Citation: MAO Jing, DAI Ke-Hua, ZHAI Yu-Chun. High Rate Capability and Cycling Stability of Li_1.07Mn_1.93O₄ Nanoflakes Synthesized via Gel-Combustion Method[J]. Acta Physico-Chimica Sinica, ;2012, 28(02): 349-354. doi: 10.3866/PKU.WHXB201112052 shu

High Rate Capability and Cycling Stability of Li_1.07Mn_1.93O₄ Nanoflakes Synthesized via Gel-Combustion Method

1.
School of Materials and Metallurgy, Northeastern University, Shenyang 110004, P. R. China

Received Date: 18 July 2011
Available Online: 5 December 2011

Li_1.07Mn_1.93O₄ nanoflakes were synthesized by a gel-combustion method using polyvinylpyrrolidone (PVP) as the polymer chelating agent and fuel. Thermogravimetric and differential thermal analyses (TG/DTA) were used to investigate the combustion process of the gel precursor. X-ray diffraction (XRD) analysis indicated that the as-prepared Li_1.07Mn_1.93O₄ was a pure, highly crystalline phase. Scanning electron microscopy (SEM) results showed that most of the secondary particles were nanoflakes, about 100 nm in thickness, and the primary particle of the nanoflakes was about 100 nm in size. Charge and discharge tests suggested that the Li_1.07Mn_1.93O₄ nanoflakes had excellent rate capability and od cycling stability. The initial discharge capacity was 115.4 mAh·g^-1 at a rate of 0.5C (1C=120 mAh·g^-1) and the capacity was maintained at 105.3 mAh·g^-1 at the high discharge rate of 40C. When cycling at 10C, the material retained 81% of its initial capacity after 850 cycles. Electrochemical impedance spectroscopy (EIS) tests indicated that the charge-transfer resistance (R_ct) of the Li_1.07Mn_1.93O₄ nanoflakes was much less than that of commercial Li_1.07Mn_1.93O₄.
- Lithium ion battery,
- Lithium manganese oxide,
- Combustion synthesis,
- Rate capability,
- Cycling stability
1. [1]
  (1) Tarascon, J. M.; Armand, M. Nature 2001, 414, 359.
2. [2]
  (2) Du Pasquier, A.; Huang, C. C.; Spitler, T. Journal of Power Sources 2009, 186, 508.
3. [3]
  (3) Kudo, T.; Honma, I.; Matsuda, H.; Zhou, H. S. Nano Letters 2009, 9, 1045.
4. [4]
  (4) Lanz, M.; Kormann, C.; Steininger, H.; Heil, G.; Haas, O.; Novak, P. Journal of the Electrochemical Society 2000, 147, 3997.
5. [5]
  (5) Lee, J.W.; Park, S. M.; Kim, H. J. Electrochemistry Communications 2009, 11, 1101.
6. [6]
  (6) Lee, K. S.; Myung, S. T.; Bang, H.; Amine, K.; Kim, D.W.; Sun, Y. K. Journal of Power Sources 2009, 189, 494.
7. [7]
  (7) Lim, S.; Cho, J. Electrochemistry Communications 2008, 10, 1478.
8. [8]
  (8) Ma, S. B.; Nam, K.W.; Yoon,W. S.; Bak, S. M.; Yang, X. Q.; Cho, B.W.; Kim, K. B. Electrochemistry Communications 2009, 11, 1575.
9. [9]
