Citation: XIAO Quan-Lan, MENG Jian-Xin, XIE Li-Juan, ZHANG Rui. Near-Infrared Luminescence Enhancement by Co-Doped Bi³⁺ in YVO₄:Yb³⁺[J]. Acta Physico-Chimica Sinica, ;2011, 27(10): 2427-2431. doi: 10.3866/PKU.WHXB20110928 shu

Near-Infrared Luminescence Enhancement by Co-Doped Bi³⁺ in YVO₄:Yb³⁺

1.
1. Department of Chemistry, Jinan University, Guangzhou 510632, P. R. China;
2. Intitute of Nanochemistry, Jinan Univesity, Guangzhou 510632, P. R. China

Received Date: 15 June 2011
Available Online: 19 July 2011
Fund Project: 国家自然科学基金(30670523) (30670523)

The near-infrared (NIR) luminescence phosphor Yb³⁺,Bi³⁺ co-doped YVO₄ was prepared by a conventional solid state method and the sensitization of Yb³⁺ near-infrared luminescence by Bi³⁺ was investigated. By co-doping with Bi³⁺ from 0 to 0.05 the characteristic NIR luminescence of Yb³⁺ in the YVO₄ matrix was greatly enhanced and the strongest site of the excitation wavelength red-shifted from 335 to 352 nm while the wavelength range of the excitation spectrum broadened from 300-360 to 300-430 nm. The optimized Bi³⁺ content is 0.03. The possible energy transfer mechanism among VO₄^3-, Bi³⁺ , and Yb³⁺ was discussed. We conclude that the NIR luminescence of YVO₄:Yb³⁺ can be remarkably improved by co-doping with Bi³⁺ and its absorbance matches better with the solar energy spectrum. YVO₄:Yb³⁺, Bi³⁺ is a promising spectral converter for silicon solar cells and it is expected to improve the photoelectric conversion efficiency.
- Near-infrared luminescence,
- Solid state reaction,
- Energy down-conversion,
- YVO₄：Yb³⁺,Bi³⁺
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Near-Infrared Luminescence Enhancement by Co-Doped Bi3+ in YVO4:Yb3+

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Near-Infrared Luminescence Enhancement by Co-Doped Bi³⁺ in YVO₄:Yb³⁺