Citation: ZHAO Lei, WANG An-Bang, WANG Wei-Kun, YU Zhong-Bao, CHEN Shi, YANG Yu-Sheng. Preparation and Electrochemical Performance of Aminoanthraquinone Derivative as Cathode Materials in Rechargeable Lithium Batteries[J]. Acta Physico-Chimica Sinica, ;2012, 28(03): 596-602. doi: 10.3866/PKU.WHXB201112261 shu

Preparation and Electrochemical Performance of Aminoanthraquinone Derivative as Cathode Materials in Rechargeable Lithium Batteries

1.
1. School of Chemical Engineering and Environment, Beijing Institute of Technology, Beijing 100081, P. R. China;
2. Military Power Sources Research and Development Center, Research Institute of Chemical Defense, Beijing 100191, P. R. China

Received Date: 11 October 2011
Available Online: 26 December 2011
Fund Project: 国家重点基础研究发展计划项目(973)(2009CB220100)资助 (973)(2009CB220100)

Two novel organic compounds, 5-amino-2,3-dihydro-1,4-dyhydroxy anthraquinone (ADDAQ) and 5-amino-1,4-dyhydroxy anthraquinone (ADAQ), were synthesized as cathode materials for lithium batteries. The compounds were characterized by ¹H nuclear magnetic resonance (¹H NMR) spectroscopy, mass spectrometry (MS), elemental analysis (EA), Fourier transform infrared spectroscopy (FTIR), ultraviolet-visible (UV-Vis) spectroscopy. The electrochemical performance of the compounds was investigated by galvanostatic discharge/charge (GD/C) measurements, cyclic voltammetry (CV), and electrochemical impedance spectrum (EIS). Compared with ADDAQ, the initial discharge specific capacity and cycle performance of ADAQ were effectively improved. The initial discharge specific capacity of ADAQ was 185 mAh·g^-1, after 50 cycles, the specific capacity was maintained at 93 mAh·g^-1. A reason for this improvement is discussed.
- Lithium battery,
- 5-Amion-2,3-dihydro-1,4-dyhydroxy anthraquinone,
- 5-Amino-1,4-dyhydroxy anthraquinone,
- Organic cathode material,
- Electrochemical performance
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