Citation: PENG Tian-You, KE Ding-Ning, ZENG Peng, ZHANG Xiao-Hu, FAN Ke. Preparation and Photoelectrochemical Performance of BiVO₄ Film Electrode[J]. Acta Physico-Chimica Sinica, ;2011, 27(09): 2160-2166. doi: 10.3866/PKU.WHXB20110913 shu

Preparation and Photoelectrochemical Performance of BiVO₄ Film Electrode

1.
College of Chemistry and Molecular Science, Wuhan University, Wuhan 430072, P. R. China

Received Date: 6 April 2011
Available Online: 11 July 2011
Fund Project: 国家自然科学基金(20871096, 20973128) (20871096, 20973128) 教育部新世纪优秀人才计划(NCET-07-0637) (NCET-07-0637)高校基本科研业务基金(2081003)资助 (2081003)

A BiVO₄ film electrode was prepared using a home-made BiVO₄ nanopowder and the effects of annealing temperature and film thickness on its photoelectrochemical behavior, electron transport and recombination in the BiVO₄ electrode were systematically studied by electrochemical techniques. Experimental results indicate that the annealing temperature and film thickness can significantly influence the photoelectrochemical characteristics of the BiVO₄ electrode. At low annealing temperature (≤500 °C) the photoelectrochemical activity improved upon increasing the temperature and the optimal activity was obtained for the electrode annealed at 500 ° C. At high temperature (>500 ° C) the photoelectrochemical activity decreased because of a marked increase of bulk traps in the electrode. The BiVO₄ electrode showed od photon-to-electron conversion efficiency under visible light and its bandgap was found to be 2.36 eV based on an incident monochromatic photon-to-electric conversion efficiency curve. The flat-band potential (E_fb) of BiVO₄ was determined to be -0.7 V (vs Ag/AgCl) by the Mött Schottky method. These results give an important reference for the optimization of the BiVO₄ photocatalytic system.
- BiVO₄ film electrode,
- Photoelectrochemical performance,
- Transient photocurrent spectrum,
- Flat-band potential
1. [1]
  (1) Kudo, A. Int. J. Hydrog. Energy 2006, 31, 197.
2. [2]
  (2) Kay, A.; Cesar, I.; Gratzel, M. J. Am. Chem. Soc. 2006, 128, 15714.
3. [3]
  (3) Hoffmann, M. R.; Martin, S. T.; Choi,W.; Bahnemann, D.W. Chem. Rev. 1995, 95, 69.
4. [4]
  (4) Kudo, A.; Miseki, Y. Chem. Soc. Rev. 2009, 38, 253.
5. [5]
  (5) Beranek, R.; Kisch, H. Electrochem. Commun. 2007, 9, 761.
6. [6]
  (6) Jiang, D. L.; Zhang, S. Q.; Zhao, H. J. Envir. Sci. & Tech. 2007, 41, 303.
7. [7]
  (7) Nakamura, R.; Tanaka, T.; Nakato, Y. J. Phys. Chem. B 2004, 108, 10617.
8. [8]
  (8) Beranek, R.; Neumann, B.; Sakthivel, S.; Janczarek, M.; Dittrich, T.; Tributsch, H.; Kisch, H. Chem. Phys. 2007, 339, 11.
9. [9]
  (9) Xie, B. P.; Zhang, H. X.; Cai, P. X.; Qiu, R. L.; Xiong, Y. Chemosphere 2006, 63, 956.
10. [10]
  (10) Kohtani, S.; Koshiko, M.; Kudo, A.; Tokumura, K.; Ishigaki, Y.; Toriba, A.; Hayakawa, K.; Nakagaki, R. Appl. Catal. B 2003, 46, 573.
11. [11]
  (11) Ke, D. N.; Peng, T. Y.; Ma, L.; Cai, P.; Jiang, P. Appl. Catal. A 2009, 35, 111.
12. [12]
  (12) Luo, H. M.; Mueller, A. H.; McCleskey, T. M.; Burrell, A. K.; Bauer, E.; Jia, Q. X. J. Phys. Chem. C 2008, 112, 6099.
13. [13]
  (13) Long, M. C.; Beranek, R.; Cai,W. M.; Kisch, H. Electrochim. Acta 2008, 53, 4621.
14. [14]
  (14) Sayama, K.; Nomura, A.; Arai, T.; Sugita, T.; Abe, R.; Yanagida, M.; Oi, T.; Iwasaki, Y.; Abe, Y.; Sugihara, H. J. Phys. Chem. B 2006, 110, 11352.
15. [15]
  (15) Peng, T. Y.; Fan, K.; Zhao, D.; Chen, J. N. J. Phys. Chem. C 2010, 114, 22346.
16. [16]
  (16) Niu, C.; Sichel, E.; Hoch, R.; Moy, D.; Tennent, H. Appl. Phys. Lett. 1997, 70, 1480.
17. [17]
  (17) Chu, D. B.; Zhang, J. H.; Feng, D. X.; Li, X. H.; Yao,W. L. Chin. J. Appl. Chem. 2006, 23, 252. [褚道葆, 张金花, 冯德香, 李晓华, 姚文俐. 应用化学, 2006, 23, 252.]
18. [18]
  (18) Li,W. Z.; Li, H.;Wang, X.; Zhang, S. J.; Chen, Q. Y. Acta Phys. -Chim. Sin. 2010, 26 (9), 2343. [李文章, 李浩, 王旋, 张姝娟, 陈启元. 物理化学学报, 2010, 26 (9), 2343.]
19. [19]
  (19) Long, M. C.; Cai,W. M.; Kisch, H. J. Phys. Chem. C 2008, 112, 548.
20. [20]
  (20) Chemla, M.; Dufreche, J. F.; Darolles, I.; Rouelle, F.; Devilliers, D.; Petitdidier, S.; Levy, D. Electrochim. Acta 2005, 51, 665.
21. [21]
  (21) Dai, J.; Hu, L. H.; Lin,W. Q.; Dai, S. Y. Acta Phys. Sin. 2008, 57, 5310.
22. [22]
  (22) Burgeth, G.; Kisch, H. Coord. Chem. Rev. 2002, 230, 41.
23. [23]
  (23) Xu, H.; Liu, L.; Jia, N. Q.; Yang, J.; Yan, M. M.; Jiang, Z. Y. Chin. J. Chem. 2005, 23, 18.
24. [24]
  (24) Sayama, K.; Nomura, A.; Zou, Z. G.; Abe, R.; Abe, Y.; Arakawa, H. Chem. Commun. 2003, No. 23, 2908.
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沈阳化工大学材料科学与工程学院沈阳 110142

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通讯作者: 陈斌, bchen63@163.com

Preparation and Photoelectrochemical Performance of BiVO₄ Film Electrode