Citation: DU Xiao-Qing, LI Hui-Qin, ZHU Qi-Rong, ZOU Zhi-Qiang, LIANG Qi. Growth and Nanotribological Properties of C₆₀ Multilayer Films on Si(111)-7×7 Surface[J]. Acta Physico-Chimica Sinica, ;2011, 27(10): 2457-2461. doi: 10.3866/PKU.WHXB20111010 shu

Growth and Nanotribological Properties of C₆₀ Multilayer Films on Si(111)-7×7 Surface

DU Xiao-Qing ^1,2 ,
LI Hui-Qin ² ,
ZHU Qi-Rong ² ,
ZOU Zhi-Qiang ² ,
LIANG Qi ^1,2,

1.
1. Department of Physics, Shanghai Jiao Tong University, Shanghai 200240, P. R. China;
2. Instrumental Analysis Center, Shanghai Jiao Tong University, Shanghai 200240, P. R. China

Received Date: 27 June 2011
Available Online: 17 August 2011
Fund Project: 国家自然科学基金(10974134)资助项目 (10974134)

C₆₀ layer by layer films without clusters were obtained on Si(111)-7×7 reconstructed surface by controlling parameters such as the evaporation speed and the temperature of substrate during the growth process. The experiments were carried out under ultra-high vacuum (UHV) using molecular beam epitaxy (MBE). These films were observed by ultra-high vacuum scanning tunneling microscopy (UHV-STM) and the mechanism of this phenomenon was analyzed. The adhesion and frictional force curves of these C₆₀ films with different layers were measured. Their frictional properties were found to be affected by the number of layers. The frictional force decreased obviously with the increase in layers and the frictional coefficient also showed a downward tendency. Our simulation showed that adhesion was not the main effect that led to a decrease in the frictional force. Since the increase of layers leads to a higher level of rotation for C₆₀ molecules, we conclude that the decrease in the frictional force is caused by the rotation of the C₆₀ molecules. C₆₀ molecule acts as"nano rolling bearing"here. That is, the rotation of the C₆₀ molecules provides a channel for energy dissipation in the microstructure. These kinds of multilayer films make it possible for us to study the relationship between the rotation of C₆₀ molecule and its other properties.
- Fullerene,
- Molecular beam epitaxy,
- Film growth,
- Nanotribological property,
- Scanning tunneling microscopy
1. [1]
  (1) Kroto, H. S.; Heath, J. R.; O'Brian, S. C.; Curl, R. F.; Smalley, R. E. Nature 1985, 318, 162.
2. [2]
  (2) Kratschmer,W.; Lamb, L. D.; Fostiropoulos, K.; Huffman, D. R. Nature 1990, 347, 354.
3. [3]
  (3) Chen, D. M.; Xu, H.; Creager,W. N.; Burnett, P. J. Vac. Sci. Technol. B 1994, 12, 1910.
4. [4]
  (4) Cepek, C.; Schiavuta, P.; Sancrotti, M.; Pedio, M. Phys. Rev. B 1999, 60, 2068.
5. [5]
  (5) Sakamoto, K.; Kondo, D.; Ushimi, Y.; Harada, M.; Kimura, A.; Kakizaki, A.; Suto, S. Phys. Rev. B 1999, 60, 2579.
6. [6]
  (6) Suto, S.; Sakamoto, K.; Kondo, D.;Wakita, T.; Kimura, A.; Kakizaki, A.; Hu, C.W.; Kasuya, A. Surf. Sci. 1999, 438, 242.
7. [7]
  (7) Sakamoto, K.; Kondo, D.; Ushimi, Y.; Kimura, A.; Kakizaki, A.; Suto, S. Surf. Sci. 1999, 438, 248.
8. [8]
  (8) Sakamoto, K.;Wakita, T.; Kondo, D.; Harasawa, A.; Kinoshita, T.; Uchida,W.; Kasuvya, A. Surf. Sci. 2002, 499, 63.
9. [9]
  (9) Ulbricht, H.; Moos, G.; Hertel, T. Phys. Rev. Lett. 2003, 90, 095501.
10. [10]
  (10) Nakaya, M.; Nakayama, T.; Kuwahara, Y.; Aono, M. Surf. Sci. 2006, 600, 2810.
11. [11]
  (11) Feng, M.; Zhao, J.; Petek, H. Science 2008, 320, 359.
12. [12]
  (12) Li, Y. Z.; Chander, M.; Patrin, J. C.;Weaver, J. H.; Chibante, L. P. F.; Smalley, R. E. Science 1991, 252, 547.
13. [13]
  (13) Li, Y. Z.; Chander, M.; Patrin, J. C.;Weaver, J. H.; Chibante, L. P. F.; Smalley, R. E. Science 1991, 253, 429.
14. [14]
