Citation: YU Hong-Bo, PU Zhi-Ying, WANG Yue-Juan, LU Ji-Qing, TENG Bo-Tao, LUO Meng-Fei. Preparation and Application of a Cr₂O₃-α-AlF₃ Catalyst with a High Specific Surface Area[J]. Acta Physico-Chimica Sinica, ;2011, 27(11): 2677-2681. doi: 10.3866/PKU.WHXB20111014 shu

Preparation and Application of a Cr₂O₃-α-AlF₃ Catalyst with a High Specific Surface Area

YU Hong-Bo ¹ ,
¹ ,
PU Zhi-Ying ² ,
WANG Yue-Juan ¹ ,
LU Ji-Qing ¹ ,
TENG Bo-Tao ¹ ,
LUO Meng-Fei ^1,

1.
1. Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua 321004, Zhejiang Province, P. R. China;
2. Research Center of Analysis and Measurement, Zhejiang University of Technology, Hangzhou 310014, Zhejiang Province, P. R. China

Received Date: 28 June 2011
Available Online: 18 August 2011
Fund Project: 浙江省自然科学基金(Y4100001) (Y4100001)浙江省科技计划(2009F70004, 2009R50020-6)资助项目 (2009F70004, 2009R50020-6)

A high specific surface area Cr₂O₃-α-AlF₃ catalyst was prepared using a carbon hard template method. The synthesis procedure consisted of three consecutive steps: (1) the impregnation of a sucrose (C₁₂H₂₂O₁₁) aqueous solution with Cr₂O₃-γ-Al₂O₃ and subsequent thermal treatment; (2) the thermal treatment of the obtained solid with HF, C@Cr₂O₃-γ-Al₂O₃ can be completely transformed into C@Cr₂O₃-γ-AlF₃ at 400°C with hydrogen fluoride; (3) the removal of the carbon template in C@Cr₂O₃-γ- AlF₃ upon high temperature combustion giving the high surface area Cr₂O₃-γ-AlF₃ (115 m²·g^-1). The catalysts were characterized by X-ray diffraction (XRD), N₂ physisorption, ammonia temperatureprogrammed desorption (NH₃-TPD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), and energy dispersion X-ray (EDX) techniques. We found that the fluorination process was crucial for the resulting Cr₂O₃-α-AlF₃ with a high specific surface area of 115 m²·g^-1 under optimal conditions. The Cr₂O₃-α-AlF₃ catalyst with a high specific surface area was more active for the decomposition of 1,1-difluoroethane than the catalyst prepared by the direct fluorination of Cr₂O₃-γ-Al₂O₃, because it contained a higher amount of acid sites.
- Cr₂O₃-&,
- alpha,
- -AlF₃,
- High specific surface area,
- Lewis acid,
- CH₃CHF₂ decomposition,
- X-ray diffraction
1. [1]
  (1) Lu, J.; Yang, H. E.; Chen, S. K.; Shi, L.; Ren, J. G.; Li, H. L.; Peng, S. K. Catal. Lett. 1996, 41, 221.
2. [2]
  (2) Kemnitz, E.; Kohne, A.; Grohmann, I.; Lippitz, A.; Unger,W. E.S. J. Catal. 1996, 159, 270.
3. [3]
  (3) Jang, H. J.; Kim, D. H.; Kim, C. H.; Cho, Y. G.; Lee, J. E.; Iikubo, Y. Catalyst for Preparation of Pentafluoroethane andPreparation Method Thereof. US Pat. Appl. 7232789, 2007.
4. [4]
  (4) Tung, H. S.; Smith, A. M.; Swain, C. F. Single Stage Process forProducing Hydrofluorocarbons from Perchloroethylene. US Pat.5545778, 1996.
5. [5]
  (5) Kim, H.; Kim, H. S.; Lee, B. G.; Kwon, Y. S.; Park, K.Y. J. Ind. Eng. Chem. 1997, 3, 203.
6. [6]
  (6) Tachuikow-Roux, E.; Quiring,W. J.; Simmie, J. M. J. Phys. Chem. 1970, 74, 2449.
