Citation: ZHAO Jing-Mao, LI Jun. Corrosion Inhibition Performance of Carbon Steel in Brine Solution Containing H₂S and CO₂by Novel Gemini Surfactants[J]. Acta Physico-Chimica Sinica, ;2012, 28(03): 623-629. doi: 10.3866/PKU.WHXB201112293 shu

Corrosion Inhibition Performance of Carbon Steel in Brine Solution Containing H₂S and CO₂by Novel Gemini Surfactants

ZHAO Jing-Mao ,
LI Jun

1.
College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, P. R. China

Received Date: 17 October 2011
Available Online: 29 December 2011
Fund Project: 国家自然科学基金(51171013)资助项目 (51171013)

A series of novel gemini surfactants containing hydroxyl group have been synthesized including 1,3-bis(dodecyl dimethyl ammonium chloride)-2-propanol, 1,3-bis(myristyl dimethyl ammonium chloride)-2-propanol, 1,3-bis(hexadecyl dimethyl ammonium chloride)-2-propanol, and 1,3-bis(octadecyl dimethyl ammonium chloride)-2-propanol, designated as n-3OH-n (n=12, 14, 16, 18, respectively). The corrosion inhibition for carbon steel in brine solution containing H₂S and CO₂ was investigated using weight loss method, potentiodynamic polarization, and electrochemical impedance spectroscopy (EIS). The results showed that the inhibition efficiencies (IEs) obtained from all of the methods employed demonstrated a clear trend, with the IEs of the gemini surfactants ranked as 14-3OH-14>12-3OH-12> 16-3OH-16>18-3OH-18. Among them, 14-3OH-14 and 12-3OH-12 acted as excellent corrosion inhibitors with IE values greater than 95% at an additive concentration of 35 mg·L^-1. Potentiodynamic polarization curves clearly revealed that the gemini surfactants are mixed-type inhibitors which preferentially inhibit the anodic corrosion process. Adsorption of the synthesized gemini surfactants n-3OH-n (n=12, 14, 16) onto a carbon steel surface obeys the Langmuir adsorption isotherm and they exhibit a mixed physical and chemical adsorption. An adsorption model was proposed to elucidate the inhibition mechanism of gemini surfactants.
- Corrosion inhibitor,
- Gemini surfactant,
- Corrosion,
- Hydrogen sulfide,
- Carbon dioxide
1. [1]
  (1) Choi, Y. S.; Nesic, S.; Ling, S. Electrochim. Acta 2011, 56, 1752.
2. [2]
  (2) Yin, Z. F.; Zhao,W. Z. Electrochim. Acta 2008, 53, 3690.
3. [3]
  (3) Hu, S. Q.; Hu, J. C.; Shi, X.; Zhang, J.; Guo,W. Y. Acta Phys. -Chim. Sin. 2009, 25 (12), 2524. [胡松青, 胡建春, 石鑫, 张军, 郭文跃. 物理化学学报, 2009, 25 (12), 2524.]
4. [4]
  (4) Trabanelli, G. Corrosion 1991, 47, 410.
5. [5]
  (5) Asefi, D.; Arami, M.; Mahmoodi, N. M. Corrosion Sci. 2010, 52, 794.
6. [6]
  (6) Qiu, L. G.; Xie, A. J.; Shen, Y. H. Appl. Surf. Sci. 2005, 246, 1.
7. [7]
  (7) Chen, Q.; Zhang, D.; Li, R.; Liu, H.; Hu, Y. Thin Solid Films 2006, 496, 42.
8. [8]
  (8) Menger, F. M.; Keiper, J. S. Angew. Chem. Int. Edit. 2000, 39, 1906.
9. [9]