  (9) Park, S. C.; Han, Y. S.; Kang, Y. S.; Lee, P. S.; Ahn, S.; Lee, H. M.; Lee, J. Y. Journal of the Electrochemical Society 2001, 148, A680.
10. [10]
  (10) Park, S. C.; Kim, Y. M.; Kang, Y. M.; Kim, K. T.; Lee, P. S.; Lee, J. Y. Journal of Power Sources 2001, 103, 86.
11. [11]
  (11) Wang, X. Q.; Tanaike, O.; Kodama, M.; Hatori, H. Journal of Power Sources 2007, 168, 282.
12. [12]
  (12) Yue, H.; Huang, X.; Lv, D.; Yang, Y. Electrochimica Acta 2009, 54, 5363.
13. [13]
  (13) Arico, A. S.; Bruce, P.; Scrosati, B.; Tarascon, J. M.; Van Schalkwijk,W. Nature Materials 2005, 4, 366.
14. [14]
  (14) Bruce, P. G.; Scrosati, B.; Tarascon, J. M. Angewandte Chemie-International Edition 2008, 47, 2930.
15. [15]
  (15) Chen, Z. Y.; Zhu, H. L.; Ji, S.; Linkov, V.; Zhang, J. L.; Zhu,W. Journal of Power Sources 2009, 189, 507.
16. [16]
  (16) Kamarulzaman, N.; Yusoff, R.; Kamarudin, N.; Shaari, N. H.; Aziz, N. A. A.; Bustam, M. A.; Bla jevic, N.; Elcombe, M.; Blackford, M.; Avdeev, M.; Arof, A. K. Journal of Power Sources 2009, 188, 274.
17. [17]
  (17) Ye, S. H.; Lv, J. Y.; Gao, X. P.;Wu, F.; Song, D. Y. Electrochimica Acta 2004, 49, 1623.
18. [18]
  (18) Caballero, A.; Cruz, M.; Hernán, L.; Melero, M.; Morales, J.; Castellón, E. R. Journal of Power Sources 2005, 150, 192.
19. [19]
  (19) Huang, Y. D.; Jiang, R. R.; Bao, S. J.; Dong, Z. F.; Cao, Y. L.; Jia, D. Z.; Guo, Z. P. Journal of Solid State Electrochemistry 2009, 13, 799.
20. [20]
  (20) Shaju, K. M.; Bruce, P. G. Chemistry of Materials 2008, 20, 5557.
21. [21]
  (21) Vivekanandhan, S.; Venkateswarlu, M.; Satyanarayana, N. Journal of Alloys and Compounds 2007, 441, 284.
22. [22]
  (22) Patey, T. J.; Buchel, R.; Nakayama, M.; Novak, P. Physical Chemistry Chemical Physics 2009, 11, 3756.
23. [23]
  (23) Patey, T. J.; Buchel, R.; Ng, S. H.; Krumeich, F.; Pratsinis, S. E.; Novak, P. Journal of Power Sources 2009, 189, 149.
24. [24]
  (24) Cabana, J.; Valdes-Solis, T.; Palacin, M. R.; Oro-Sole, J.; Fuertes, A.; Marban, G.; Fuertes, A. B. Journal of Power Sources 2007, 166, 492.
25. [25]
  (25) Jiao, F.; Bao, J. L.; Hill, A. H.; Bruce, P. G. Angewandte Chemie-International Edition 2008, 47, 9711.
26. [26]
  (26) Luo, J. Y.;Wang, Y. G.; Xiong, H. M.; Xia, Y. Y. Chemistry of Materials 2007, 19, 4791.
27. [27]
  (27) Katakura, K.;Wada, K.; Kajiki, Y.; Yamamoto, A.; Ogumi, Z. Journal of Power Sources 2009, 189, 240.
28. [28]
  (28) Luo, J. Y.; Cheng, L.; Xia, Y. Y. Electrochemistry Communications 2007, 9, 1404.
29. [29]
  (29) Uchiyama, H.; Hosono, E.; Zhou, H. S.; Imai, H. Journal of Materials Chemistry 2009, 19, 4012.
30. [30]
  (30) Fang, H. S.; Li, L. P.; Yang, Y.; Yan, G. F.; Li, G. S. Journal of Power Sources 2008, 184, 494.
31. [31]