  (14) Chen, D.; Sarid, D. Phys. Rev. B 1994, 49, 7612.
15. [15]
  (15) Sakamoto, K.; Harada, M.; Kondo, D.; Kimura, A.; Suto, S. Phys. Rev. B 1998, 58, 13951.
16. [16]
  (16) Park, S. H.; Jeong, J. G.; Kim, H. J.; Park, S. H.; Cho, M. H.; Cho, S.W.; Yi, Y.; Heo. M. Y.; Sohn, H. Appl. Phys. Lett. 2010, 96, 013302.
17. [17]
  (17) Brommer, K. D.; Needels, M.; Larson, B.; Joannopoulos, J. D. Phys. Rev. Lett. 1992, 68, 1355.
18. [18]
  (18) Tsuyoshi, Y. J. Vac. Sci. Technol. B 1994, 12, 1932.
19. [19]
  (19) Suto, S.; Sakamoto, K.;Wakita, T.; Harada, M.; Kasuya, A. Surf. Sci. 1998, 402-404, 523.
20. [20]
  (20) Lee, J. Y.; Kang, M. H. Surf. Sci. 2008, 602, 1408.
21. [21]
  (21) Sakamoto, K.; Kondo, D.; Ohno, K.; Kimura, A.; Kakizaki, A.; Suto, S.; Uchida,W.; Kasuya, A. J. Appl. Phys. 2000, 39, 4536.
22. [22]
  (22) Levinson, J. A.; Hamza, A. V.; Shaqfeh, E. S. G.; Balooch, M. J. Vac. Sci. Technol. A 1998, 16, 2385.
23. [23]
  (23) Xu, H.; Chen, D. M.; Creager,W. N. Phys. Rev. Lett. 1993, 70, 1850.
24. [24]
  (24) Johnson, R. D.; Yannoni, C. S.; Meijer, G.; Dorn, H. C.; Salem, J. R.; Bethune, D. S. Science 1992, 255, 1235.
25. [25]
  (25) Chen, D.; Sarid, D. Surf. Sci. 1994, 318, 74.
26. [26]
  (26) Liang, Q.; Li, H. N.; Xu, Y. B.; Xiao, X. D. J. Phys. Chem. B 2006, 110, 403
27. [27]
  (27) Johnson, K. L.; Kendall, K. K.; Roberts, A. D. Proc. R. Soc. London Sect. A 1971, 324, 301
1. [1]
  Wenjiang LI , Pingli GUAN , Rui YU , Yuansheng CHENG , Xianwen WEI . C₆₀-MoP-C nanoflowers van der Waals heterojunctions and its electrocatalytic hydrogen evolution performance. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 771-781. doi: 10.11862/CJIC.20230289
2. [2]
  Mengfei He , Chao Chen , Yue Tang , Si Meng , Zunfa Wang , Liyu Wang , Jiabao Xing , Xinyu Zhang , Jiahui Huang , Jiangbo Lu , Hongmei Jing , Xiangyu Liu , Hua Xu . Epitaxial Growth of Nonlayered 2D MnTe Nanosheets with Thickness-Tunable Conduction for p-Type Field Effect Transistor and Superior Contact Electrode. Acta Physico-Chimica Sinica, 2025, 41(2): 100016-. doi: 10.3866/PKU.WHXB202310029
3. [3]
  Hongyun Liu , Jiarun Li , Xinyi Li , Zhe Liu , Jiaxuan Li , Cong Xiao . Course Ideological and Political Design of a Comprehensive Chemistry Experiment: Constructing a Visual Molecular Logic System Based on Intelligent Hydrogel Film Electrodes. University Chemistry, 2024, 39(2): 227-233. doi: 10.3866/PKU.DXHX202309070
4. [4]
  Qin Li , Huihui Zhang , Huajun Gu , Yuanyuan Cui , Ruihua Gao , Wei-Lin Dai . In situ Growth of Cd_0.5Zn_0.5S Nanorods on Ti₃C₂ MXene Nanosheet for Efficient Visible-Light-Driven Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2025, 41(4): 100031-. doi: 10.3866/PKU.WHXB202402016
5. [5]
  Rui Gao , Ying Zhou , Yifan Hu , Siyuan Chen , Shouhong Xu , Qianfu Luo , Wenqing Zhang . Design, Synthesis and Performance Experiment of Novel Photoswitchable Hybrid Tetraarylethenes. University Chemistry, 2024, 39(5): 125-133. doi: 10.3866/PKU.DXHX202310050
6. [6]
  Xiao SANG , Qi LIU , Jianping LANG . Synthesis, structure, and fluorescence properties of Zn(Ⅱ) coordination polymers containing tetra-alkenylpyridine ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2124-2132. doi: 10.11862/CJIC.20240158
7. [7]
  Jingwen Wang , Minghao Wu , Xing Zuo , Yaofeng Yuan , Yahao Wang , Xiaoshun Zhou , Jianfeng Yan . Advances in the Application of Electrochemical Regulation in Investigating the Electron Transport Properties of Single-Molecule Junctions. University Chemistry, 2025, 40(3): 291-301. doi: 10.12461/PKU.DXHX202406023
8. [8]