  (9) Bagha, A. R. T.; Bahrami, H.; Movassagh, B.; Arami, M.; Arirshahi, S. H.; Menger, F. M. Colloid. Surf. A 2007, 307, 121.
10. [10]
  (10) Yao, S. Z.; Jiang, X. H.; Zhou, L. M.; Lv, Y. J.; Hu, X. Q. Mater. Chem. Phys. 2007, 104, 301.
11. [11]
  (11) Bagha, A. R. T.; Bahrami, H.; Movassagh, B.; Arami, M.; Menger, F. M. Dyes and Pigments 2007, 72, 331.
12. [12]
  (12) Qiu, L. G.;Wang, Y. M.; Jiang, X. Corrosion Sci. 2008, 50, 576.
13. [13]
  (13) Achouri, M. E.; Infante, M. R.; Izquierdo, F.; Kertit, S.; uttaya, H. M.; Nciri, B. Corrosion Sci. 2001, 43, 19.
14. [14]
  (14) Qiu, L. G.; Xie, A. J.; Shen, Y. H. Corrosion Sci. 2005, 47, 273.
15. [15]
  (15) Huang,W.; Zhao, J. Colloid. Surf. A 2006, 278, 246.
16. [16]
  (16) Qiu, L. G.; Xie, A. J.; Shen, Y. H. Mater. Chem. Phys. 2005, 91, 269.
17. [17]
  (17) Wang, X.; Yang, H.;Wang, F. Corrosion Sci. 2010, 52, 1268.
18. [18]
  (18) Hegazy, M. A.; Abdallah, M.; Ahmed, H. Corrosion Sci. 2010, 52, 2897.
19. [19]
  (19) Hegazy, M. A. Corrosion Sci. 2009, 51, 2610.
20. [20]
  (20) Yang, J. Z.; Miao, Z. C.; Xu, L. Fine Chemicals 2005, 22, 49. [杨建洲, 苗宗成, 林里. 精细化工, 2005, 22, 49.]
21. [21]
  (21) Tang, L. B.; Mu, G. N.; Liu, G. H. Corrosion Sci. 2003, 45, 2251.
22. [22]
  (22) Cao, C. N. Journal of Chinese Society of Corrosion and Protection 1985, 5, 155. [曹楚南. 中国腐蚀与防护学报, 1985, 5, 155.]
23. [23]
  (23) Jüttner, K. Electrochim. Acta 1990, 35, 1501.
24. [24]
  (24) Paskossy, T. J. Electroanal. Chem. 1994, 364, 111.
25. [25]
  (25) Saliyan, V. R.; Adhikari, A. V. Corrosion Sci. 2008, 50, 55.
26. [26]
  (26) Benedetti, A. V.; Sumodjo, P. T. A.; Nobe, K.; Cabot, P. L.; Proud,W. G. Electrochim. Acta 1995, 40, 2657.
27. [27]
  (27) Hassan, H. H. Electrochim. Acta 2007, 53, 1722.
28. [28]
  (28) Quraishi, M. A.; Rawat, J. Mater. Chem. Phys. 2001, 70, 95.
29. [29]
  (29) Muralidharan, S.; Phani, K. L. N.; Pitchumani, S.; Ravichandran, S.; Iyer, S. V. K. J. Electrochem. Soc. 1995, 142, 1478.
30. [30]
  (30) Christov, M.; Popova, A. Corrosion Sci. 2004, 46, 1613.
31. [31]
  (31) Qiu, L. G.;Wu, Y. Progress in Corrosion Research; Bettini, E. L. Ed.; Nova Science Publishers, Inc.: New York, 2007, 159.
32. [32]
  (32) Elachouri, M.; Hajji, M. S.; Salem, M.; Kertit, S.; Aride, J.; Coudert, R.; Essassi, E. NACE. International; TEXAS: Houston, 1996, 52, 103.
33. [33]
  (33) Savitri, B. V.; Mayanna, S. Indian J. Chem. Technol. 1996, 3, 103.
34. [34]
  (34) Hu, S. Q.; Hu, J. C.; Fan, C. C.; Mi, S. Q.; Zhang, J. Guo,W. Y. Acta Phys. -Chim. Sin. 2010, 26, 2163. [胡松青, 胡建春, 范成成, 米思奇, 张军, 郭文跃. 物理化学学报, 2010, 26, 2163.]
35. [35]
  (35) Okafor, P. C.; Zheng, Y. G. Corrosion Sci. 2009, 51, 850.
36. [36]
  (36) Ma, H. Y.; Cheng, X. L.; Chen, S. H.;Wang, C.; Zhang, J. P.; Yang, H. Q. J. Electroanal. Chem. 1998, 451, 11.
37. [37]
  (37) Cheng, X. L.; Ma, H. Y.; Zhang, J. P.; Chen, X.; Chen, S. H.; Yang, H. Q. Corrosion 1998, 54, 369.
