Citation: BU Yu-Yu, LI Wei-Bing, YU Jian-Qiang, WANG Xiu-Tong, QI Mei-Ling, NIE Meng-Yan, HOU Bao-Rong. Fabrication of SrTiO₃ Nanocrystalline Film Photoelectrode and Its Photoelectrochemical Anticorrosion Properties for Stainless Steel[J]. Acta Physico-Chimica Sinica, ;2011, 27(10): 2393-2399. doi: 10.3866/PKU.WHXB20110926 shu

Fabrication of SrTiO₃ Nanocrystalline Film Photoelectrode and Its Photoelectrochemical Anticorrosion Properties for Stainless Steel

1.
1. Faculty of Environment and Safety, Qingdao University of Science and Technology, Qingdao 266042, Shandong Province, P. R. China;
2. Key Laboratory of New Fiber Materials and Modern Textile, Qingdao University 266071, Shandong Province, P. R. China;
3. Institute of Oceanology, Chinese Academy of Science, Qingdao 266071, Shandong Province, P. R. China;
4. National Centre for Advanced Tribology at Southampton, School of Engineering Sciences, University of Southampton, Southampton, United Kingdom

Received Date: 2 June 2011
Available Online: 15 July 2011
Fund Project: 中国科学院知识创新工程领域前沿项目及国家自然科学基金(20973097)资助 (20973097)

The photoelectrochemical properties of a SrTiO₃ film coated on an indium-tin oxide (ITO) conducting glass were investigated for the anticorrosion of 304 stainless steel (304SS) under solar light illumination. The SrTiO₃ nanocrystal powders were synthesized using a sol-gel process in the absence and presence of the cetyltrimethyl ammonium bromide (CTAB) surfactant and characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). It was showed that the as-synthesized SrTiO₃ materials exhibit a single perovskite structure and the presence of CTAB leads to uniform particles with an average size of 90 nm. The UV-Vis diffuse reflectance analysis shows that both SrTiO₃ films that were prepared in the absence and presence of CTAB surfactant absorbs strongly in the UV region with an absorption threshold edge near 380 nm while the SiTiO3 prepared in the presence of CTAB exhibited a stronger absorption in the UV region than those in the absence of CTAB. The photo-electrochemical anticorrosion effects of SrTiO₃ on 304 stainless steel substrates in a 0.5 mol·L^-1 NaCl solution were investigated using a 0.1 mol·L^-1 NaOH and 0.2 mol·L^-1 Na₂S hole sacrifice electrolyte solution. Metallographic images of the 304 stainless steel before and after immersion in a 0.5 mol·L^-1 NaCl+0.05 mol·L^-1 HCl solution for 6 h demonstrates that the SrTiO₃ film coated photoelectrode exhibits excellent photoelectrochemical anticorrosion performance on 304 stainless steel.
- SrTiO₃,
- Film photoelectrode,
- Photoelectrochemistry,
- Corrosion and protection,
- 304 stainless steel
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1.
沈阳化工大学材料科学与工程学院沈阳 110142

Fabrication of SrTiO3 Nanocrystalline Film Photoelectrode and Its Photoelectrochemical Anticorrosion Properties for Stainless Steel

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通讯作者: 陈斌, bchen63@163.com

Fabrication of SrTiO₃ Nanocrystalline Film Photoelectrode and Its Photoelectrochemical Anticorrosion Properties for Stainless Steel