Citation: WANG Cai-Cai, LI Jian-Hui, SUN Yi-Fei, ZHU Xiao-Quan, HUANG Chuan-Jing, WENG Wei-Zheng, WAN Hui-Lin. Synthesis and Catalytic Performances of Mesoporous CeNiO Catalysts for the Oxidative Dehydrogenation of Propane to Propene[J]. Acta Physico-Chimica Sinica, ;2011, 27(10): 2421-2426. doi: 10.3866/PKU.WHXB20110932 shu

Synthesis and Catalytic Performances of Mesoporous CeNiO Catalysts for the Oxidative Dehydrogenation of Propane to Propene

1.
State Key Laboratory of Physical Chemistry of Solid Surfaces, National Engineering Laboratory for Green Chemical Productions of Alcohols, Ethers and Esters, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian Province, P. R. China

Received Date: 2 June 2011
Available Online: 27 July 2011
Fund Project: 国家重点基础研究发展规划项目(973) (2010CB732300) (973) (2010CB732300) 国家自然科学基金(21073148, 21033006, 20803060) (21073148, 21033006, 20803060)福建省自然科学基金(2009J01038)资助 (2009J01038)

Mesoporous NiO and CeNiO catalysts were prepared by homogeneous precipitation using sodium dodecyl sulfate (SDS) mixed with triblock copolymer P123 as a template and urea as a hydrolysiscontrolling agent. The prepared catalysts were evaluated for the oxidative dehydrogenation of propane (ODP) to propene and the structure and properties of the catalysts were characterized by N₂ adsorptiondesorption, transmission electron microscopy (TEM), powder X-ray diffraction (XRD), and H₂ temperatureprogrammed reduction (H₂-TPR). The results showed that between 400 and 450°C, the NiO and CeNiO catalysts exhibited similar catalytic behavior for the ODP reaction but at low temperatures (<400°C) the catalysts doped with Ce had higher catalytic activity. On NiO only a 3.1% propene yield was obtained at 325°C while the yield on 5CeNiO (n_Ce/n_Ni=5%) was as high as 12.2% at the same temperature. The results of N₂ adsorption-desorption and TEM indicated that both the prepared NiO and CeNiO catalysts possessed a high surface area and a wormhole-like mesostructure. The H₂-TPR results revealed that part of the oxygen species became more reducible because of the presence of Ce in CeNiO, which may be the main reason for the higher activities of the catalysts.
- Propane,
- Oxidative dehydrogenation,
- Propene,
- Mesoporous CeNiO catalyst
1. [1]
  (1) Cavani, F.; Ballarini, N.; Cericola, A. Catal. Today 2007, 127, 113.
2. [2]
  (2) Batiot, C.; Hodnett, B. Appl. Catal. A 1996, 137, 179.
3. [3]
  (3) Liu,W.; Lai, S. Y.; Dai, H.;Wang, S.; Sun, H.; Au, C. T. Catal. Today 2008, 131, 450.
4. [4]
  (4) Liu, Y. M.; Cao, Y.; Yi, N.; Feng,W. L.; Dai,W. L.; Yan, S. R.; He, H. Y.; Fan, K. N. J. Catal. 2004, 224, 417.
5. [5]
  (5) Liu, Y. M.; Cao, Y.; Zhu, K. K.; Yan, S. R.; Dai,W. L.; He, H. Y.; Fan, K. N. Chem. Commun. 2002, 2832.
6. [6]
  (6) Liu, Y. M.; Feng,W. L.;Wang, L. C.; Cao, Y.; Dai,W. L.; He, H. Y.; Fan, K. N. Catal. Lett. 2006, 106, 145.
7. [7]
  (7) Chen, K.; Xie, S.; Bell, A. T.; Iglesia, E. J. Catal. 2001, 198, 232.
8. [8]
  (8) Chen, K.; Iglesia, E.; Bell, A. T. J. Phys. Chem. B 2001, 105, 646.
9. [9]
  (9) Chen, K.; Xie, S.; Bell, A. T.; Iglesia, E. J. Catal. 2000, 195, 244.
10. [10]
  (10) Samson, K.; Klisinska, A.; Gressel, I.; Grzybowska, B. React. Kinet. Catal. Lett. 2002, 77, 309.
11. [11]
  (11) Dury, F.; Gaigneaux, E.; Ruiz, P. Appl. Catal. A 2003, 242, 187.
12. [12]
  (12) Ducarme, V.; Martin, G. Catal. Lett. 1994, 23, 97.
13. [13]
  (13) Jalowiecki-Duhamel, L.; Ponchel, A.; Lamonier, C.; D?Huysser, A.; Barbaux, Y. Langmuir 2001, 17, 1511.
14. [14]
  (14) Boizumault-Moriceau, P.; Pennequin, A.; Grzybowska, B.; Barbaux, Y. Appl. Catal. A 2003, 245, 55.
15. [15]
  (15) Liu, Y. M.;Wang, L. C.; Chen, M.; Xu, J.; Cao, Y.; He, H. Y.; Fan, K. N. Catal. Lett. 2009, 130, 350.
16. [16]
  (16) He, Y.;Wu, Y.; Chen, T.;Weng,W.;Wan, H. Catal. Commun. 2006, 7, 268.
17. [17]
  (17) Wu, Y.; He, Y.; Chen, T.;Weng,W.;Wan, H. Appl. Surf. Sci. 2006, 252, 5220.
18. [18]
  (18) Li, J. H.;Wang, C. C.; Huang, C. J.;Weng,W. Z.;Wan, H. L. Catal. Lett. 2010, 137, 81.
19. [19]
  (19) Li, J. H.;Wang, C. C.; Huang, C. J.; Sun, Y. F.;Weng,W. Z.; Wan, H. L. Appl. Catal. A 2010, 382, 99.
20. [20]
  (20) Liu, Q.; Zhang,W. M.; Cui, Z. M.; Zhang, B.;Wan, L. J.; Song, W. G. Microporous Mesoporous Mat. 2007, 100, 233.
21. [21]
  (21) Liu, J.; Du, S.;Wei, L.; Liu, H.; Tian, Y.; Chen, Y. Catal. Lett. 2006, 60, 3601.
