Citation: WEI Yi, WANG Li-Juan, YAN Ji, SHA Ou, TANG Zhi-Yuan, MA Li. Calcination Temperature Effects on the Electrochemical Performance of Li₂MnSiO₄/C Cathode Material for Lithium Ion Batteries[J]. Acta Physico-Chimica Sinica, ;2011, 27(11): 2587-2592. doi: 10.3866/PKU.WHXB20111124 shu

Calcination Temperature Effects on the Electrochemical Performance of Li₂MnSiO₄/C Cathode Material for Lithium Ion Batteries

WEI Yi ^1, ,
WANG Li-Juan ¹ ,
YAN Ji ¹ ,
SHA Ou ¹ ,
TANG Zhi-Yuan ¹ ,
MA Li ²

1.
1. School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, P. R. China;
2. McNair Technology Company, Limited, Dongguan 523800, Guangdong Province, P. R. China

Received Date: 4 July 2011
Available Online: 13 September 2011
Fund Project: 国家自然科学基金(20973124)资助项目 (20973124)

As a new potential cathode material for lithium ion batteries, Li₂MnSiO₄/C was synthesized by a solution method. The thermal behavior of the precursor for Li₂MnSiO₄/C was measured by thermogravimetric (TG) analysis and the range of calcination temperatures from 600 to 800°C was determined. X-ray powder diffraction (XRD) patterns indicated that all the Li₂MnSiO₄/C samples crystallized in an orthorhombic structure with space group Pmn2₁. The morphology and particle size of the samples were also characterized by scanning electron microscopy (SEM). The effects of calcination temperature on the electrochemical performance of Li₂MnSiO₄/C were studied using galvanostatic charge-discharge measurements at various current densities. The results showed that the sample prepared at 700°C exhibited a much higher coulombic efficiency and better cyclic performance than the other samples.
- Lithium ion battery,
- Cathode material,
- Li₂MnSiO₄,
- Solution method,
- Calcination temperature
1. [1]
  (1) Padhi, A. K.; Nanjundaswamy, K. S.; odenough, J. B. J. Electrochem. Soc. 1997, 144, 1188.
2. [2]
  (2) Padhi, A. K.; Nanjundaswamy, K. S.; odenough, J. B. J. Electrochem. Soc. 1997, 144, 1609.
3. [3]
  (3) Padhi, A. K.; Nanjundaswamy, K. S.; Masquelier, C.; odenough, J. B. J. Electrochem. Soc. 1997, 144, 2581.
4. [4]
  (4) Arroyo-de Dompablo, M. E.; Armand, M.; Tarascon, J. M.; Amador, U. Electrochem. Commun. 2006, 8, 1292.
5. [5]
  (5) Zhou, F.; Cococcioni, M.; Kang, K.; Ceder, G. Electrochem. Commun. 2004, 6, 1144.
6. [6]
  (6) Nytén, A.; Abouimrane, A.; Armand, M. Electrochem. Commun. 2005, 7, 156.
7. [7]
  (7) Nytén, A.; Kamali, S.; Haggstrom, L.; Gustafsson, T.; Thomas, J. O. J. Mater. Chem. 2006, 16, 2266.
8. [8]
  (8) Islam, M. S; Dominko, R.; Masquelier, C.; Sirisopanaporn, C.; Armstrong, A. R.; Bruce, P. G. J. Mater. Chem. 2011, 21, 9811.
9. [9]
  (9) Zaghib, K.; Ait Salah, A.; Ravet, N.; Maguger, A.; Gendron, F.; Julien, C. M. J. Power Sources 2006, 160, 1381.
10. [10]
  (10) Dominko, R.; Conte, D. E.; Hanzel, D.; Gaberscek, M.; Jamnik, J. J. Power Sources 2008, 178, 842.
11. [11]
  (11) Yang, Y.; Fang, H. S.; L, L. P.; Yan, G. F.; Li, G. S. Rare Metals and Engineering 2008, 6, 1085.
12. [12]
  (12) Belharouak, I.; Abouimrane, A.; Amine, K. J. Phys. Chem. C 2009, 113, 20733.
13. [13]
  (13) Liu,W. G.; Xu, Y. H.; Yang, R. J. Alloy. Compd. 2009, 480, L1.
14. [14]
  (14) Dominko, R.; Bele, M.; Gaberscek, M.; Meden, A.; Remskar, M. J. Electrochem. Commun. 2006, 8, 217.
15. [15]
  (15) Dominko, R.; Bele, M.; Kokalj, A.; Gaberscek, M.; Jamnik, J. J. Power Sources 2007, 174, 457.
16. [16]
  (16) Dominko, R. J. Power Sources 2008, 184, 462.
17. [17]
  (17) Aravindan, V.; Ravi, S.; Kim,W. S.; Lee, S. Y.; Lee, Y. S. J. Colloid Interface Sci. 2011, 355, 472.
18. [18]
  (18) Liu,W. G.; Xu, Y. H.; Yang, R. Rare Metals 2010, 29, 511.
19. [19]
  (19) Guo, H. J.; Xiang, K. X.; Cao, X.; Li, X. H.;Wang, Z. X.; Li, L. M. Trans. Nonferrous Met. Soc. China 2009, 19, 169.
20. [20]
  (20) Kam, K. C.; Gustafsson, T.; Thomas, J. O. Solid State Ionics 2011, 192, 356.
21. [21]
  (21) Li, L. M.; Guo, H. J.; Li, X. H.;Wang, Z. X.; Peng,W. J.; Xiang, K. X.; Cao, X. J. Power Sources 2009, 189, 45.
22. [22]
  (22) Ohzuku, T.; Kitagawa, M.; Hirai, T. J. Electrochem. Soc. 1990, 137, 769.
23. [23]
  (23) Jang, D. H.; Shin, Y. J.; Oh, S. M. J. Electrochem. Soc. 1996, 143, 2204.
24. [24]
  (24) Muraliganth, T.; Stroukoff, K. R.; Manthiram, A. Chem. Mater. 2010, 22, 5754.
25. [25]
  (25) Li, Y. X.; ng, Z. L.; Yang, Y. J. Power Sources 2007, 174, 528.
26. [26]
  (26) Kokalj, A.; Dominko, R.; Mali, G.; Meden, A.; Gaberscek, M.; Jamnik, J. Chem. Mater. 2007, 19, 3633.
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Calcination Temperature Effects on the Electrochemical Performance of Li₂MnSiO₄/C Cathode Material for Lithium Ion Batteries