Citation: LI Bo. Investigation on Photocurrent Polarity of a Bulk Heterojunction Organic Photovoltaic Device Using a Ferroelectric Thin Film[J]. Acta Physico-Chimica Sinica, ;2012, 28(01): 217-222. doi: 10.3866/PKU.WHXB201111111 shu

Investigation on Photocurrent Polarity of a Bulk Heterojunction Organic Photovoltaic Device Using a Ferroelectric Thin Film

LI Bo

1.
Department of Applied Physics, College of Science, Zhejiang University of Technology, Hangzhou 310023, P. R. China

Received Date: 6 September 2011
Available Online: 11 November 2011
Fund Project: 国家自然科学基金(61008008)资助项目 (61008008)

The ferroelectric thin film of lead magnesium niobate-lead titanate (PMN-PT) was fabricated and characterized using UV-Vis transmission spectroscopy, X-ray diffraction (XRD), and atomic force microscopy (AFM). To determine the photocurrent properties of the bulk heterojunction organic blend film a photovoltaic device with the structure of tin indium oxide (ITO)/PMN-PT/organic blend film/aluminum (Al) was fabricated. Under modulated laser irradiation the amplitude and polarity of the transient photocurrent varied with the bias voltage, which shows that the photocurrent polarity of a conventional bulk heterojunction organic photovoltaic device is determined by the internal electric field that is induced by the difference between the work function of the anode and cathode electrodes. A new method is proposed for investigating the photocurrent properties of bulk heterojunction organic photovoltaic devices.
- Ferroelectric thin film,
- Organics,
- Photovoltaic device,
- Bulk heterojunction,
- Transient photocurrent,
- Lead magnesium niobate-lead titanate,
- Polarity
1. [1]
  (1) Kim, J. Y.; Lee, K.; Coates, N. E.; Moses, D.; Nguyen, T. Q.; Dante, M.; Heeger, A. J. Science 2007, 317, 222.
2. [2]
  (2) Peumans, P.; Uchida, S.; Forrest, S. R. Nature 2003, 425, 158.
3. [3]
  (3) Brabec, C. J.; Sariciftci, N. S.; Hummelen, J. C. Adv. Funct. Mater. 2001, 11, 15.
4. [4]
  (4) Zhuo, Z. L.; Zhang, F. J.; Xu, X.W.;Wang, J.; Lu, L. F.; Xu, Z. Acta Phys. -Chim. Sin. 2011, 27, 875. [卓祖亮, 张福俊, 许晓伟, 王健, 卢丽芳, 徐征. 物理化学学报, 2011, 27, 875.]
5. [5]
  (5) ng, X.; Tong, M. H.; Xia, Y. J.; Cai,W. Z.; Moon, J. S.; Cao, Y.; Yu, G.; Shieh, C. L.; Nilsson, B.; Heeger, A. J. Science 2009, 325, 1665.
6. [6]
  (6) Loser, S.; Bruns, C. J.; Miyauchi, H.; Ortiz, R. P.; Facchetti, A.; Stupp, S. I.; Marks, T. J. J. Am. Chem. Soc. 2011, 133, 8142.
7. [7]
  (7) Zhao, G. J.; He, Y. J.; Li, Y. F. Adv. Mater. 2010, 22, 4355.
8. [8]
  (8) Scharber, M. C.; Mühlbacher, D.; Koppe, M.; Denk, P.; Waldauf, C.; Heeger, A. J.; Brabec, C. J. Adv. Mater. 2006, 18, 789.
9. [9]
  (9) Seo, J. H.; Gutacker, A.; Sun, Y. M.;Wu, H. B.; Huang, F.; Cao, Y.; Scherf, U.; Heeger, A. J.; Bazan, G. C. J. Am. Chem. Soc. 2011, 133, 8416.
10. [10]
  (10) Coakley, K. M.; McGehee, M. D. Chem. Mater. 2004, 16, 4533.
11. [11]
  (11) Günes, S.; Neugebauer, H.; Sariciftci, N. S. Chem. Rev. 2007, 107, 1324.
12. [12]
  (12) Helgesen, M.; Søndergaard, R.; Krebs, F. C. J. Mater. Chem. 2010, 20, 36.
13. [13]
  (13) Thompson, B. C.; Fréchet, J. M. J. Angew. Chem. Int. Edit. 2008, 47, 58
14. [14]
  (14) Dennler, G.; Scharber, M. C.; Brabec, C. J. Adv. Mater. 2009, 21, 1323.
15. [15]
  (15) Sommer, M.; Huettner, S.; Thelakkat, M. J. Mater. Chem. 2010, 20, 10788.
16. [16]
