Citation: JIANG Li-Long, MA Yong-De, CAO Yan-Ning, YANG Yang, WEI Ke-Mei. Modified Bauxite Supported Ruthenium Catalysts for Hydrogen Evolution in the Water-Gas Shift Reaction[J]. Acta Physico-Chimica Sinica, ;2012, 28(03): 674-680. doi: 10.3866/PKU.WHXB201112271 shu

Modified Bauxite Supported Ruthenium Catalysts for Hydrogen Evolution in the Water-Gas Shift Reaction

1.
National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou 350002, P. R. China

Received Date: 19 September 2011
Available Online: 27 December 2011
Fund Project: 福建省自然科学基金(2011J01036) (2011J01036) 福建省教育厅基金(JA09012) (JA09012) 福州大学人才启动基金及福州大学科技发展基金项目(2010-XQ-05)资助 (2010-XQ-05)

Hydrothermally treated bauxite with high surface area was used as a ruthenium-based catalyst support. A series of Ru/bauxite and 2.0% (mass fraction) Ru/Al₂O₃ catalysts were prepared by incipientwetness impregnation. The loading content of ruthenium in the Ru/bauxite catalysts was varied from 1.0% to 4.0%. The catalysts were thoroughly characterized by X-ray fluorescence (XRF), low temperature N₂ physical adsorption, X-ray diffraction (XRD), H₂ temperature-programmed reduction (H₂-TPR), and CO temperature-programmed desorption (CO-TPD). The performances of the catalysts for the water-gas shift reaction were also investigated. The results indicated that Ru/bauxite catalysts possess an excellent ability to evolve hydrogen in the water-gas shift reaction. This was attributed to the interaction between Ru and Fe₂O₃ in the modified bauxite, which could decrease the reduction temperature of Fe₂O₃, and also improve the adsorption-desorption behavior and decrease the desorption temperature of Ru/bauxite catalysts for CO molecules, resulting in higher activity in the water-gas shift reaction.
- Bauxite,
- Ru/bauxite catalyst,
- Water-gas shift,
- Hydrogen evolution
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