38. [38]
  (38) Ma, H. Y.; Cheng, X. L.; Chen, S. H.; Li, G. Q; Chen, X.; Lei, S. B.; Yang, H. Q. Corrosion 1998, 54, 634.
39. [39]
  (39) Gao, Y. M.; Chen, J. J.; Lei, L. C.; Yang, H. Y.; Cao, D. C.;Wu, W. T. Journal of Chinese Society of Corrosion and Protection 2000, 20, 142. [高延敏, 陈家坚, 雷良才, 杨怀玉, 曹殿珍, 吴维弢. 中国腐蚀与防护学报, 2000, 20, 142.]
40. [40]
  (40) Zhang, J.; Yu,W. Z.; Yan, Y. G.; Yu, L. J.; Ren, Z. J. Acta Phys. -Chim. Sin. 2010, 26, 1386. [张军, 于维钊, 燕友果, 于立军, 任振甲. 物理化学学报, 2010, 26, 1386.]
1. [1]
  Xingyu Liao , Xiangming Yi , Kin Shing Chan . 追凶之路上的怪客——硫化氢. University Chemistry, 2025, 40(6): 172-176. doi: 10.12461/PKU.DXHX202408039
2. [2]
  Jiayi Yang , Jianxiu Hao , Huacong Zhou , Quansheng Liu . “Gorgeous Transformation” of Carbon Dioxide into Cyclic Carbonates: Catalyst Types and Roles. University Chemistry, 2026, 41(2): 178-189. doi: 10.12461/PKU.DXHX202502105
3. [3]
  Xiaolong Li , Shiqi Zhong , Xiangfeng Wei , Zhiqiang Liu , Pan Zhan , Jiehua Liu . Carbon Dioxide: From the Past to the Future. University Chemistry, 2026, 41(2): 242-247. doi: 10.12461/PKU.DXHX202503013
4. [4]
  Yanhui Guo , Li Wei , Zhonglin Wen , Chaorong Qi , Huanfeng Jiang . Recent Progress on Conversion of Carbon Dioxide into Carbamates. Acta Physico-Chimica Sinica, 2024, 40(4): 2307004-0. doi: 10.3866/PKU.WHXB202307004
5. [5]
  Hailian Cheng , Shuaiqiang Jia , Chunjun Chen , Haihong Wu , Buxing Han . Electrocatalytic CO₂ Conversion: A Key to Unlocking a Low-Carbon Future. University Chemistry, 2026, 41(2): 1-13. doi: 10.12461/PKU.DXHX202502023
6. [6]
  Xiaofei Liu , He Wang , Li Tao , Weimin Ren , Xiaobing Lu , Wenzhen Zhang . Electrocarboxylation of Benzylic Phosphates and Phosphinates with Carbon Dioxide. Acta Physico-Chimica Sinica, 2024, 40(9): 2307008-0. doi: 10.3866/PKU.WHXB202307008
7. [7]
  Jiayin Hu , Yafei Guo , Long Li , Tianlong Deng . Teaching Innovation of Salt-Water System Phase Diagrams under the “Dual Carbon” Background: Introducing the Pressurized CO₂ Carbonization Phase Equilibria. University Chemistry, 2025, 40(11): 31-36. doi: 10.12461/PKU.DXHX202412031
8. [8]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-Based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-0. doi: 10.3866/PKU.WHXB202406029
9. [9]
  Jianan Hong , Chenyu Xu , Yan Liu , Changqi Li , Menglin Wang , Yanwei Zhang . Decoding the interfacial competition between hydrogen evolution and CO₂ reduction via edge-active-site modulation in photothermal catalysis. Acta Physico-Chimica Sinica, 2025, 41(9): 100099-0. doi: 10.1016/j.actphy.2025.100099
10. [10]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
11. [11]
  Yucai Zhang , Jun Jiang . Electrochemical Carbon Dioxide Reduction to Ethylene. University Chemistry, 2026, 41(2): 190-196. doi: 10.12461/PKU.DXHX202503006
12. [12]
