Citation: LUO Xiao-Lin, HAN Yin-Feng, YANG De-Suo, CHEN Ya-Shao. Solvo-Thermal Synthesis of Cu₂O Micro-Spheres and Their Catalytic Performance for Thermal Decomposition of Ammonium Perchlorate[J]. Acta Physico-Chimica Sinica doi: 10.3866/PKU.WHXB201112012 shu

Solvo-Thermal Synthesis of Cu₂O Micro-Spheres and Their Catalytic Performance for Thermal Decomposition of Ammonium Perchlorate

1.
1. Shaanxi Key Laboratory for Phytochemistry, Department of Chemistry and Chemical Engineering, Baoji University of Arts and Sciences, Baoji 721013, Shaanxi Province, P. R. China;
2. Key Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education, School of Chemistry & Chemical Engineering, Shaanxi Normal University, Xi'an 710062, P. R. China

Received Date: 5 September 2011
Available Online: 1 December 2011
Fund Project: 陕西省教育厅项目(11JK0603) (11JK0603)陕西省重点实验室项目(11JS007)资助 (11JS007)

Cu₂O micro-spheres were fabricated by a solvothermal method using poly vinylpyrrolidone (PVP) as an additive. The influences of PVP dosage and reaction temperature on the morphologies of the products were investigated. Cu₂O micro-spheres with diameters of 100-200 nm and about 1 μm were synthesized with reaction time of 2.5 and 4.5 h, respectively. Meanwhile, differential thermal analysis (DTA) was used to determine the catalytic performance of these Cu₂O micro-spheres with different diameters for thermal decomposition of ammonium perchlorate (AP). Adding 2% (w) Cu₂O micro-spheres with diameters of 100-200 nm and about 1 μm into AP decreased the maximum temperature of AP decomposition by 116 and 118 °C, respectively, and increased the amount of AP decomposed at lower temperature.
- Cu₂O micro-spheres,
- Solvent-thermal synthesis,
- Ammonium perchlorate,
- Thermal decomposition
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沈阳化工大学材料科学与工程学院沈阳 110142

Solvo-Thermal Synthesis of Cu2O Micro-Spheres and Their Catalytic Performance for Thermal Decomposition of Ammonium Perchlorate

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通讯作者: 陈斌, bchen63@163.com

Solvo-Thermal Synthesis of Cu₂O Micro-Spheres and Their Catalytic Performance for Thermal Decomposition of Ammonium Perchlorate