Citation: LI Bo. Investigation on Photocurrent Polarity of a Bulk Heterojunction Organic Photovoltaic Device Using a Ferroelectric Thin Film[J]. Acta Physico-Chimica Sinica, ;2012, 28(01): 217-222. doi: 10.3866/PKU.WHXB201111111 shu

Investigation on Photocurrent Polarity of a Bulk Heterojunction Organic Photovoltaic Device Using a Ferroelectric Thin Film

LI Bo

1.
Department of Applied Physics, College of Science, Zhejiang University of Technology, Hangzhou 310023, P. R. China

Received Date: 6 September 2011
Available Online: 11 November 2011
Fund Project: 国家自然科学基金(61008008)资助项目 (61008008)

The ferroelectric thin film of lead magnesium niobate-lead titanate (PMN-PT) was fabricated and characterized using UV-Vis transmission spectroscopy, X-ray diffraction (XRD), and atomic force microscopy (AFM). To determine the photocurrent properties of the bulk heterojunction organic blend film a photovoltaic device with the structure of tin indium oxide (ITO)/PMN-PT/organic blend film/aluminum (Al) was fabricated. Under modulated laser irradiation the amplitude and polarity of the transient photocurrent varied with the bias voltage, which shows that the photocurrent polarity of a conventional bulk heterojunction organic photovoltaic device is determined by the internal electric field that is induced by the difference between the work function of the anode and cathode electrodes. A new method is proposed for investigating the photocurrent properties of bulk heterojunction organic photovoltaic devices.
- Ferroelectric thin film,
- Organics,
- Photovoltaic device,
- Bulk heterojunction,
- Transient photocurrent,
- Lead magnesium niobate-lead titanate,
- Polarity
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