  Yukai Jiang , Yihan Wang , Yunkai Zhang , Yunping Wei , Ying Ma , Na Du . Characterization and Phase Diagram of Surfactant Lyotropic Liquid Crystal. University Chemistry, 2024, 39(4): 114-118. doi: 10.3866/PKU.DXHX202309033
13. [13]
  Qiang Zhang , Yuanbiao Huang , Rong Cao . Imidazolium-Based Materials for CO₂ Electroreduction. Acta Physico-Chimica Sinica, 2024, 40(4): 2306040-0. doi: 10.3866/PKU.WHXB202306040
14. [14]
  Tianhao GE , Sirong LU , Zhiyin XIAO , Wei ZHONG . Synthesis of porphyrin-based ionic polymeric materials for catalytic application in CO₂ conversion. Chinese Journal of Inorganic Chemistry, 2026, 42(4): 722-736. doi: 10.11862/CJIC.20250312
15. [15]
  Congying Lu , Fei Zhong , Zhenyu Yuan , Shuaibing Li , Jiayao Li , Jiewen Liu , Xianyang Hu , Liqun Sun , Rui Li , Meijuan Hu . Experimental Improvement of Surfactant Interface Chemistry: An Integrated Design for the Fusion of Experiment and Simulation. University Chemistry, 2024, 39(3): 283-293. doi: 10.3866/PKU.DXHX202308097
16. [16]
  Bizhu Shao , Huijun Dong , Yunnan Gong , Jianhua Mei , Fengshi Cai , Jinbiao Liu , Dichang Zhong , Tongbu Lu . Metal-Organic Framework-Derived Nickel Nanoparticles for Efficient CO₂ Electroreduction in Wide Potential Windows. Acta Physico-Chimica Sinica, 2024, 40(4): 2305026-0. doi: 10.3866/PKU.WHXB202305026
17. [17]
  Yan Kong , Wei Wei , Lekai Xu , Chen Chen . Electrochemical Synthesis of Organonitrogen Compounds from N-integrated CO₂ Reduction Reaction. Acta Physico-Chimica Sinica, 2024, 40(8): 2307049-0. doi: 10.3866/PKU.WHXB202307049
18. [18]
  Huiying ZHANG , Ping LI , Weixia DONG , Zhiwen HU , Qifu BAO , Qizheng DONG , Mingmin BAI , Wenqi LI . Photocatalytic performance of spheroidal nano Bi₄Ti₃O₁₂ prepared by surfactant-assisted hydrothermal reaction. Chinese Journal of Inorganic Chemistry, 2026, 42(3): 551-561. doi: 10.11862/CJIC.20250269
19. [19]
  Jie ZHAO , Huili ZHANG , Xiaoqing LU , Zhaojie WANG . Theoretical calculations of CO₂ capture and separation by functional groups modified 2D covalent organic framework. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 275-283. doi: 10.11862/CJIC.20240213
20. [20]
  Wei HE , Jing XI , Tianpei HE , Na CHEN , Quan YUAN . Application of solar-driven inorganic semiconductor-microbe hybrids in carbon dioxide fixation and biomanufacturing. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 35-44. doi: 10.11862/CJIC.20240364

Get Citation

PDF

XML

Metrics

PDF Downloads(947)
Abstract views(2968)
HTML views(87)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Corrosion Inhibition Performance of Carbon Steel in Brine Solution Containing H2S and CO2by Novel Gemini Surfactants

Metrics

通讯作者: 陈斌, bchen63@163.com

Corrosion Inhibition Performance of Carbon Steel in Brine Solution Containing H₂S and CO₂by Novel Gemini Surfactants