Citation: LIU Qing-Shan, YAN Pei-Fang, YANG Miao, TAN Zhi-Cheng, LI Chang-Ping, WELZ-BIERMANN Urs. Dynamic Viscosity and Conductivity of Ionic Liquids [C_npy][NTf₂] (n=2, 4, 5)[J]. Acta Physico-Chimica Sinica, ;2011, 27(12): 2762-2766. doi: 10.3866/PKU.WHXB20112762 shu

Dynamic Viscosity and Conductivity of Ionic Liquids [C_npy][NTf₂] (n=2, 4, 5)

1.
1. China Ionic Liquid Laboratory, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, LiaoningProvince, P. R. China;
2. Thermochemistry Laboratory, Dalian Institute of Chemical Physics, Chinese Academy of Sciences,Dalian 116023, Liaoning Province, P. R. China;
3. College of Chemical Engineering and the Environment, Dalian University,Dalian 116622, Liaoning Province, P. R. China

Received Date: 20 April 2011
Available Online: 26 September 2011
Fund Project: 国家自然科学基金(21073189, 21006007, 20901076, 21176033) (21073189, 21006007, 20901076, 21176033)中国科学院大连化学物理研究所创新基金(K2009D03)资助项目 (K2009D03)

Experimental dynamic viscosity and conductivity data of the air- and water-stable hydrophobic ionic liquids (ILs) N-alkylpyridinium bis(trifluoromethylsulfonyl)imide ([C_npy][NTf₂] n=2, 4, 5) were recorded at temperatures ranging from 298.15 to 338.15 K and from 283.15 to 338.15 K with an interval of 5 K. The dynamic viscosity and conductivity values of the [C_npy][NTf₂] (n=2, 4, 5) ILs were fitted using the Arrhenius equation and the Fulcher equation. The molar conductivity was calculated at temperatures ranging from 283.15 to 338.15 K from the conductivity and density data. The relationship between the dynamic viscosity and the molar conductivity was discussed in terms of Walden's rule.
- Ionic liquids,
- Dynamic viscosity,
- Conductivity,
- Molar conductivity,
- Walden rule
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Dynamic Viscosity and Conductivity of Ionic Liquids [Cnpy][NTf2] (n=2, 4, 5)

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Dynamic Viscosity and Conductivity of Ionic Liquids [C_npy][NTf₂] (n=2, 4, 5)