22. [22]
  (22) Sominski, E.; Gedanken, A.; Perkas, N.; Buchkremer, H.; Menzler, N.; Zhang, L.; Yu, J. Microporous Mesoporous Mat. 2003, 60, 91.
23. [23]
  (23) Banerjee, S.; Santhanam, A.; Dhathathreyan, A.; Rao, P. M. Langmuir 2003, 19, 5522.
24. [24]
  (24) Zhao, D. D.; Xu, M.W.; Zhou,W. J.; Zhang, J.; Li, H. L. Electrochim. Acta 2008, 53, 2699.
25. [25]
  (25) Liu, Y.; Zhao,W.; Zhang, X. Electrochim. Acta 2008, 53, 3296.
26. [26]
  (26) Tan, Y.; Srinivasan, S.; Choi, K. S. J. Am. Chem. Soc. 2005, 127, 3596.
27. [27]
  (27) Liu, Y. M.; Cao, Y.; Dai,W. L.; Fan, K. N. Petrochemical Technology 2004, 33, 368.
28. [28]
  [刘永梅, 曹勇, 戴维林, 范康年. 石油化工2004, 33, 368.]
29. [29]
  (28) Liu, Y. M. Preparation and Characterization of New Nanostructured Catalysts for Oxidative Dehydrogenation of Propane to Propene. Ph. D. Dissertation, Fudan University, Shanghai, 2004.
30. [30]
  [刘咏梅. 丙烷氧化脱氢制丙烯纳米催化剂的制备表征及应用
31. [31]
  [D]. 上海: 复旦大学, 2004.]
1. [1]
  Pei Li , Yuenan Zheng , Zhankai Liu , An-Hui Lu . Boron-Containing MFI Zeolite: Microstructure Control and Its Performance of Propane Oxidative Dehydrogenation. Acta Physico-Chimica Sinica, 2025, 41(4): 100034-. doi: 10.3866/PKU.WHXB202406012
2. [2]
  Zhuoyan Lv , Yangming Ding , Leilei Kang , Lin Li , Xiao Yan Liu , Aiqin Wang , Tao Zhang . Light-Enhanced Direct Epoxidation of Propylene by Molecular Oxygen over CuO_x/TiO₂ Catalyst. Acta Physico-Chimica Sinica, 2025, 41(4): 100038-. doi: 10.3866/PKU.WHXB202408015
3. [3]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
4. [4]
  Guojie Xu , Fang Yu , Yunxia Wang , Meng Sun . Introduction to Metal-Catalyzed β-Carbon Elimination Reaction of Cyclopropenones. University Chemistry, 2024, 39(8): 169-173. doi: 10.3866/PKU.DXHX202401060
5. [5]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
6. [6]
  Xingyang LI , Tianju LIU , Yang GAO , Dandan ZHANG , Yong ZHOU , Meng PAN . A superior methanol-to-propylene catalyst: Construction via synergistic regulation of pore structure and acidic property of high-silica ZSM-5 zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1279-1289. doi: 10.11862/CJIC.20240026
7. [7]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
8. [8]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
9. [9]
  Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V₂O₅/TiO₂ catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210
10. [10]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
11. [11]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . 层状双金属氢氧化物的层间阴离子对衍生的Ni-Al₂O₃催化剂光热催化CO₂甲烷化反应的影响. Acta Physico-Chimica Sinica, 2025, 41(1): 2309002-. doi: 10.3866/PKU.WHXB202309002
12. [12]
  Hailian Tang , Siyuan Chen , Qiaoyun Liu , Guoyi Bai , Botao Qiao , Fei Liu . Stabilized Rh/hydroxyapatite Catalyst for Furfuryl Alcohol Hydrogenation: Application of Oxidative Strong Metal-Support Interactions in Reducing Conditions. Acta Physico-Chimica Sinica, 2025, 41(4): 100036-. doi: 10.3866/PKU.WHXB202408004
13. [13]
  Zijian Zhao , Yanxin Shi , Shicheng Li , Wenhong Ruan , Fang Zhu , Jijun Jiang . A New Exploration of the Preparation of Polyacrylic Acid by Free Radical Polymerization Based on the Concept of Green Chemistry. University Chemistry, 2024, 39(5): 315-324. doi: 10.3866/PKU.DXHX202311094
14. [14]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
15. [15]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
16. [16]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
17. [17]
  Juntao Yan , Liang Wei . 2D S-Scheme Heterojunction Photocatalyst. Acta Physico-Chimica Sinica, 2024, 40(10): 2312024-. doi: 10.3866/PKU.WHXB202312024
18. [18]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-. doi: 10.3866/PKU.WHXB202405016
19. [19]
  Dan Li , Hui Xin , Xiaofeng Yi . Comprehensive Experimental Design on Ni-based Catalyst for Biofuel Production. University Chemistry, 2024, 39(8): 204-211. doi: 10.3866/PKU.DXHX202312046
20. [20]
  Minna Ma , Yujin Ouyang , Yuan Wu , Mingwei Yuan , Lijuan Yang . Green Synthesis of Medical Chemiluminescence Reagents by Photocatalytic Oxidation. University Chemistry, 2024, 39(5): 134-143. doi: 10.3866/PKU.DXHX202310093

Get Citation

PDF

XML

Metrics

PDF Downloads(982)
Abstract views(2855)
HTML views(15)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142