  (31) Jiang, C. H.; Dou, S. X.; Liu, H. K.; Ichihara, M.; Zhou, H. S. Journal of Power Sources 2007, 172, 410.
32. [32]
  (32) Kim, D. K.; Muralidharan, P.; Lee, H.W.; Ruffo, R.; Yang, Y.; Chan, C. K.; Peng, H.; Huggins, R. A.; Cui, Y. Nano Letters 2008, 8, 3948.
33. [33]
  (33) Fey, G.; Cho, Y.; Kumar, T. Materials Chemistry and Physics 2006, 99, 451.
34. [34]
  (34) Liu, Q. G.; Yang,W. S.; Zhang, G.; Xie, J. Y.; Yang, L. L. Journal of Power Sources 1999, 81, 412.
35. [35]
  (35) Fey, G. T. K.; Cho, Y. D.; Kumar, T. P. Materials Chemistry and Physics 2004, 87, 275.
36. [36]
  (36) Kalyani, P.; Kalaiselvi, N.; Muniyandi, N. Journal of Power Sources 2002, 111, 232.
37. [37]
  (37) Park, H. B.; Kim, J.; Lee, C.W. Journal of Power Sources 2001, 92, 124.
38. [38]
  (38) Subramania, A.; Angayarkanni, N.; Vasudevan, T. Materials Chemistry and Physics 2007, 102, 19.
39. [39]
  (39) Wu, X. M.; Li, X. H.; Xiao, Z. B.; Liu, J.; Yan,W. B.; Ma, M. Y. Materials Chemistry and Physics 2004, 84, 182.
40. [40]
  (40) Zhang, Y.; Shin, H. C.; Dong, J.; Liu, M. Solid State Ionics 2004, 171, 25.
41. [41]
  (41) Amarilla, J. M.; Petrov, K.; Pico, F.; Avdeev, G.; Rojo, J. M.; Rojas, R. M. Journal of Power Sources 2009, 191, 591.
42. [42]
  (42) Kovacheva, D.; Gadjov, H.; Petrov, K.; Mandal, S.; Lazarraga, M. G.; Pascual, L.; Amarilla, J. M.; Rojas, R. M.; Herrero, P.; Rojo, J. M. Journal of Materials Chemistry 2002, 12, 1184.
43. [43]
  (43) Zhang, J. H.; Liu, J. B.;Wang, S. Z.; Zhan, P.;Wang, Z. L.; Ming, N. B. Adv. Funct. Mater. 2004, 14, 1089.
44. [44]
  (44) Fu, Y. S.; Chen, L. J.; Liao, J. D.; Chuang, Y. J.; Hsu, K. C.; Chiang, Y. F. J. Appl. Polym. Sci. 2011, 121, 154.
45. [45]
  (45) Kanamura, K.; Rho, Y. H. J. Electroanal. Chem. 2003, 559, 69.
46. [46]
  (46) Kanamura, K.; Rho, Y. H. J. Solid State Chem. 2004, 177, 2094.
47. [47]
  (47) Kanamura, K.; Rho, Y. H. Journal of Power Sources 2006, 158, 1436.
48. [48]
  (48) Kanamura, K.; Rho, Y. H.; Umegaki, T. Chem. Lett. 2001, 1322.
49. [49]
  (49) Dai, K. H.; Mao, J.; Zhai, Y. C. Acta Phys. -Chim. Sin. 2010, 26, 2130. [代克化, 毛景, 翟玉春. 物理化学学报, 2010, 26, 2130.]
50. [50]
  (50) Hirose, S.; Kodera, T.; Ogihara, T. Journal of Alloys and Compounds 2010, 506, 883.
51. [51]
  (51) Peng, Z. D.; Jiang, Q. L.; Du, K.;Wang,W. G.; Hu, G. R.; Liu, Y. X. Journal of Alloys and Compounds 2010, 493, 640.
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

High Rate Capability and Cycling Stability of Li1.07Mn1.93O4 Nanoflakes Synthesized via Gel-Combustion Method

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通讯作者: 陈斌, bchen63@163.com

High Rate Capability and Cycling Stability of Li_1.07Mn_1.93O₄ Nanoflakes Synthesized via Gel-Combustion Method