  (16) Tanaka, S.; Hanada, T.; Ono, K.;Watanabe, K.; Yoshino, K.; Hiromitsu, I. Appl. Phys. Lett. 2010, 97, 253306.
17. [17]
  (17) Tanaka, H.; Yasuda, T.; Fujita, K.; Tsutsui, T. Appl. Phys. Lett. 2006, 88, 253506.
18. [18]
  (18) Zhang, F.; Sun, F.; Shi, Y.; Zhuo, Z.; Lu, L.; Zhao, D.; Xu, Z.; Wang, Y. Energ. Fuel. 2010, 24, 3739.
19. [19]
  (19) Zhang, F. J.; Zhao, D.W.; Zhuo, Z.L.;Wang, H.; Xu, Z.;Wang, Y. S. Sol. Energ. Mat. Sol. C 2010, 94, 2416.
20. [20]
  (20) Hoppe, H.; Sariciftci, N. S. J. Mater. Res. 2004, 19, 1924.
21. [21]
  (21) Gebeyehu, D.; Maennig, B.; Drechsel, J.; Leo, K.; Pfeiffer, M. Sol. Energ. Mat. Sol. C 2003, 79, 81.
22. [22]
  (22) Wongmaneerung, R.; Yimnirun, R.; Ananta, S. J. Mater. Sci. 2009, 44, 5428.
23. [23]
  (23) Zawilski, K. T.; Custodio, M. C. C.; Demattei, R. C.; Lee, S. G.; Monteiro, R. G.; Odagawa, H.; Feigelson, R. S. J. Cryst. Growth 2003, 258, 353.
24. [24]
  (24) Chen, J.; Fan, H. Q.; Ke, S. M.; Chen, X. L.; Yang, C.; Fang, P. Y. J. Alloy. Compd. 2009, 478, 853.
25. [25]
  (25) Kumar, P.; Thakur, O. P.; Prakash, C.; el, T. C. Physica B 2005, 357, 241.
26. [26]
  (26) Zhang, D. J.; Yao, X. Acta Phys. -Chim. Sin. 2004, 20, 712. [张栋杰, 姚熹. 物理化学学报, 2004, 20, 712.]
27. [27]
  (27) Choi, S.W.; Shrout, T. R.; Jang, S. J.; Bhalla, A. S. Ferroelectrics 1989, 100, 29.
28. [28]
  (28) Wu, A. Y.; Vilarinho, P. M.; Kholkin, A. J. Am. Ceram. Soc. 2007, 90, 1029.
29. [29]
  (29) Yu, B.; Huang, L. Z.;Wang, H. B.; Yan, D. H. Adv. Mater. 2010, 22, 1017.
30. [30]
  (30) Zeng,W. J.; Yong, K. S.; Kam, Z. M.; Zhu, F. R.; Li, Y. N. Appl. Phys. Lett. 2010, 97, 133304.
31. [31]
  (31) Park, J. H.; Xu, F.; Trolier-McKinstry, S. J. Appl. Phys. 2001, 89, 568.
32. [32]
  (32) Kumar, P.; Sonia; Patel, R. K.; Prakash, C.; el, T. C. Mater. Chem. Phys. 2008, 110, 7.
33. [33]
  (33) Feng, M.;Wang,W.; Ke, H.; Rao, J. C.; Zhou, Y. J. Alloy. Compd. 2010, 495, 154.
1. [1]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . 钛酸铋/氮化碳无机有机复合S型异质结纯水光催化产过氧化氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-. doi: 10.3866/PKU.WHXB202403009
2. [2]
  Bao Jia , Yunzhe Ke , Shiyue Sun , Dongxue Yu , Ying Liu , Shuaishuai Ding . Innovative Experimental Teaching for the Preparation and Modification of Conductive Organic Polymer Thin Films in Undergraduate Courses. University Chemistry, 2024, 39(10): 271-282. doi: 10.12461/PKU.DXHX202404121
3. [3]
  Liang TANG , Jingfei NI , Kang XIAO , Xiangmei LIU . Synthesis and X-ray imaging application of lanthanide-organic complex-based scintillators. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1892-1902. doi: 10.11862/CJIC.20240139
4. [4]
  Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
5. [5]
  Baohua LÜ , Yuzhen LI . Anisotropic photoresponse of two-dimensional layered α-In₂Se₃(2H) ferroelectric materials. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1911-1918. doi: 10.11862/CJIC.20240105
6. [6]
  Ming ZHENG , Yixiao ZHANG , Jian YANG , Pengfei GUAN , Xiudong LI . Energy storage and photoluminescence properties of Sm³⁺-doped Ba_0.85Ca_0.15Ti_0.90Zr_0.10O₃ lead-free multifunctional ferroelectric ceramics. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 686-692. doi: 10.11862/CJIC.20230388
7. [7]
  Shicheng Yan . Experimental Teaching Design for the Integration of Scientific Research and Teaching: A Case Study on Organic Electrooxidation. University Chemistry, 2024, 39(11): 350-358. doi: 10.12461/PKU.DXHX202408036
