Citation: WANG Cai-Cai, LI Jian-Hui, SUN Yi-Fei, ZHU Xiao-Quan, HUANG Chuan-Jing, WENG Wei-Zheng, WAN Hui-Lin. Synthesis and Catalytic Performances of Mesoporous CeNiO Catalysts for the Oxidative Dehydrogenation of Propane to Propene[J]. Acta Physico-Chimica Sinica, ;2011, 27(10): 2421-2426. doi: 10.3866/PKU.WHXB20110932 shu

Synthesis and Catalytic Performances of Mesoporous CeNiO Catalysts for the Oxidative Dehydrogenation of Propane to Propene

1.
State Key Laboratory of Physical Chemistry of Solid Surfaces, National Engineering Laboratory for Green Chemical Productions of Alcohols, Ethers and Esters, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian Province, P. R. China

Received Date: 2 June 2011
Available Online: 27 July 2011
Fund Project: 国家重点基础研究发展规划项目(973) (2010CB732300) (973) (2010CB732300) 国家自然科学基金(21073148, 21033006, 20803060) (21073148, 21033006, 20803060)福建省自然科学基金(2009J01038)资助 (2009J01038)

Mesoporous NiO and CeNiO catalysts were prepared by homogeneous precipitation using sodium dodecyl sulfate (SDS) mixed with triblock copolymer P123 as a template and urea as a hydrolysiscontrolling agent. The prepared catalysts were evaluated for the oxidative dehydrogenation of propane (ODP) to propene and the structure and properties of the catalysts were characterized by N₂ adsorptiondesorption, transmission electron microscopy (TEM), powder X-ray diffraction (XRD), and H₂ temperatureprogrammed reduction (H₂-TPR). The results showed that between 400 and 450°C, the NiO and CeNiO catalysts exhibited similar catalytic behavior for the ODP reaction but at low temperatures (<400°C) the catalysts doped with Ce had higher catalytic activity. On NiO only a 3.1% propene yield was obtained at 325°C while the yield on 5CeNiO (n_Ce/n_Ni=5%) was as high as 12.2% at the same temperature. The results of N₂ adsorption-desorption and TEM indicated that both the prepared NiO and CeNiO catalysts possessed a high surface area and a wormhole-like mesostructure. The H₂-TPR results revealed that part of the oxygen species became more reducible because of the presence of Ce in CeNiO, which may be the main reason for the higher activities of the catalysts.
- Propane,
- Oxidative dehydrogenation,
- Propene,
- Mesoporous CeNiO catalyst
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