Citation: YANG Xiao-Hong, LIU Chang, LIU Jin-Ku, ZHU Zi-Chun. Facile Synthesis of Assembly HAP Nanoribbon Spheres and the Synergized Action of Its Photocatalytic Properties[J]. Acta Physico-Chimica Sinica, ;2011, 27(12): 2939-2945. doi: 10.3866/PKU.WHXB20112939 shu

Facile Synthesis of Assembly HAP Nanoribbon Spheres and the Synergized Action of Its Photocatalytic Properties

1.
1. Department of Chemistry, East China University of Science and Technology, Shanghai 200237, P. R. China;
2. Department of Chemistry, Chizhou University, Chizhou 247000, Anhui Province, P. R. China

Received Date: 24 June 2011
Available Online: 30 September 2011
Fund Project: 国家自然科学基金(21071024) (21071024)安徽省教育厅重点科研项目(KJ2010A244) (KJ2010A244)污染控制与资源化研究国家重点实验室开放课题(PCRRF09005)资助 (PCRRF09005)

Hydroxyapatite (HAP) nanoribbon spheres with well-defined nanoscale structures and regular morphology were successfully synthesized using a bioactive cooperate template. The spheres are about 5-6 μm in diameter and they form from nanoribbons of 2.5 to 3 μm in length. The morphologies, structures, and surface areas of the products were studied by X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), Fourier transform infrared (FT-IR) spectroscopy and Brunauer-Emmett-Teller (BET) analysis. In addition, the products were used as carried materials for the synthesis of the HAP/ZnO composite catalyst. The degradation rate of rhodamine B (RhB) increased by 125% and the recovery increased by 23.1% when using the composite as a catalyst compared with the ZnO nanoparticles. Possible mechanisms for the formation of the HAP assembly microspheres and their synergistic action are also discussed.
- HAP,
- ZnO,
- Assembly sphere,
- Photocatalysis,
- Synergized action
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