8. [8]
  Xinyuan Shi , Chenyangjiang , Changyu Zhai , Xuemei Lu , Jia Li , Zhu Mao . Preparation and Photoelectric Performance Characterization of Perovskite CsPbBr₃ Thin Films. University Chemistry, 2024, 39(6): 383-389. doi: 10.3866/PKU.DXHX202312019
9. [9]
  Cheng PENG , Jianwei WEI , Yating CHEN , Nan HU , Hui ZENG . First principles investigation about interference effects of electronic and optical properties of inorganic and lead-free perovskite Cs₃Bi₂X₉ (X=Cl, Br, I). Chinese Journal of Inorganic Chemistry, 2024, 40(3): 555-560. doi: 10.11862/CJIC.20230282
10. [10]
  Wendian XIE , Yuehua LONG , Jianyang XIE , Liqun XING , Shixiong SHE , Yan YANG , Zhihao HUANG . Preparation and ion separation performance of oligoether chains enriched covalent organic framework membrane. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1528-1536. doi: 10.11862/CJIC.20240050
11. [11]
  Jizhou Liu , Chenbin Ai , Chenrui Hu , Bei Cheng , Jianjun Zhang . 六氯锡酸铵促进钙钛矿太阳能电池界面电子转移及其飞秒瞬态吸收光谱研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2402006-. doi: 10.3866/PKU.WHXB202402006
12. [12]
  Changjun You , Chunchun Wang , Mingjie Cai , Yanping Liu , Baikang Zhu , Shijie Li . 引入内建电场强化BiOBr/C₃N₅ S型异质结中光载流子分离以实现高效催化降解微污染物. Acta Physico-Chimica Sinica, 2024, 40(11): 2407014-. doi: 10.3866/PKU.WHXB202407014
13. [13]
  Yukun Chang , Haoqin Huang , Baolei Wang . Preparation of Trans-Cinnamic Acid via “One-Pot” Protocol of Aldol Condensation-Hydrolysis Reaction: Recommending an Improved Organic Synthesis Experiment. University Chemistry, 2024, 39(4): 322-328. doi: 10.3866/PKU.DXHX202309095
14. [14]
  Yuan Zheng , Quan Lan , Zhenggen Zha , Lingling Li , Jun Jiang , Pingping Zhu . Teaching Reform of Organic Synthesis Experiments by Introducing Reverse Thinking and Design Concepts: Taking the Synthesis of Cinnamic Acid Based on Retrosynthetic Analysis as an Example. University Chemistry, 2024, 39(6): 207-213. doi: 10.3866/PKU.DXHX202310065
15. [15]
  Tianyun Chen , Ruilin Xiao , Xinsheng Gu , Yunyi Shao , Qiujun Lu . Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes. University Chemistry, 2024, 39(5): 363-370. doi: 10.3866/PKU.DXHX202312017
16. [16]
  Yujia LI , Tianyu WANG , Fuxue WANG , Chongchen WANG . Direct Z-scheme MIL-100(Fe)/BiOBr heterojunctions: Construction and photo-Fenton degradation for sulfamethoxazole. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 481-495. doi: 10.11862/CJIC.20230314
17. [17]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
18. [18]
  Kexin Dong , Chuqi Shen , Ruyu Yan , Yanping Liu , Chunqiang Zhuang , Shijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag₃PO₄/C₃N₅ Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-. doi: 10.3866/PKU.WHXB202310013
19. [19]
  You Wu , Chang Cheng , Kezhen Qi , Bei Cheng , Jianjun Zhang , Jiaguo Yu , Liuyang Zhang . ZnO/D-A共轭聚合物S型异质结高效光催化产H₂O₂及其电荷转移动力学研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406027-. doi: 10.3866/PKU.WHXB202406027
20. [20]
  Jiaxing Cai , Wendi Xu , Haoqiang Chi , Qian Liu , Wa Gao , Li Shi , Jingxiang Low , Zhigang Zou , Yong Zhou . 具有0D/2D界面的InOOH/ZnIn₂S₄空心球S型异质结用于增强光催化CO₂转化性能. Acta Physico-Chimica Sinica, 2024, 40(11): 2407002-. doi: 10.3866/PKU.WHXB202407002

Get Citation

PDF

XML

Metrics

PDF Downloads(897)
Abstract views(2439)
HTML views(6)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142