Citation: HE Sai-Nan, HU Cai-Yuan, XIAO Ge, ZHENG Hua-Jun. Hydrothermal Synthesis and Amperometric Determination of Hydrogen Peroxide of Highly-Dispersed MnO₂ Nanofibers[J]. Acta Physico-Chimica Sinica, ;2012, 28(03): 630-634. doi: 10.3866/PKU.WHXB201112214 shu

Hydrothermal Synthesis and Amperometric Determination of Hydrogen Peroxide of Highly-Dispersed MnO₂ Nanofibers

1.
1. Women's Hospital, School of Medicine, Zhejiang University, Hangzhou 310006, P. R. China;
2. College of Chemical Engineering and Materials Science, Zhejiang University of Technology, Hangzhou 310014, P. R. China

Received Date: 14 October 2011
Available Online: 21 December 2011
Fund Project: 国家自然科学基金(20973156)资助项目 (20973156)

A high dispersed nanofiber cryptomelane-type manganese dioxide was synthesized by a facile hydrothermal reduction route. The morphological characterization was examined by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The structure and electrochemical properties of the synthesized manganese dioxide were characterized by X-ray diffraction (XRD), Brunauer- Emmett-Teller (BET) surface area analyses, and an electrochemical workstation (EW). A glassy carbon electrode (GCE) modified with the nanostructured cryptomelane-type manganese dioxide was investigated for amperometric detection of hydrogen peroxide (H₂O₂) in phosphate buffer solution with a pH 7.4 at an open circuit potential of 0.2 V. The oxidation peak current was found to increase by 1.3 μA with the addition of 0.1 mmol·L^-1 H₂O₂ based on a MnO₂ nanofiber-gelatin/GCE electrode. The amperometric signals are linearly proportional to the H₂O₂ concentration in the range 0.1-1.5 mmol·L^-1 with a correlation coefficient of 0.996 using the GCE modified with 0.1% (w, mass fraction) cryptomelane-type manganese oxides. The sensor is sensitive and its significant electrocatalytic activity results from the nanostructure of the cryptomelane-type manganese oxides. In addition, the sensor has a od reproducibility, a low detection limit, simplicity, and a low cost of construction. These results demonstrate that this material with high electrocatalytic activity offers great promise as a new class of nanostructured electrodes for biosensors.
- Hydrogen peroxide,
- Cryptomelane-type manganese dioxide,
- Glassy carbon electrode,
- Phosphate buffer solution,
- Biosensor
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沈阳化工大学材料科学与工程学院沈阳 110142

Hydrothermal Synthesis and Amperometric Determination of Hydrogen Peroxide of Highly-Dispersed MnO2 Nanofibers

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通讯作者: 陈斌, bchen63@163.com

Hydrothermal Synthesis and Amperometric Determination of Hydrogen Peroxide of Highly-Dispersed MnO₂ Nanofibers