018)江苏省产学研联合创新项目(BY2011178)资助 (BY2011178)

Flexible carbon nanotube/polyaniline/graphene (CNT/PANI/GR) composite papers were prepared by electrochemical polymerization of PANI on cyclic voltammetry electrochemical oxidized CNT (CV-CNT) papers and the successive adsorption of GR. CNT, PANI, and GR provided a flexible conducting network skeleton, faradaic pseudocapacitive material, and surface conductivity modification properties, respectively. The composite papers exhibited a sandwich structure with an outer layer of GR and an inner layer composite network of CV-CNT/PANI, taking full advantage of the superior properties of the three components. The structure and morphology were characterized by field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), and Raman spectroscopy. The chemical capacitance characteristics were studied thoroughly. It was shown that PANI nanowhiskers wrapped around the CV-CNT surface evenly. The composite paper exhibited enhanced capacitance and high current charge/discharge characteristics as a supercapacitor electrode. The specific capacitance level could reach 415 F·g^-1 at a current density of 0.5 A·g^-1 and maintain a level of 106 F·g^-1 at the higher current density of 20 A·g^-1. In the protection of GR, the composite maintained a higher capacitance than CV-CNT/PANI after 1000 cycles, suggesting that the CV-CNT/PANI/GR composite would be an ideal flexible electrode material for a supercapacitor.
- Carbon nanotube,
- Polyaniline,
- Graphene,
- Electrochemical polymerization,
- Capacitance
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