Citation: YIN Shi-Bin, LUO Lin, JING Sheng-Yu, ZHU Qiang-Qiang, QIANG Ying-Huai. Effect of Intermittent Microwave Heating on the Performance of Catalysts for Oxygen Reduction Reaction[J]. Acta Physico-Chimica Sinica, ;2012, 28(01): 85-89. doi: 10.3866/PKU.WHXB201111153 shu

Effect of Intermittent Microwave Heating on the Performance of Catalysts for Oxygen Reduction Reaction

1.
1. Low Carbon Energy Institute, China University of Mining and Technology, Xuzhou 221116, Jiangsu Province, P. R. China;
2. School of Materials Science and Engineering, China University of Mining and Technology, Xuzhou 221116, Jiangsu Province, P. R. China;
3. School of Information and Electrical Engineering, China University of Mining and Technology, Xuzhou 221116, Jiangsu Province, P. R. China

Received Date: 9 October 2011
Available Online: 15 November 2011
Fund Project: 国家自然科学基金(21106178) (21106178) 中国博士后基金(20110491480) (20110491480) 徐州市科技项目(XJ11B009) (XJ11B009) 徐州市多晶硅与光伏能源技术专项(6AT102092) (6AT102092)材料复合新技术国家重点实验室(武汉理工大学)开放基金(2012-KF-13) (武汉理工大学)开放基金(2012-KF-13)中国矿业大学青年基金(2011QNA21, 2009A026)资助 (2011QNA21, 2009A026)

The influence of intermittent microwave heating (IMH) on the physicochemical and electrochemical properties of platinum loaded on multi-walled carbon nanotubes (Pt/MWCNTs) was investigated. X-ray diffraction results revealed that the crystal size of Pt particles hardly increased for smaller numbers of pulse repetitions, but became much larger as the number of pulse repetitions increased. Cyclic voltammetry (CV) and rotating disk electrode (RDE) results showed that the Pt/MWCNTs catalysts prepared by IMH in a repeated pulse form of 5s-on/5s-off for 20 pulse repetitions possessed the largest electrochemical surface area. An onset potential of approximately 1.0 V (vs RHE) was observed for the oxygen reduction reaction in oxygen-saturated 0.5 mol·L^-1 H₂SO₄ aqueous solutions. The IMH method is simple, economical, and can potentially be scaled up for the mass production of nanomaterials.
- Catalyst,
- Intermittent microwave heating method,
- Rotating disk electrode,
- Oxygen reduction reaction,
- Multi-walled carbon nanotube
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