7. [7]
  (7) Lee, H.; Kim, H. S.; Kim, H.; Jeong,W. S.; Seo, I. J. Mol. Catal. A: Chem. 1998, 136, 85.
8. [8]
  (8) Lu, J.; Shi, L.; Yang, H. E.; Chen, S. K.; Ren, J. G.; Li, H. L.; Peng, S. Y. Chin. J. Catal. 1996, 17, 459.
9. [9]
  (9) Cuzzato, P.; Veneto, P. Catalyst for the Fluorination ofHalogenated Organic Compounds. US Pat. 6300530, 2001.
10. [10]
  (10) Lu, J.; Quan, H. D.; Li, H. F.; Yang, H. E.; Wang, Z. Y.; Li, Z.; Shi, L.; Qu, H. X.; Zhao, Z. X.; Li, J.; Hao, Z. Z.; Li, H. L.Catalyst for Fluoreation of Halogenated Hydrocarbon. CNPatent 11 452 75.1, 1997-03-19.
11. [11]
  [吕剑, 权恒道, 李惠芳, 杨会娥, 王振宇, 李忠, 石磊, 屈宏翔, 赵智霞, 李杰, 郝仲璋, 李惠黎. 氟化卤代烃的氟化催化剂: 中国, CN11 452 75.1
12. [12]
  [P]. 1997-03-19.]
13. [13]
  (11) Daniel, P.; Bulou, A.; Rousseau, M.; Nouet, J.; Fourquet, J. L.; Leblanc, M.; Burriel, R. J. Phys.: Condens. Matter 1990, 2,5663.
14. [14]
  (12) Fourquet, J. L.; Rivie`re, M.; Bail, A. L.; Nygrens, M.; Grins, J.Eur. J. Solid State Inorg. Chem. 1988, 25, 535.
15. [15]
  (13) Bail, A. L.; Jacoboni, C.; Leblanc, M.; De Pape, R.; Duroy, H.; Fourquet, J. L. J. Solid State Chem. 1988, 77, 96.
16. [16]
  (14) Herron, N.; Thorn, D. L.; Harlow, R. L.; Jones, G. A.; Parise, J.B.; Fernandez-Baca, J. A.; Vogt, T. Chem. Mater. 1995, 7, 75.
17. [17]
  (15) Bail, A. L.; Fourquet, J. L.; Bentrup, U. J. Solid State Chem.1992, 100, 151.
18. [18]
  (16) Ravez, J.; Mogus-Milankovic, A.; Chaminade, J. P.; Hagenmuller, P. Mater. Res. Bull. 1984, 19, 1311.
19. [19]
  (17) Kemnitz, E.; Gross, U.; Rüdiger, S.; Shekar, S. C. Angew. Chem. Int. Edit. 2003, 42, 4251.
20. [20]
  (18) Ruediger, S. K.; Gross, U.; Feist, M.; Prescott, H. A.; Shekar, S.C.; Troyanov, S. I.; Kemnitz, E. J. Mater. Chem. 2005, 15, 588.
21. [21]
  (19) Adamczyk, B.; Boese, O.; Weiher, N.; Schroeder, S. L. M.; Kemnitz, E. J. Fluorine. Chem. 2000, 101, 239.
22. [22]
  (20) Yim, S. D.; Nam, I. S. J. Catal. 2004, 221, 601.
23. [23]
  (21) Dambournet, D.; Eltanamy, G.; Vimont, A.; Lavalley, J. C.; upil, J. M.; Demourgues, A.; Durand, E.; Majimel, J.; Rudiger, S.; Kemnitz, E.; Winfield, J. M.; Tressaud, A. Chem. Eur. J. 2008, 14, 6205.
24. [24]
  (22) Alonso, C.; Morato, A.; Medina, F.; Guirado, F.; Cesteros, Y.; Salagre, P.; Sueiras, J. E. Chem. Mater. 2000, 12, 1148.
25. [25]
  (23) Alonso, C.; Morato, A.; Medina, F.; Cesteros, Y.; Salagre, P.; Sueiras, J. E. Appl. Catal. B: Environ. 2003, 40, 259.
26. [26]
  (24) Scholz, G.; Koenig, R.; Petersen, J.; Angelow, B.; Dorfel, I.; Kemnitz, E. Chem. Mater. 2008, 20, 5406.
27. [27]
  (25) Li, G. L.; Nishiguchi, H.; Ishihara, T.; Moro-oka, Y.; Takita, Y.Appl. Catal. B: Environ. 1998, 16, 309.
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Preparation and Application of a Cr2O3-α-AlF3 Catalyst with a High Specific Surface Area

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Preparation and Application of a Cr₂O₃-α-AlF₃ Catalyst with a High Specific Surface Area