  Guoqiang Chen , Zixuan Zheng , Wei Zhong , Guohong Wang , Xinhe Wu . 熔融中间体运输导向合成富氨基g-C₃N₄纳米片用于高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406021-. doi: 10.3866/PKU.WHXB202406021
9. [9]
  Pengyang FAN , Shan FAN , Qinjin DAI , Xiaoying ZHENG , Wei DONG , Mengxue WANG , Xiaoxiao HUANG , Yong ZHANG . Preparation and performance of rich 1T-MoS₂ nanosheets for high-performance aqueous zinc ion battery cathode materials. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 675-682. doi: 10.11862/CJIC.20240339
10. [10]
  Zhiwen HUANG , Qi LIU , Jianping LANG . W/Cu/S cluster-based supramolecular macrocycles and their third-order nonlinear optical responses. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 79-87. doi: 10.11862/CJIC.20240184
11. [11]
  Peng ZHOU , Xiao CAI , Qingxiang MA , Xu LIU . Effects of Cu doping on the structure and optical properties of Au₁₁(dppf)₄Cl₂ nanocluster. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1254-1260. doi: 10.11862/CJIC.20240047
12. [12]
  Laiying Zhang , Yinghuan Wu , Yazi Yu , Yecheng Xu , Haojie Zhang , Weitai Wu . Innovation and Practice of Polymer Chemistry Experiment Teaching for Non-Polymer Major Students of Chemistry: Taking the Synthesis, Solution Property, Optical Performance and Application of Thermo-Sensitive Polymers as an Example. University Chemistry, 2024, 39(4): 213-220. doi: 10.3866/PKU.DXHX202310126
13. [13]
  Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169
14. [14]
  Huan LI , Shengyan WANG , Long Zhang , Yue CAO , Xiaohan YANG , Ziliang WANG , Wenjuan ZHU , Wenlei ZHU , Yang ZHOU . Growth mechanisms and application potentials of magic-size clusters of groups Ⅱ-Ⅵ semiconductors. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1425-1441. doi: 10.11862/CJIC.20240088
15. [15]
  Xinyuan Shi , Chenyangjiang , Changyu Zhai , Xuemei Lu , Jia Li , Zhu Mao . Preparation and Photoelectric Performance Characterization of Perovskite CsPbBr₃ Thin Films. University Chemistry, 2024, 39(6): 383-389. doi: 10.3866/PKU.DXHX202312019
16. [16]
  Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1079-1087. doi: 10.11862/CJIC.20240036
17. [17]
  Wendian XIE , Yuehua LONG , Jianyang XIE , Liqun XING , Shixiong SHE , Yan YANG , Zhihao HUANG . Preparation and ion separation performance of oligoether chains enriched covalent organic framework membrane. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1528-1536. doi: 10.11862/CJIC.20240050
18. [18]
  Bao Jia , Yunzhe Ke , Shiyue Sun , Dongxue Yu , Ying Liu , Shuaishuai Ding . Innovative Experimental Teaching for the Preparation and Modification of Conductive Organic Polymer Thin Films in Undergraduate Courses. University Chemistry, 2024, 39(10): 271-282. doi: 10.12461/PKU.DXHX202404121
19. [19]
  Xinyu ZENG , Guhua TANG , Jianming OUYANG . Inhibitory effect of Desmodium styracifolium polysaccharides with different content of carboxyl groups on the growth, aggregation and cell adhesion of calcium oxalate crystals. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1563-1576. doi: 10.11862/CJIC.20230374
20. [20]
  Jiaxin Su , Jiaqi Zhang , Shuming Chai , Yankun Wang , Sibo Wang , Yuanxing Fang . Optimizing Poly(heptazine imide) Photoanodes Using Binary Molten Salt Synthesis for Water Oxidation Reaction. Acta Physico-Chimica Sinica, 2024, 40(12): 2408012-. doi: 10.3866/PKU.WHXB202408012

Get Citation

PDF

XML

Metrics

PDF Downloads(942)
Abstract views(1939)
HTML views(4)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Growth and Nanotribological Properties of C60 Multilayer Films on Si(111)-7×7 Surface

Metrics

通讯作者: 陈斌, bchen63@163.com

Growth and Nanotribological Properties of C₆₀ Multilayer Films on Si(111)-7×7 Surface