Citation: WEI Yi, WANG Li-Juan, YAN Ji, SHA Ou, TANG Zhi-Yuan, MA Li. Calcination Temperature Effects on the Electrochemical Performance of Li₂MnSiO₄/C Cathode Material for Lithium Ion Batteries[J]. Acta Physico-Chimica Sinica, ;2011, 27(11): 2587-2592. doi: 10.3866/PKU.WHXB20111124 shu

Calcination Temperature Effects on the Electrochemical Performance of Li₂MnSiO₄/C Cathode Material for Lithium Ion Batteries

WEI Yi ^1, ,
WANG Li-Juan ¹ ,
YAN Ji ¹ ,
SHA Ou ¹ ,
TANG Zhi-Yuan ¹ ,
MA Li ²

1.
1. School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, P. R. China;
2. McNair Technology Company, Limited, Dongguan 523800, Guangdong Province, P. R. China

Received Date: 4 July 2011
Available Online: 13 September 2011
Fund Project: 国家自然科学基金(20973124)资助项目 (20973124)

As a new potential cathode material for lithium ion batteries, Li₂MnSiO₄/C was synthesized by a solution method. The thermal behavior of the precursor for Li₂MnSiO₄/C was measured by thermogravimetric (TG) analysis and the range of calcination temperatures from 600 to 800°C was determined. X-ray powder diffraction (XRD) patterns indicated that all the Li₂MnSiO₄/C samples crystallized in an orthorhombic structure with space group Pmn2₁. The morphology and particle size of the samples were also characterized by scanning electron microscopy (SEM). The effects of calcination temperature on the electrochemical performance of Li₂MnSiO₄/C were studied using galvanostatic charge-discharge measurements at various current densities. The results showed that the sample prepared at 700°C exhibited a much higher coulombic efficiency and better cyclic performance than the other samples.
- Lithium ion battery,
- Cathode material,
- Li₂MnSiO₄,
- Solution method,
- Calcination temperature
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Calcination Temperature Effects on the Electrochemical Performance of Li₂MnSiO₄/C Cathode Material for Lithium Ion Batteries